Synthesis of a new Cu3S3 heterocycle

David J. Birdsall; Dominico Cupertino; J. Derek Woollins; Alexandra M.Z. Slawin

doi:10.1080/10426509708545660

Synthesis of a new Cu₃S₃ heterocycle

David J. Birdsall^*
, Dominico Cupertino
, J. Derek Woollins
, Alexandra M.Z. Slawin

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

Abstract

We report on the formation of a Cu₃S₃ heterocycle from the reaction of copper(II) bromide and the ligand [NH(ⁱPr₂PS)₂] bis(diisopropyldithiophosphino)amine. The single crystal X-ray structure and other spectroscopic details are presented. The molecule exists as a six membered ring which displays a single peak in its solution ³¹P NMR though different phosphorus environments are evident in the solid state.

Original language	English
Pages (from-to)	465-468
Number of pages	4
Journal	Phosphorus, Sulfur and Silicon and Related Elements
Volume	124
DOIs	https://doi.org/10.1080/10426509708545660
Publication status	Published - 1 Jan 1997

Keywords

Copper
Heterocycle
Sulfur

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Cite this

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title = "Synthesis of a new Cu3S3 heterocycle",

abstract = "We report on the formation of a Cu3S3 heterocycle from the reaction of copper(II) bromide and the ligand [NH(iPr2PS)2] bis(diisopropyldithiophosphino)amine. The single crystal X-ray structure and other spectroscopic details are presented. The molecule exists as a six membered ring which displays a single peak in its solution 31P NMR though different phosphorus environments are evident in the solid state.",

keywords = "Copper, Heterocycle, Sulfur",

author = "Birdsall, \{David J.\} and Dominico Cupertino and Woollins, \{J. Derek\} and Slawin, \{Alexandra M.Z.\}",

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journal = "Phosphorus, Sulfur and Silicon and Related Elements",

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T1 - Synthesis of a new Cu3S3 heterocycle

AU - Birdsall, David J.

AU - Cupertino, Dominico

AU - Woollins, J. Derek

AU - Slawin, Alexandra M.Z.

PY - 1997/1/1

Y1 - 1997/1/1

N2 - We report on the formation of a Cu3S3 heterocycle from the reaction of copper(II) bromide and the ligand [NH(iPr2PS)2] bis(diisopropyldithiophosphino)amine. The single crystal X-ray structure and other spectroscopic details are presented. The molecule exists as a six membered ring which displays a single peak in its solution 31P NMR though different phosphorus environments are evident in the solid state.

AB - We report on the formation of a Cu3S3 heterocycle from the reaction of copper(II) bromide and the ligand [NH(iPr2PS)2] bis(diisopropyldithiophosphino)amine. The single crystal X-ray structure and other spectroscopic details are presented. The molecule exists as a six membered ring which displays a single peak in its solution 31P NMR though different phosphorus environments are evident in the solid state.

KW - Copper

KW - Heterocycle

KW - Sulfur

UR - https://www.scopus.com/pages/publications/0347704204

U2 - 10.1080/10426509708545660

DO - 10.1080/10426509708545660

M3 - Article

AN - SCOPUS:0347704204

SN - 1042-6507

VL - 124

SP - 465

EP - 468

JO - Phosphorus, Sulfur and Silicon and Related Elements

JF - Phosphorus, Sulfur and Silicon and Related Elements

ER -