Synthesis of phosphorus esters by transesterification mediated by N- heterocyclic carbenes (NHCs)

R Singh; Steven Patrick Nolan

doi:10.1039/b509783e

Synthesis of phosphorus esters by transesterification mediated by N- heterocyclic carbenes (NHCs)

R Singh, Steven Patrick Nolan

Research output: Contribution to journal › Article › peer-review

49 Citations (Scopus)

Abstract

The versatile nucleophilic organic catalysts N-heterocyclic carbenes (NHCs) have been shown to effectively mediate the transesterification of phosphorus esters under mild conditions; user-friendly imidazolium salts can also be employed as pre-catalysts.

Original language	English
Pages (from-to)	5456-5458
Number of pages	3
Journal	Chemical Communications
Issue number	43
DOIs	https://doi.org/10.1039/b509783e
Publication status	Published - 2005

Keywords

RING-OPENING POLYMERIZATION
NUCLEOPHILIC CARBENES
CHEMICAL DETOXIFICATION
LIVING POLYMERIZATION
GAMMA-BUTYROLACTONES
STABLE CARBENES
1ST EXAMPLE
CATALYSTS
ALCOHOLS
GENERATION

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10.1039/b509783e

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abstract = "The versatile nucleophilic organic catalysts N-heterocyclic carbenes (NHCs) have been shown to effectively mediate the transesterification of phosphorus esters under mild conditions; user-friendly imidazolium salts can also be employed as pre-catalysts.",

keywords = "RING-OPENING POLYMERIZATION, NUCLEOPHILIC CARBENES, CHEMICAL DETOXIFICATION, LIVING POLYMERIZATION, GAMMA-BUTYROLACTONES, STABLE CARBENES, 1ST EXAMPLE, CATALYSTS, ALCOHOLS, GENERATION",

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KW - RING-OPENING POLYMERIZATION

KW - NUCLEOPHILIC CARBENES

KW - CHEMICAL DETOXIFICATION

KW - LIVING POLYMERIZATION

KW - GAMMA-BUTYROLACTONES

KW - STABLE CARBENES

KW - 1ST EXAMPLE

KW - CATALYSTS

KW - ALCOHOLS

KW - GENERATION

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SP - 5456

EP - 5458

JO - Chemical Communications

JF - Chemical Communications

IS - 43

ER -

Synthesis of phosphorus esters by transesterification mediated by N- heterocyclic carbenes (NHCs)

Abstract

Keywords

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