Synthesis, Structure and Properties of New Pyridylaminophosphine Complexes

SM Aucott, Alexandra Martha Zoya Slawin, John Derek Woollins

Research output: Other contribution

17 Citations (Scopus)

Abstract

Reaction of diphenylphosphino-2-aminopyridine with a variety of late transition metal species eg Pt (II), Pd (II), Ru (II) and Rh (III) in most cases leads to five-membered metallocycles containing M-P-N(H)-C-N rings. Treatment of these species with base results in deprotonation of the amino group, formation of a neutral species and election delocalisation over the P-N bond.

Original languageEnglish
Volume125
Publication statusPublished - 1997

Keywords

  • phosphine
  • metallocycle
  • complex
  • X-ray

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