Synthesis of a family of aluminium benzylphosphonates

N Zakowsky, GB Hix, Russell Edward Morris

Research output: Contribution to journalArticlepeer-review

20 Citations (Scopus)

Abstract

A family of four aluminium benzylphosphonate phases has been synthesised using hydrothermal methods. The effect of changing the synthetic conditions (starting pH, starting Al : P ratio, aluminium source etc.) has been studied and full structural characterisation of two of the phases by NMR, TGA and X-ray diffraction methods has been completed; Al(OH)(O3PCH2C6H5). H2O, monoclinic P2(1)/c, a = 14.985(9), b = 7.066(5), c = 9.613(9) Angstrom, beta = 113.9(3)degrees, and Al3H(PO3CH2C6H5)(5). H2O, monoclinic P2(1)/c, a = 17.2497(13), b = 25.7851(18), c = 9.4339(7) Angstrom, beta = 103.567(1)degrees.

Original languageEnglish
Pages (from-to)2375-2380
Number of pages6
JournalJournal of Materials Chemistry
Volume10
Publication statusPublished - 2000

Keywords

  • METAL PHOSPHONATES
  • STRUCTURAL CHARACTERIZATION
  • UNIDIMENSIONAL CHANNELS
  • ZIRCONIUM-PHOSPHATE
  • ALMEPO-ALPHA
  • PHENYLPHOSPHONATES
  • METHYLPHOSPHONATE
  • ARRANGEMENT
  • CALCIUM
  • BETA

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