Synthesis of N-heterocyclic carbene gold complexes using solution-phase and solid-state protocols

Jonathan Egbert; Alexandra Martha Zoya Slawin; Steven Patrick Nolan

doi:10.1021/om301187a

Synthesis of N-heterocyclic carbene gold complexes using solution-phase and solid-state protocols

Jonathan Egbert, Alexandra Martha Zoya Slawin, Steven Patrick Nolan

Research output: Contribution to journal › Article › peer-review

Abstract

Several new phenolate complexes were prepared by reacting [Au(IPr)(OH)] (IPr = 1,3-bis(2,6-di-isopropylphenyl) imidazol-2-ylidene) with phenols in solution. These complexes were also prepared by a new method. The precursor to the gold hydroxide [Au(IPr)Cl] was simply ground with KOH and the organic substrates. [Au(IPr)(R)] complexes that required heating in solution for extended periods of time were prepared using the grinding method in only minutes.

Original language	English
Pages (from-to)	2271-2274
Number of pages	4
Journal	Organometallics
Volume	32
Issue number	7
Early online date	18 Mar 2013
DOIs	https://doi.org/10.1021/om301187a
Publication status	Published - 8 Apr 2013

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10.1021/om301187a

EPSRC - EP/J011053/1- LATE TRANSITION: Late Transition Metal Hydroxide in Homogeneous Catalysis
Nolan, S. P. (PI)
EPSRC
15/03/12 → 14/03/15
Project: Standard
FUNCAT: EU FP7 ERC Advanced Grant - FUNCAT - Fundamental Studies in Organometallic Chemistry and Homogeneous Catalysis
Nolan, S. P. (PI)
European Research Council
1/01/09 → 31/12/14
Project: Standard

Cite this

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title = "Synthesis of N-heterocyclic carbene gold complexes using solution-phase and solid-state protocols",

abstract = "Several new phenolate complexes were prepared by reacting [Au(IPr)(OH)] (IPr = 1,3-bis(2,6-di-isopropylphenyl) imidazol-2-ylidene) with phenols in solution. These complexes were also prepared by a new method. The precursor to the gold hydroxide [Au(IPr)Cl] was simply ground with KOH and the organic substrates. [Au(IPr)(R)] complexes that required heating in solution for extended periods of time were prepared using the grinding method in only minutes.",

author = "Jonathan Egbert and Slawin, {Alexandra Martha Zoya} and Nolan, {Steven Patrick}",

note = "The ERC (Advanced Investigator Award FUNCAT to S.P.N.) and the EPSRC are acknowledged for support. S.P.N. is a Royal Society-Wolfson Research Merit Award holder.",

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doi = "10.1021/om301187a",

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AU - Egbert, Jonathan

AU - Slawin, Alexandra Martha Zoya

AU - Nolan, Steven Patrick

N1 - The ERC (Advanced Investigator Award FUNCAT to S.P.N.) and the EPSRC are acknowledged for support. S.P.N. is a Royal Society-Wolfson Research Merit Award holder.

PY - 2013/4/8

Y1 - 2013/4/8

N2 - Several new phenolate complexes were prepared by reacting [Au(IPr)(OH)] (IPr = 1,3-bis(2,6-di-isopropylphenyl) imidazol-2-ylidene) with phenols in solution. These complexes were also prepared by a new method. The precursor to the gold hydroxide [Au(IPr)Cl] was simply ground with KOH and the organic substrates. [Au(IPr)(R)] complexes that required heating in solution for extended periods of time were prepared using the grinding method in only minutes.

AB - Several new phenolate complexes were prepared by reacting [Au(IPr)(OH)] (IPr = 1,3-bis(2,6-di-isopropylphenyl) imidazol-2-ylidene) with phenols in solution. These complexes were also prepared by a new method. The precursor to the gold hydroxide [Au(IPr)Cl] was simply ground with KOH and the organic substrates. [Au(IPr)(R)] complexes that required heating in solution for extended periods of time were prepared using the grinding method in only minutes.

U2 - 10.1021/om301187a

DO - 10.1021/om301187a

M3 - Article

SN - 0276-7333

VL - 32

SP - 2271

EP - 2274

JO - Organometallics

JF - Organometallics

IS - 7

ER -

Synthesis of N-heterocyclic carbene gold complexes using solution-phase and solid-state protocols

Abstract

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Projects

EPSRC - EP/J011053/1- LATE TRANSITION: Late Transition Metal Hydroxide in Homogeneous Catalysis

FUNCAT: EU FP7 ERC Advanced Grant - FUNCAT - Fundamental Studies in Organometallic Chemistry and Homogeneous Catalysis

Cite this