Synthesis of FeAPO-34 molecular sieve under ionothermal condition

Mazlina Musa; Daniel M. Dawson; Russell E. Morris; Sharon E. Ashbrook

doi:10.1021/acs.inorgchem.2c02352

Synthesis of FeAPO-34 molecular sieve under ionothermal condition

Mazlina Musa^*, Daniel M. Dawson, Russell E. Morris, Sharon E. Ashbrook

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

Abstract

FeAPO-34 with chabazite (CHA) topology structure was successfully synthesized under ionothermal conditions using 1-ethyl-3-methylimidazoliumchloride (EMIMCl) ionic liquid in the presence of ethylenediamine (EDA). The material was characterised using powder Xray Diffraction (XRD), thermogravimetric analysis (TGA), elemental analyses and solid-state NMR spectroscopy. Incorporation of iron within the covalent framework of the material was confirmed by the presence of broad signals between 1000 and 14000 ppm in the ³¹P NMR spectrum, corresponding to P(OFe)_x(OAl)_4–x species.

Original language	English
Pages (from-to)	16685-16692
Number of pages	8
Journal	Inorganic Chemistry
Volume	61
Issue number	42
Early online date	10 Oct 2022
DOIs	https://doi.org/10.1021/acs.inorgchem.2c02352
Publication status	Published - 24 Oct 2022

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Copyright © 2022 American Chemical Society. This work has been made available online in accordance with publisher policies or with permission. Permission for further reuse of this content should be sought from the publisher or the rights holder. This is the author created accepted manuscript following peer review and may differ slightly from the final published version. The final published version of this work is available at https://doi.org/10.1021/acs.inorgchem.2c02352
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Data underpinning: "Synthesis of FeAPO-34 Molecular Sieve under Ionothermal Condition"
Musa, M. (Creator), Dawson, D. M. (Creator), Morris, R. E. (Creator) & Ashbrook, S. E. (Creator), University of St Andrews, 9 Nov 2022
DOI: 10.17630/d409a295-fe4d-4a2f-88ea-4c4a52f9004d
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abstract = "FeAPO-34 with chabazite (CHA) topology structure was successfully synthesized under ionothermal conditions using 1-ethyl-3-methylimidazoliumchloride (EMIMCl) ionic liquid in the presence of ethylenediamine (EDA). The material was characterised using powder Xray Diffraction (XRD), thermogravimetric analysis (TGA), elemental analyses and solid-state NMR spectroscopy. Incorporation of iron within the covalent framework of the material was confirmed by the presence of broad signals between 1000 and 14000 ppm in the 31P NMR spectrum, corresponding to P(OFe)x(OAl)4–x species.",

author = "Mazlina Musa and Dawson, {Daniel M.} and Morris, {Russell E.} and Ashbrook, {Sharon E.}",

year = "2022",

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doi = "10.1021/acs.inorgchem.2c02352",

language = "English",

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T1 - Synthesis of FeAPO-34 molecular sieve under ionothermal condition

AU - Musa, Mazlina

AU - Dawson, Daniel M.

AU - Morris, Russell E.

AU - Ashbrook, Sharon E.

PY - 2022/10/24

Y1 - 2022/10/24

N2 - FeAPO-34 with chabazite (CHA) topology structure was successfully synthesized under ionothermal conditions using 1-ethyl-3-methylimidazoliumchloride (EMIMCl) ionic liquid in the presence of ethylenediamine (EDA). The material was characterised using powder Xray Diffraction (XRD), thermogravimetric analysis (TGA), elemental analyses and solid-state NMR spectroscopy. Incorporation of iron within the covalent framework of the material was confirmed by the presence of broad signals between 1000 and 14000 ppm in the 31P NMR spectrum, corresponding to P(OFe)x(OAl)4–x species.

AB - FeAPO-34 with chabazite (CHA) topology structure was successfully synthesized under ionothermal conditions using 1-ethyl-3-methylimidazoliumchloride (EMIMCl) ionic liquid in the presence of ethylenediamine (EDA). The material was characterised using powder Xray Diffraction (XRD), thermogravimetric analysis (TGA), elemental analyses and solid-state NMR spectroscopy. Incorporation of iron within the covalent framework of the material was confirmed by the presence of broad signals between 1000 and 14000 ppm in the 31P NMR spectrum, corresponding to P(OFe)x(OAl)4–x species.

U2 - 10.1021/acs.inorgchem.2c02352

DO - 10.1021/acs.inorgchem.2c02352

M3 - Article

SN - 0020-1669

VL - 61

SP - 16685

EP - 16692

JO - Inorganic Chemistry

JF - Inorganic Chemistry

IS - 42

ER -

Synthesis of FeAPO-34 molecular sieve under ionothermal condition

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Data underpinning: "Synthesis of FeAPO-34 Molecular Sieve under Ionothermal Condition"

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