Synthesis of cyclic Imides by acceptorless dehydrogenative coupling of diols and amines catalyzed by a manganese pincer complex

Noel A Espinosa-Jalapa; Amit Kumar; Gregory Leitus; Yael Diskin-Posner; David Milstein

doi:10.1021/jacs.7b08341

Synthesis of cyclic Imides by acceptorless dehydrogenative coupling of diols and amines catalyzed by a manganese pincer complex

Noel A Espinosa-Jalapa, Amit Kumar, Gregory Leitus, Yael Diskin-Posner, David Milstein

School of Chemistry

Research output: Contribution to journal › Article › peer-review

Abstract

The first example of base-metal-catalyzed dehydrogenative coupling of diols and amines to form cyclic imides is reported. The reaction is catalyzed by a pincer complex of the earth abundant manganese and forms hydrogen gas as the sole byproduct, making the overall process atom economical and environmentally benign.

Original language	English
Pages (from-to)	11722–11725
Journal	Journal of the American Chemical Society
Volume	139
Issue number	34
Early online date	10 Aug 2017
DOIs	https://doi.org/10.1021/jacs.7b08341
Publication status	Published - 30 Aug 2017

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10.1021/jacs.7b08341

Amit Kumar
- ak336st-andrews.acuk
- School of Chemistry - Principal Research Fellow
Person: Academic - Research

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title = "Synthesis of cyclic Imides by acceptorless dehydrogenative coupling of diols and amines catalyzed by a manganese pincer complex",

abstract = "The first example of base-metal-catalyzed dehydrogenative coupling of diols and amines to form cyclic imides is reported. The reaction is catalyzed by a pincer complex of the earth abundant manganese and forms hydrogen gas as the sole byproduct, making the overall process atom economical and environmentally benign.",

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AU - Espinosa-Jalapa, Noel A

AU - Kumar, Amit

AU - Leitus, Gregory

AU - Diskin-Posner, Yael

AU - Milstein, David

PY - 2017/8/30

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AB - The first example of base-metal-catalyzed dehydrogenative coupling of diols and amines to form cyclic imides is reported. The reaction is catalyzed by a pincer complex of the earth abundant manganese and forms hydrogen gas as the sole byproduct, making the overall process atom economical and environmentally benign.

U2 - 10.1021/jacs.7b08341

DO - 10.1021/jacs.7b08341

M3 - Article

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JO - Journal of the American Chemical Society

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Synthesis of cyclic Imides by acceptorless dehydrogenative coupling of diols and amines catalyzed by a manganese pincer complex

Abstract

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