Synthetic routes to phenylene vinylene dendrimers

JN Pillow; PL Burn; Ifor David William Samuel; M Halim

Synthetic routes to phenylene vinylene dendrimers

JN Pillow, PL Burn, Ifor David William Samuel, M Halim

Research output: Contribution to journal › Article › peer-review

Abstract

Dendrimers offer the opportunity to vary the electronic properties of an electroactive material without changing the processing procedure. Poly(1,4-phenylenevinylene) and its derivatives have been widely studied for use in light-emitting diodes. We have investigated two different iterative routes for the formation of phenylenevinylene based dendrimers to compare their properties with the linear counterparts. Our approach involves palladium-catalysed coupling of styryl derivatives to halo-benzenes which has enabled the rapid construction of a family of dendrimers.

Original language	English
Pages (from-to)	1468
Number of pages	1468
Journal	Synthetic Metals
Volume	102
Publication status	Published - Jun 1999

Keywords

transition-metal-catalysed reactions
electroluminescence
organic semiconductors based on conjugated molecules

Cite this

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title = "Synthetic routes to phenylene vinylene dendrimers",

abstract = "Dendrimers offer the opportunity to vary the electronic properties of an electroactive material without changing the processing procedure. Poly(1,4-phenylenevinylene) and its derivatives have been widely studied for use in light-emitting diodes. We have investigated two different iterative routes for the formation of phenylenevinylene based dendrimers to compare their properties with the linear counterparts. Our approach involves palladium-catalysed coupling of styryl derivatives to halo-benzenes which has enabled the rapid construction of a family of dendrimers.",

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author = "JN Pillow and PL Burn and Samuel, \{Ifor David William\} and M Halim",

year = "1999",

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language = "English",

volume = "102",

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journal = "Synthetic Metals",

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T1 - Synthetic routes to phenylene vinylene dendrimers

AU - Pillow, JN

AU - Burn, PL

AU - Samuel, Ifor David William

AU - Halim, M

PY - 1999/6

Y1 - 1999/6

N2 - Dendrimers offer the opportunity to vary the electronic properties of an electroactive material without changing the processing procedure. Poly(1,4-phenylenevinylene) and its derivatives have been widely studied for use in light-emitting diodes. We have investigated two different iterative routes for the formation of phenylenevinylene based dendrimers to compare their properties with the linear counterparts. Our approach involves palladium-catalysed coupling of styryl derivatives to halo-benzenes which has enabled the rapid construction of a family of dendrimers.

AB - Dendrimers offer the opportunity to vary the electronic properties of an electroactive material without changing the processing procedure. Poly(1,4-phenylenevinylene) and its derivatives have been widely studied for use in light-emitting diodes. We have investigated two different iterative routes for the formation of phenylenevinylene based dendrimers to compare their properties with the linear counterparts. Our approach involves palladium-catalysed coupling of styryl derivatives to halo-benzenes which has enabled the rapid construction of a family of dendrimers.

KW - transition-metal-catalysed reactions

KW - electroluminescence

KW - organic semiconductors based on conjugated molecules

UR - https://www.scopus.com/pages/publications/0033137719

M3 - Article

SN - 0379-6779

VL - 102

SP - 1468

JO - Synthetic Metals

JF - Synthetic Metals

ER -

Synthetic routes to phenylene vinylene dendrimers

Abstract

Keywords

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