Synthesis of novel (NHC)Pd(acac)Cl complexes (acac= acetylacetonate) and their activity in cross-coupling reactions

O Navarro; N Marion; NM Scott; J Gonzalez; D Amoroso; A Bell; Steven Patrick Nolan

doi:10.1016/j.tet.2005.06.081

Synthesis of novel (NHC)Pd(acac)Cl complexes (acac= acetylacetonate) and their activity in cross-coupling reactions

O Navarro, N Marion, NM Scott, J Gonzalez, D Amoroso, A Bell, Steven Patrick Nolan

Research output: Contribution to journal › Article › peer-review

Abstract

The synthesis and characterization of two new complexes (IPr)Pd(acac)(2) (1) and (IPr)Pd(acac)CI (2) (IPr=(N,N'-bis(2,6-diisopropylphenyl)imidazol)-2-ylidene, acac = acetylacetonate) are described. Complex 2 can be prepared in a one-pot protocol in high yield. A study detailing the versatility of 2 to effectively catalyze a series of cross-coupling reactions is discussed. (c) 2005 Elsevier Ltd. All rights reserved.

Original language	English
Pages (from-to)	9716-9722
Number of pages	7
Journal	Tetrahedron
Volume	61
Issue number	41
DOIs	https://doi.org/10.1016/j.tet.2005.06.081
Publication status	Published - 10 Oct 2005

Keywords

N-heterocyclic carbenes
palladium
aryl amination
ketone arylation
N-HETEROCYCLIC CARBENE
PALLADIUM-CATALYZED AMINATION
FORMING REDUCTIVE ELIMINATION
NITROGEN BOND FORMATION
ARYL CHLORIDES
NUCLEOPHILIC CARBENES
METAL-COMPLEXES
LIGANDS
REACTIVITY
KETONES

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10.1016/j.tet.2005.06.081

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title = "Synthesis of novel (NHC)Pd(acac)Cl complexes (acac= acetylacetonate) and their activity in cross-coupling reactions",

abstract = "The synthesis and characterization of two new complexes (IPr)Pd(acac)(2) (1) and (IPr)Pd(acac)CI (2) (IPr=(N,N'-bis(2,6-diisopropylphenyl)imidazol)-2-ylidene, acac = acetylacetonate) are described. Complex 2 can be prepared in a one-pot protocol in high yield. A study detailing the versatility of 2 to effectively catalyze a series of cross-coupling reactions is discussed. (c) 2005 Elsevier Ltd. All rights reserved.",

keywords = "N-heterocyclic carbenes, palladium, aryl amination, ketone arylation, N-HETEROCYCLIC CARBENE, PALLADIUM-CATALYZED AMINATION, FORMING REDUCTIVE ELIMINATION, NITROGEN BOND FORMATION, ARYL CHLORIDES, NUCLEOPHILIC CARBENES, METAL-COMPLEXES, LIGANDS, REACTIVITY, KETONES",

author = "O Navarro and N Marion and NM Scott and J Gonzalez and D Amoroso and A Bell and Nolan, {Steven Patrick}",

year = "2005",

month = oct,

day = "10",

doi = "10.1016/j.tet.2005.06.081",

language = "English",

volume = "61",

pages = "9716--9722",

journal = "Tetrahedron",

issn = "0040-4020",

publisher = "Elsevier",

number = "41",

}

TY - JOUR

T1 - Synthesis of novel (NHC)Pd(acac)Cl complexes (acac= acetylacetonate) and their activity in cross-coupling reactions

AU - Navarro, O

AU - Marion, N

AU - Scott, NM

AU - Gonzalez, J

AU - Amoroso, D

AU - Bell, A

AU - Nolan, Steven Patrick

PY - 2005/10/10

Y1 - 2005/10/10

N2 - The synthesis and characterization of two new complexes (IPr)Pd(acac)(2) (1) and (IPr)Pd(acac)CI (2) (IPr=(N,N'-bis(2,6-diisopropylphenyl)imidazol)-2-ylidene, acac = acetylacetonate) are described. Complex 2 can be prepared in a one-pot protocol in high yield. A study detailing the versatility of 2 to effectively catalyze a series of cross-coupling reactions is discussed. (c) 2005 Elsevier Ltd. All rights reserved.

AB - The synthesis and characterization of two new complexes (IPr)Pd(acac)(2) (1) and (IPr)Pd(acac)CI (2) (IPr=(N,N'-bis(2,6-diisopropylphenyl)imidazol)-2-ylidene, acac = acetylacetonate) are described. Complex 2 can be prepared in a one-pot protocol in high yield. A study detailing the versatility of 2 to effectively catalyze a series of cross-coupling reactions is discussed. (c) 2005 Elsevier Ltd. All rights reserved.

KW - N-heterocyclic carbenes

KW - palladium

KW - aryl amination

KW - ketone arylation

KW - N-HETEROCYCLIC CARBENE

KW - PALLADIUM-CATALYZED AMINATION

KW - FORMING REDUCTIVE ELIMINATION

KW - NITROGEN BOND FORMATION

KW - ARYL CHLORIDES

KW - NUCLEOPHILIC CARBENES

KW - METAL-COMPLEXES

KW - LIGANDS

KW - REACTIVITY

KW - KETONES

UR - http://www.scopus.com/inward/record.url?scp=24344490401&partnerID=8YFLogxK

U2 - 10.1016/j.tet.2005.06.081

DO - 10.1016/j.tet.2005.06.081

M3 - Article

SN - 0040-4020

VL - 61

SP - 9716

EP - 9722

JO - Tetrahedron

JF - Tetrahedron

IS - 41

ER -

Synthesis of novel (NHC)Pd(acac)Cl complexes (acac= acetylacetonate) and their activity in cross-coupling reactions

Abstract

Keywords

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