Synthetic routes to [Au(NHC)(OH)] (NHC = N-heterocyclic carbene) complexes

Adrian Gomez-Suarez; Ruben S. Ramon; Alexandra M. Z. Slawin; Steven P. Nolan

doi:10.1039/c2dt30294b

Synthetic routes to [Au(NHC)(OH)] (NHC = N-heterocyclic carbene) complexes

Adrian Gomez-Suarez, Ruben S. Ramon, Alexandra M. Z. Slawin, Steven P. Nolan

Research output: Contribution to journal › Article › peer-review

Abstract

New procedures for the synthesis of [Au(NHC)(OH)] are reported. Initially, a two-step reaction via the digold complex [{Au(NHC)}(2)(mu-OH)][qBF(4)] was probed, enabling the preparation of the novel [Au(SIPr)(OH)] complex and of its previously reported congener [Au(IPr)(OH)]. After further optimization, a one-step procedure was developed.

Original language	English
Pages (from-to)	5461-5463
Number of pages	3
Journal	Dalton Transactions
Volume	41
Issue number	18
DOIs	https://doi.org/10.1039/c2dt30294b
Publication status	Published - 2012

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10.1039/c2dt30294b

EPSRC - EP/J011053/1- LATE TRANSITION: Late Transition Metal Hydroxide in Homogeneous Catalysis
Nolan, S. (PI)
EPSRC
15/03/12 → 14/03/15
Project: Standard

Cite this

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title = "Synthetic routes to [Au(NHC)(OH)] (NHC = N-heterocyclic carbene) complexes",

abstract = "New procedures for the synthesis of [Au(NHC)(OH)] are reported. Initially, a two-step reaction via the digold complex [{Au(NHC)}(2)(mu-OH)][qBF(4)] was probed, enabling the preparation of the novel [Au(SIPr)(OH)] complex and of its previously reported congener [Au(IPr)(OH)]. After further optimization, a one-step procedure was developed.",

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AU - Gomez-Suarez, Adrian

AU - Ramon, Ruben S.

AU - Slawin, Alexandra M. Z.

AU - Nolan, Steven P.

PY - 2012

Y1 - 2012

N2 - New procedures for the synthesis of [Au(NHC)(OH)] are reported. Initially, a two-step reaction via the digold complex [{Au(NHC)}(2)(mu-OH)][qBF(4)] was probed, enabling the preparation of the novel [Au(SIPr)(OH)] complex and of its previously reported congener [Au(IPr)(OH)]. After further optimization, a one-step procedure was developed.

AB - New procedures for the synthesis of [Au(NHC)(OH)] are reported. Initially, a two-step reaction via the digold complex [{Au(NHC)}(2)(mu-OH)][qBF(4)] was probed, enabling the preparation of the novel [Au(SIPr)(OH)] complex and of its previously reported congener [Au(IPr)(OH)]. After further optimization, a one-step procedure was developed.

U2 - 10.1039/c2dt30294b

DO - 10.1039/c2dt30294b

M3 - Article

SN - 1477-9226

VL - 41

SP - 5461

EP - 5463

JO - Dalton Transactions

JF - Dalton Transactions

IS - 18

ER -

Synthetic routes to [Au(NHC)(OH)] (NHC = N-heterocyclic carbene) complexes

Abstract

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Projects

EPSRC - EP/J011053/1- LATE TRANSITION: Late Transition Metal Hydroxide in Homogeneous Catalysis

Cite this