Abstract
Reaction of diphenylphosphino-2-aminopyridine with a variety of late transition metal species eg Pt (II), Pd (II), Ru (II) and Rh (III) in most cases leads to five-membered metallocycles containing M-P-N(H)-C-N rings. Treatment of these species with base results in deprotonation of the amino group, formation of a neutral species and election delocalisation over the P-N bond.
Original language | English |
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Volume | 125 |
Publication status | Published - 1997 |
Keywords
- phosphine
- metallocycle
- complex
- X-ray