Synthesis of periodic mesoporous ethylenesilicas under acidic conditions

W Wang; S Xie; Wuzong Zhou; A Sayari

doi:10.1021/cm035235z

Synthesis of periodic mesoporous ethylenesilicas under acidic conditions

W Wang, S Xie, Wuzong Zhou, A Sayari

Research output: Contribution to journal › Article › peer-review

Abstract

High-quality mesoporous ethylenesilicas were prepared for the first time under acidic conditions using alkylpoly(ethylene oxide) oligomers or polyalkylene oxide triblock copolymers as supramolecular templates. Depending on the synthesis conditions, materials with medium (4-5 nm) and large (8-9 nm) mesopores were obtained. Addition of butanol in conjunction with P123 under acidic condition had a dramatic effect on the pore-size distribution, which became much narrower, indicating the occurrence of a porous system with enhanced ordering.

Original language	English
Pages (from-to)	1756-1762
Number of pages	7
Journal	Chemistry of Materials
Volume	16
DOIs	https://doi.org/10.1021/cm035235z
Publication status	Published - 4 May 2004

Keywords

INORGANIC NANOCOMPOSITE MATERIALS
COPOLYMER-ASSISTED SYNTHESIS
MOLECULAR-SCALE PERIODICITY
CAGE-LIKE PORES
CHANNEL WALLS
MESOSTRUCTURED MATERIALS
STRUCTURE DIRECTORS
SILICA STRUCTURES
BENZENE-SILICA
ORGANIC GROUPS

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10.1021/cm035235z

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title = "Synthesis of periodic mesoporous ethylenesilicas under acidic conditions",

abstract = "High-quality mesoporous ethylenesilicas were prepared for the first time under acidic conditions using alkylpoly(ethylene oxide) oligomers or polyalkylene oxide triblock copolymers as supramolecular templates. Depending on the synthesis conditions, materials with medium (4-5 nm) and large (8-9 nm) mesopores were obtained. Addition of butanol in conjunction with P123 under acidic condition had a dramatic effect on the pore-size distribution, which became much narrower, indicating the occurrence of a porous system with enhanced ordering.",

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author = "W Wang and S Xie and Wuzong Zhou and A Sayari",

year = "2004",

month = may,

day = "4",

doi = "10.1021/cm035235z",

language = "English",

volume = "16",

pages = "1756--1762",

journal = "Chemistry of Materials",

issn = "0897-4756",

publisher = "American Chemical Society (ACS)",

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T1 - Synthesis of periodic mesoporous ethylenesilicas under acidic conditions

AU - Wang, W

AU - Xie, S

AU - Zhou, Wuzong

AU - Sayari, A

PY - 2004/5/4

Y1 - 2004/5/4

N2 - High-quality mesoporous ethylenesilicas were prepared for the first time under acidic conditions using alkylpoly(ethylene oxide) oligomers or polyalkylene oxide triblock copolymers as supramolecular templates. Depending on the synthesis conditions, materials with medium (4-5 nm) and large (8-9 nm) mesopores were obtained. Addition of butanol in conjunction with P123 under acidic condition had a dramatic effect on the pore-size distribution, which became much narrower, indicating the occurrence of a porous system with enhanced ordering.

AB - High-quality mesoporous ethylenesilicas were prepared for the first time under acidic conditions using alkylpoly(ethylene oxide) oligomers or polyalkylene oxide triblock copolymers as supramolecular templates. Depending on the synthesis conditions, materials with medium (4-5 nm) and large (8-9 nm) mesopores were obtained. Addition of butanol in conjunction with P123 under acidic condition had a dramatic effect on the pore-size distribution, which became much narrower, indicating the occurrence of a porous system with enhanced ordering.

KW - INORGANIC NANOCOMPOSITE MATERIALS

KW - COPOLYMER-ASSISTED SYNTHESIS

KW - MOLECULAR-SCALE PERIODICITY

KW - CAGE-LIKE PORES

KW - CHANNEL WALLS

KW - MESOSTRUCTURED MATERIALS

KW - STRUCTURE DIRECTORS

KW - SILICA STRUCTURES

KW - BENZENE-SILICA

KW - ORGANIC GROUPS

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U2 - 10.1021/cm035235z

DO - 10.1021/cm035235z

M3 - Article

SN - 0897-4756

VL - 16

SP - 1756

EP - 1762

JO - Chemistry of Materials

JF - Chemistry of Materials

ER -

Synthesis of periodic mesoporous ethylenesilicas under acidic conditions

Abstract

Keywords

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