Synthesis of Hg(NSO)2 in Liquid Ammonia

RJ Reynolds; John Derek Woollins

Synthesis of Hg(NSO)₂ in Liquid Ammonia

RJ Reynolds, John Derek Woollins

Research output: Other contribution

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Abstract

The reaction of thionyl chloride with liquid ammonia produces the thionyl imide anion,NSO- Addition of metal chloride bis-phosphine complexes such as [PtCl2(PMe3)(2)] the resulting NH3(I) solution has been shown to produce compounds of the type [Pt(NSO)(2)(PMe3)(2)].([1]) Here, we describe the synthesis of Hg(NSO)(2) in liquid ammonia, using HgCl2 as the starting material.

Original language	English
Volume	125
Publication status	Published - 1997

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title = "Synthesis of Hg(NSO)2 in Liquid Ammonia",

abstract = "The reaction of thionyl chloride with liquid ammonia produces the thionyl imide anion,NSO- Addition of metal chloride bis-phosphine complexes such as [PtCl2(PMe3)(2)] the resulting NH3(I) solution has been shown to produce compounds of the type [Pt(NSO)(2)(PMe3)(2)].([1]) Here, we describe the synthesis of Hg(NSO)(2) in liquid ammonia, using HgCl2 as the starting material.",

author = "RJ Reynolds and Woollins, {John Derek}",

note = "Phosphorus, Sulfur, Silicon",

year = "1997",

language = "English",

volume = "125",

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TY - GEN

T1 - Synthesis of Hg(NSO)2 in Liquid Ammonia

AU - Reynolds, RJ

AU - Woollins, John Derek

N1 - Phosphorus, Sulfur, Silicon

PY - 1997

Y1 - 1997

N2 - The reaction of thionyl chloride with liquid ammonia produces the thionyl imide anion,NSO- Addition of metal chloride bis-phosphine complexes such as [PtCl2(PMe3)(2)] the resulting NH3(I) solution has been shown to produce compounds of the type [Pt(NSO)(2)(PMe3)(2)].([1]) Here, we describe the synthesis of Hg(NSO)(2) in liquid ammonia, using HgCl2 as the starting material.

AB - The reaction of thionyl chloride with liquid ammonia produces the thionyl imide anion,NSO- Addition of metal chloride bis-phosphine complexes such as [PtCl2(PMe3)(2)] the resulting NH3(I) solution has been shown to produce compounds of the type [Pt(NSO)(2)(PMe3)(2)].([1]) Here, we describe the synthesis of Hg(NSO)(2) in liquid ammonia, using HgCl2 as the starting material.

UR - http://www.scopus.com/inward/record.url?scp=0347073612&partnerID=8YFLogxK

M3 - Other contribution

VL - 125

ER -

Synthesis of Hg(NSO)₂ in Liquid Ammonia

Abstract

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