Synthesis, X-ray characterisation and reactions of a trigonal planar palladium(0) carbonyl complex, (tbpx)PdCO

RM Bellabarba; RP Tooze; Alexandra Martha Zoya Slawin

doi:10.1039/b305854a

Synthesis, X-ray characterisation and reactions of a trigonal planar palladium(0) carbonyl complex, (tbpx)PdCO

RM Bellabarba, RP Tooze, Alexandra Martha Zoya Slawin

Research output: Other contribution

10 Citations (Scopus)

Abstract

The novel complex (tbpx) PdCO (1), the first example of a structurally characterised sixteen electron, trigonal planar palladium(0) carbonyl complex, was prepared, characterised by NMR spectroscopy and X-ray crystallography, and some unusual aspects of its reactivity were studied.

Original language	English
Volume	7
DOIs	https://doi.org/10.1039/b305854a
Publication status	Published - 2003

Keywords

METHYL PROPANOATE
CATALYTIC METHOXYCARBONYLATION
ETHENE
MONOXIDE

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10.1039/b305854a

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title = "Synthesis, X-ray characterisation and reactions of a trigonal planar palladium(0) carbonyl complex, (tbpx)PdCO",

abstract = "The novel complex (tbpx) PdCO (1), the first example of a structurally characterised sixteen electron, trigonal planar palladium(0) carbonyl complex, was prepared, characterised by NMR spectroscopy and X-ray crystallography, and some unusual aspects of its reactivity were studied.",

keywords = "METHYL PROPANOATE, CATALYTIC METHOXYCARBONYLATION, ETHENE, MONOXIDE",

author = "RM Bellabarba and RP Tooze and Slawin, {Alexandra Martha Zoya}",

note = "Chem Commun (Camb)",

year = "2003",

doi = "10.1039/b305854a",

language = "English",

volume = "7",

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T1 - Synthesis, X-ray characterisation and reactions of a trigonal planar palladium(0) carbonyl complex, (tbpx)PdCO

AU - Bellabarba, RM

AU - Tooze, RP

AU - Slawin, Alexandra Martha Zoya

N1 - Chem Commun (Camb)

PY - 2003

Y1 - 2003

N2 - The novel complex (tbpx) PdCO (1), the first example of a structurally characterised sixteen electron, trigonal planar palladium(0) carbonyl complex, was prepared, characterised by NMR spectroscopy and X-ray crystallography, and some unusual aspects of its reactivity were studied.

AB - The novel complex (tbpx) PdCO (1), the first example of a structurally characterised sixteen electron, trigonal planar palladium(0) carbonyl complex, was prepared, characterised by NMR spectroscopy and X-ray crystallography, and some unusual aspects of its reactivity were studied.

KW - METHYL PROPANOATE

KW - CATALYTIC METHOXYCARBONYLATION

KW - ETHENE

KW - MONOXIDE

UR - http://www.ncbi.nlm.nih.gov/entrez/query.fcgi?cmd=Retrieve&db=pubmed&dopt=Abstract&list_uids=12932031

U2 - 10.1039/b305854a

DO - 10.1039/b305854a

M3 - Other contribution

VL - 7

ER -

Synthesis, X-ray characterisation and reactions of a trigonal planar palladium(0) carbonyl complex, (tbpx)PdCO

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Keywords

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