Synthetic control of framework zinc purinate crystallisation and properties of a large pore, decorated, mixed-linker RHO-type ZIF

Juergen Kahr; John P. S. Mowat; Alexandra M. Z. Slawin; Russell E. Morris; David Fairen-Jimenez; Paul A. Wright

doi:10.1039/c2cc32927a

Synthetic control of framework zinc purinate crystallisation and properties of a large pore, decorated, mixed-linker RHO-type ZIF

Juergen Kahr, John P. S. Mowat, Alexandra M. Z. Slawin, Russell E. Morris, David Fairen-Jimenez, Paul A. Wright

Research output: Contribution to journal › Article › peer-review

Abstract

A novel form of mixed-linker ZIF with the RHO topology is one of four zinc-imidazolate frameworks prepared with purine and 2-nitroimidazole. In this structure the linkers order to give a large pore solid with a high pore volume and an unusual symmetry and linker orientation. It possesses extra-framework zinc imidazolate units decorating the internal surface which can be removed to give high porosity.

Original language	English
Pages (from-to)	6690-6692
Number of pages	3
Journal	Chemical Communications
Volume	48
Issue number	53
DOIs	https://doi.org/10.1039/c2cc32927a
Publication status	Published - 2012

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title = "Synthetic control of framework zinc purinate crystallisation and properties of a large pore, decorated, mixed-linker RHO-type ZIF",

abstract = "A novel form of mixed-linker ZIF with the RHO topology is one of four zinc-imidazolate frameworks prepared with purine and 2-nitroimidazole. In this structure the linkers order to give a large pore solid with a high pore volume and an unusual symmetry and linker orientation. It possesses extra-framework zinc imidazolate units decorating the internal surface which can be removed to give high porosity.",

author = "Juergen Kahr and Mowat, {John P. S.} and Slawin, {Alexandra M. Z.} and Morris, {Russell E.} and David Fairen-Jimenez and Wright, {Paul A.}",

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doi = "10.1039/c2cc32927a",

language = "English",

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journal = "Chemical Communications",

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publisher = "Royal Society of Chemistry",

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T1 - Synthetic control of framework zinc purinate crystallisation and properties of a large pore, decorated, mixed-linker RHO-type ZIF

AU - Kahr, Juergen

AU - Mowat, John P. S.

AU - Slawin, Alexandra M. Z.

AU - Morris, Russell E.

AU - Fairen-Jimenez, David

AU - Wright, Paul A.

PY - 2012

Y1 - 2012

N2 - A novel form of mixed-linker ZIF with the RHO topology is one of four zinc-imidazolate frameworks prepared with purine and 2-nitroimidazole. In this structure the linkers order to give a large pore solid with a high pore volume and an unusual symmetry and linker orientation. It possesses extra-framework zinc imidazolate units decorating the internal surface which can be removed to give high porosity.

AB - A novel form of mixed-linker ZIF with the RHO topology is one of four zinc-imidazolate frameworks prepared with purine and 2-nitroimidazole. In this structure the linkers order to give a large pore solid with a high pore volume and an unusual symmetry and linker orientation. It possesses extra-framework zinc imidazolate units decorating the internal surface which can be removed to give high porosity.

U2 - 10.1039/c2cc32927a

DO - 10.1039/c2cc32927a

M3 - Article

SN - 1359-7345

VL - 48

SP - 6690

EP - 6692

JO - Chemical Communications

JF - Chemical Communications

IS - 53

ER -

Synthetic control of framework zinc purinate crystallisation and properties of a large pore, decorated, mixed-linker RHO-type ZIF

Abstract

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