Synthesis of cyclic Imides by acceptorless dehydrogenative coupling of diols and amines catalyzed by a manganese pincer complex

Noel A Espinosa-Jalapa; Amit Kumar; Gregory Leitus; Yael Diskin-Posner; David Milstein

doi:10.1021/jacs.7b08341

Synthesis of cyclic Imides by acceptorless dehydrogenative coupling of diols and amines catalyzed by a manganese pincer complex

Noel A Espinosa-Jalapa, Amit Kumar, Gregory Leitus, Yael Diskin-Posner, David Milstein

School of Chemistry

Research output: Contribution to journal › Article › peer-review

Abstract

The first example of base-metal-catalyzed dehydrogenative coupling of diols and amines to form cyclic imides is reported. The reaction is catalyzed by a pincer complex of the earth abundant manganese and forms hydrogen gas as the sole byproduct, making the overall process atom economical and environmentally benign.

Original language	English
Pages (from-to)	11722–11725
Journal	Journal of the American Chemical Society
Volume	139
Issue number	34
Early online date	10 Aug 2017
DOIs	https://doi.org/10.1021/jacs.7b08341
Publication status	Published - 30 Aug 2017

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title = "Synthesis of cyclic Imides by acceptorless dehydrogenative coupling of diols and amines catalyzed by a manganese pincer complex",

abstract = "The first example of base-metal-catalyzed dehydrogenative coupling of diols and amines to form cyclic imides is reported. The reaction is catalyzed by a pincer complex of the earth abundant manganese and forms hydrogen gas as the sole byproduct, making the overall process atom economical and environmentally benign.",

author = "Espinosa-Jalapa, \{Noel A\} and Amit Kumar and Gregory Leitus and Yael Diskin-Posner and David Milstein",

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T1 - Synthesis of cyclic Imides by acceptorless dehydrogenative coupling of diols and amines catalyzed by a manganese pincer complex

AU - Espinosa-Jalapa, Noel A

AU - Kumar, Amit

AU - Leitus, Gregory

AU - Diskin-Posner, Yael

AU - Milstein, David

PY - 2017/8/30

Y1 - 2017/8/30

N2 - The first example of base-metal-catalyzed dehydrogenative coupling of diols and amines to form cyclic imides is reported. The reaction is catalyzed by a pincer complex of the earth abundant manganese and forms hydrogen gas as the sole byproduct, making the overall process atom economical and environmentally benign.

AB - The first example of base-metal-catalyzed dehydrogenative coupling of diols and amines to form cyclic imides is reported. The reaction is catalyzed by a pincer complex of the earth abundant manganese and forms hydrogen gas as the sole byproduct, making the overall process atom economical and environmentally benign.

UR - https://www.scopus.com/pages/publications/85028685210

U2 - 10.1021/jacs.7b08341

DO - 10.1021/jacs.7b08341

M3 - Article

SN - 0002-7863

VL - 139

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JO - Journal of the American Chemical Society

JF - Journal of the American Chemical Society

IS - 34

ER -

Synthesis of cyclic Imides by acceptorless dehydrogenative coupling of diols and amines catalyzed by a manganese pincer complex

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Amit Kumar

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Synthesis of cyclic Imides by acceptorless dehydrogenative coupling of diols and amines catalyzed by a manganese pincer complex

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