Synthesis of homoleptic and heteroleptic bis-N-heterocylic carbene group 11 complexes

F. Lazreg; D.B. Cordes; A.M.Z. Slawin; C.S.J. Cazin

doi:10.1021/om500882t

Synthesis of homoleptic and heteroleptic bis-N-heterocylic carbene group 11 complexes

F. Lazreg, D.B. Cordes, A.M.Z. Slawin, C.S.J. Cazin

Research output: Contribution to journal › Article › peer-review

Abstract

A straightforward synthetic route has been developed permitting the formation of homoleptic and heteroleptic bis-N-heterocyclic carbene metal complexes. The methodology has proven efficient for all group 11 members. These complexes are easily synthesized using [M(Cl)(NHC)] with different NHC salts in the presence of inexpensive bases such as sodium hydroxide. These systems were fully characterized and displayed high stability even in the presence of light.

Original language	English
Pages (from-to)	419-425
Number of pages	7
Journal	Organometallics
Volume	34
Issue number	2
Early online date	8 Jan 2015
DOIs	https://doi.org/10.1021/om500882t
Publication status	Published - 26 Jan 2015

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10.1021/om500882t

Structuring the Future: Structuring the Future - Underpinning world-leading science in EaStCHEM through cutting edge characterisation
Woollins, J. D. (PI), Ashbrook, S. E. (CoI), Morris, R. E. (CoI) & Slawin, A. M. Z. (CoI)
EPSRC
1/01/13 → 31/03/13
Project: Standard

Synthesis of homoleptic and heteroleptic bis-N-heterocylic carbene group 11 complexes
Lazreg, F. (Creator), Cordes, D. B. (Creator), Slawin, A. M. Z. (Creator) & Cazin, C. S. J. (Creator), Cambridge Crystallographic Data Centre, 2015
https://dx.doi.org/10.5517/cc11yyfc and 9 more links, https://dx.doi.org/10.5517/cc11yyb8, https://dx.doi.org/10.5517/cc11yydb, https://dx.doi.org/10.5517/cc11yy97, https://dx.doi.org/10.5517/cc11yyc9, https://dx.doi.org/10.5517/cc11yygd, https://dx.doi.org/10.5517/cc11yyhf, https://dx.doi.org/10.5517/cc11y9x6, https://dx.doi.org/10.5517/cc11y9y7, https://dx.doi.org/10.5517/cc11yyjg (show fewer)
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title = "Synthesis of homoleptic and heteroleptic bis-N-heterocylic carbene group 11 complexes",

abstract = "A straightforward synthetic route has been developed permitting the formation of homoleptic and heteroleptic bis-N-heterocyclic carbene metal complexes. The methodology has proven efficient for all group 11 members. These complexes are easily synthesized using [M(Cl)(NHC)] with different NHC salts in the presence of inexpensive bases such as sodium hydroxide. These systems were fully characterized and displayed high stability even in the presence of light.",

author = "F. Lazreg and D.B. Cordes and A.M.Z. Slawin and C.S.J. Cazin",

note = "The authors gratefully acknowledge the Royal Society (University Research Fellowship to C.S.J.C.) for funding.",

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doi = "10.1021/om500882t",

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AU - Lazreg, F.

AU - Cordes, D.B.

AU - Slawin, A.M.Z.

AU - Cazin, C.S.J.

N1 - The authors gratefully acknowledge the Royal Society (University Research Fellowship to C.S.J.C.) for funding.

PY - 2015/1/26

Y1 - 2015/1/26

N2 - A straightforward synthetic route has been developed permitting the formation of homoleptic and heteroleptic bis-N-heterocyclic carbene metal complexes. The methodology has proven efficient for all group 11 members. These complexes are easily synthesized using [M(Cl)(NHC)] with different NHC salts in the presence of inexpensive bases such as sodium hydroxide. These systems were fully characterized and displayed high stability even in the presence of light.

AB - A straightforward synthetic route has been developed permitting the formation of homoleptic and heteroleptic bis-N-heterocyclic carbene metal complexes. The methodology has proven efficient for all group 11 members. These complexes are easily synthesized using [M(Cl)(NHC)] with different NHC salts in the presence of inexpensive bases such as sodium hydroxide. These systems were fully characterized and displayed high stability even in the presence of light.

U2 - 10.1021/om500882t

DO - 10.1021/om500882t

M3 - Article

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JO - Organometallics

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Synthesis of homoleptic and heteroleptic bis-N-heterocylic carbene group 11 complexes

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Structuring the Future: Structuring the Future - Underpinning world-leading science in EaStCHEM through cutting edge characterisation

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Synthesis of homoleptic and heteroleptic bis-N-heterocylic carbene group 11 complexes

Cite this