Synthetic and crystallographic investigation of the layered coordination framework copper-1,3-bis(4-carboxyphenyl)-5-ethoxybenzene

Lauren N. McHugh; David B. Cordes; Paul S. Wheatley; Alexandra M. Z. Slawin; Russell E. Morris

doi:10.1021/acs.cgd.9b01369

Synthetic and crystallographic investigation of the layered coordination framework copper-1,3-bis(4-carboxyphenyl)-5-ethoxybenzene

Lauren N. McHugh, David B. Cordes, Paul S. Wheatley, Alexandra M. Z. Slawin, Russell E. Morris

Research output: Contribution to journal › Article › peer-review

Abstract

The reaction of 1,3-bis(4-carboxyphenyl)-5-ethoxybenzene and copper acetate monohydrate yields copper-1,3-bis(4-carboxyphenyl)-5-ethoxybenzene(DMF), and upon removal of coordinated DMF molecules, copper-1,3-bis(4-carboxyphenyl)-5-ethoxybenzene is attained. The compound does not form as a traditional three-dimensional metal–organic framework and instead produces a “layered coordination framework”, where the individual layers are separated by the ethyl chains on the linker. The synthesis and crystallographic characterization of the material are described.

Original language	English
Pages (from-to)	39-42
Number of pages	4
Journal	Crystal Growth & Design
Volume	20
Issue number	1
Early online date	2 Dec 2019
DOIs	https://doi.org/10.1021/acs.cgd.9b01369
Publication status	Published - 2 Jan 2020

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10.1021/acs.cgd.9b01369

Synthetic and crystallographic investigation of the layered coordination framework copper-1,3-bis(4-carboxyphenyl)-5-ethoxybenzene (dataset)
McHugh, L. N. (Creator), Cordes, D. B. (Creator), Wheatley, P. S. (Creator), Slawin, A. M. Z. (Creator) & Morris, R. E. (Creator), Cambridge Crystallographic Data Centre, 2020
https://dx.doi.org/10.5517/ccdc.csd.cc23krhy and one more link, https://dx.doi.org/10.5517/ccdc.csd.cc23krgx (show fewer)
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title = "Synthetic and crystallographic investigation of the layered coordination framework copper-1,3-bis(4-carboxyphenyl)-5-ethoxybenzene",

abstract = "The reaction of 1,3-bis(4-carboxyphenyl)-5-ethoxybenzene and copper acetate monohydrate yields copper-1,3-bis(4-carboxyphenyl)-5-ethoxybenzene(DMF), and upon removal of coordinated DMF molecules, copper-1,3-bis(4-carboxyphenyl)-5-ethoxybenzene is attained. The compound does not form as a traditional three-dimensional metal–organic framework and instead produces a “layered coordination framework”, where the individual layers are separated by the ethyl chains on the linker. The synthesis and crystallographic characterization of the material are described.",

author = "McHugh, {Lauren N.} and Cordes, {David B.} and Wheatley, {Paul S.} and Slawin, {Alexandra M. Z.} and Morris, {Russell E.}",

note = "The authors would like to acknowledge the financial support from the EPSRC industrial CASE award (Grant EP/N50936X/1).",

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doi = "10.1021/acs.cgd.9b01369",

language = "English",

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T1 - Synthetic and crystallographic investigation of the layered coordination framework copper-1,3-bis(4-carboxyphenyl)-5-ethoxybenzene

AU - McHugh, Lauren N.

AU - Cordes, David B.

AU - Wheatley, Paul S.

AU - Slawin, Alexandra M. Z.

AU - Morris, Russell E.

N1 - The authors would like to acknowledge the financial support from the EPSRC industrial CASE award (Grant EP/N50936X/1).

PY - 2020/1/2

Y1 - 2020/1/2

N2 - The reaction of 1,3-bis(4-carboxyphenyl)-5-ethoxybenzene and copper acetate monohydrate yields copper-1,3-bis(4-carboxyphenyl)-5-ethoxybenzene(DMF), and upon removal of coordinated DMF molecules, copper-1,3-bis(4-carboxyphenyl)-5-ethoxybenzene is attained. The compound does not form as a traditional three-dimensional metal–organic framework and instead produces a “layered coordination framework”, where the individual layers are separated by the ethyl chains on the linker. The synthesis and crystallographic characterization of the material are described.

AB - The reaction of 1,3-bis(4-carboxyphenyl)-5-ethoxybenzene and copper acetate monohydrate yields copper-1,3-bis(4-carboxyphenyl)-5-ethoxybenzene(DMF), and upon removal of coordinated DMF molecules, copper-1,3-bis(4-carboxyphenyl)-5-ethoxybenzene is attained. The compound does not form as a traditional three-dimensional metal–organic framework and instead produces a “layered coordination framework”, where the individual layers are separated by the ethyl chains on the linker. The synthesis and crystallographic characterization of the material are described.

U2 - 10.1021/acs.cgd.9b01369

DO - 10.1021/acs.cgd.9b01369

M3 - Article

SN - 1528-7483

VL - 20

SP - 39

EP - 42

JO - Crystal Growth & Design

JF - Crystal Growth & Design

IS - 1

ER -

Synthetic and crystallographic investigation of the layered coordination framework copper-1,3-bis(4-carboxyphenyl)-5-ethoxybenzene

Abstract

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Synthetic and crystallographic investigation of the layered coordination framework copper-1,3-bis(4-carboxyphenyl)-5-ethoxybenzene (dataset)

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