Synthesis, Structure and Properties of New Pyridylaminophosphine Complexes

SM Aucott; Alexandra Martha Zoya Slawin; John Derek Woollins

Synthesis, Structure and Properties of New Pyridylaminophosphine Complexes

SM Aucott, Alexandra Martha Zoya Slawin, John Derek Woollins

Research output: Other contribution

Abstract

Reaction of diphenylphosphino-2-aminopyridine with a variety of late transition metal species eg Pt (II), Pd (II), Ru (II) and Rh (III) in most cases leads to five-membered metallocycles containing M-P-N(H)-C-N rings. Treatment of these species with base results in deprotonation of the amino group, formation of a neutral species and election delocalisation over the P-N bond.

Original language	English
Volume	125
Publication status	Published - 1997

Keywords

phosphine
metallocycle
complex
X-ray

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@misc{3b420844ab6a4866a391d054034b86d9,

title = "Synthesis, Structure and Properties of New Pyridylaminophosphine Complexes",

abstract = "Reaction of diphenylphosphino-2-aminopyridine with a variety of late transition metal species eg Pt (II), Pd (II), Ru (II) and Rh (III) in most cases leads to five-membered metallocycles containing M-P-N(H)-C-N rings. Treatment of these species with base results in deprotonation of the amino group, formation of a neutral species and election delocalisation over the P-N bond.",

keywords = "phosphine, metallocycle, complex, X-ray",

author = "SM Aucott and Slawin, \{Alexandra Martha Zoya\} and Woollins, \{John Derek\}",

note = "Phosphorus, Sulfur, Silicon",

year = "1997",

language = "English",

volume = "125",

type = "Other",

}

TY - GEN

T1 - Synthesis, Structure and Properties of New Pyridylaminophosphine Complexes

AU - Aucott, SM

AU - Slawin, Alexandra Martha Zoya

AU - Woollins, John Derek

N1 - Phosphorus, Sulfur, Silicon

PY - 1997

Y1 - 1997

N2 - Reaction of diphenylphosphino-2-aminopyridine with a variety of late transition metal species eg Pt (II), Pd (II), Ru (II) and Rh (III) in most cases leads to five-membered metallocycles containing M-P-N(H)-C-N rings. Treatment of these species with base results in deprotonation of the amino group, formation of a neutral species and election delocalisation over the P-N bond.

AB - Reaction of diphenylphosphino-2-aminopyridine with a variety of late transition metal species eg Pt (II), Pd (II), Ru (II) and Rh (III) in most cases leads to five-membered metallocycles containing M-P-N(H)-C-N rings. Treatment of these species with base results in deprotonation of the amino group, formation of a neutral species and election delocalisation over the P-N bond.

KW - phosphine

KW - metallocycle

KW - complex

KW - X-ray

UR - https://www.scopus.com/pages/publications/0347704172

M3 - Other contribution

VL - 125

ER -

Synthesis, Structure and Properties of New Pyridylaminophosphine Complexes

Abstract

Keywords

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