Synthesis of new phosphino amines: their metal complexes and their applications in catalysis

M Rodriguez i Zubiri, Alexandra Martha Zoya Slawin, David John Cole-Hamilton, John Derek Woollins

Research output: Other contribution

1 Citation (Scopus)

Abstract

The compounds (C6H4O2P)(2)(NN)-N-boolean AND, (Ph2P)(2)(NN)-N-boolean AND and ((Pr2P)-Pr-i)(2)(NN)-N-boolean AND (where (NN)-N-boolean AND = homopiperazine) prepared by the condensation reaction of diamines with chlorophosphines in presence of Et3N have been tested in Rhodium catalysed hydroformylation and Palladium allylic alkylation. Also a variety of late transition metal complexes with Pt(II), Pd(II), Au(I) and Mo(0) were prepared.

Original languageEnglish
Volume168
Publication statusPublished - 2001

Keywords

  • Phosphorus-Nitrogen bond containing ligands and complexes
  • selenium
  • catalysis
  • BITE ANGLE
  • LIGANDS

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