Synthesis of a family of aluminium benzylphosphonates

N Zakowsky; GB Hix; Russell Edward Morris

Synthesis of a family of aluminium benzylphosphonates

N Zakowsky, GB Hix, Russell Edward Morris

Research output: Contribution to journal › Article › peer-review

Abstract

A family of four aluminium benzylphosphonate phases has been synthesised using hydrothermal methods. The effect of changing the synthetic conditions (starting pH, starting Al : P ratio, aluminium source etc.) has been studied and full structural characterisation of two of the phases by NMR, TGA and X-ray diffraction methods has been completed; Al(OH)(O3PCH2C6H5). H2O, monoclinic P2(1)/c, a = 14.985(9), b = 7.066(5), c = 9.613(9) Angstrom, beta = 113.9(3)degrees, and Al3H(PO3CH2C6H5)(5). H2O, monoclinic P2(1)/c, a = 17.2497(13), b = 25.7851(18), c = 9.4339(7) Angstrom, beta = 103.567(1)degrees.

Original language	English
Pages (from-to)	2375-2380
Number of pages	6
Journal	Journal of Materials Chemistry
Volume	10
Publication status	Published - 2000

Keywords

METAL PHOSPHONATES
STRUCTURAL CHARACTERIZATION
UNIDIMENSIONAL CHANNELS
ZIRCONIUM-PHOSPHATE
ALMEPO-ALPHA
PHENYLPHOSPHONATES
METHYLPHOSPHONATE
ARRANGEMENT
CALCIUM
BETA

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@article{a3167752a40b407dba9fcb31f81f4a92,

title = "Synthesis of a family of aluminium benzylphosphonates",

abstract = "A family of four aluminium benzylphosphonate phases has been synthesised using hydrothermal methods. The effect of changing the synthetic conditions (starting pH, starting Al : P ratio, aluminium source etc.) has been studied and full structural characterisation of two of the phases by NMR, TGA and X-ray diffraction methods has been completed; Al(OH)(O3PCH2C6H5). H2O, monoclinic P2(1)/c, a = 14.985(9), b = 7.066(5), c = 9.613(9) Angstrom, beta = 113.9(3)degrees, and Al3H(PO3CH2C6H5)(5). H2O, monoclinic P2(1)/c, a = 17.2497(13), b = 25.7851(18), c = 9.4339(7) Angstrom, beta = 103.567(1)degrees.",

keywords = "METAL PHOSPHONATES, STRUCTURAL CHARACTERIZATION, UNIDIMENSIONAL CHANNELS, ZIRCONIUM-PHOSPHATE, ALMEPO-ALPHA, PHENYLPHOSPHONATES, METHYLPHOSPHONATE, ARRANGEMENT, CALCIUM, BETA",

author = "N Zakowsky and GB Hix and Morris, {Russell Edward}",

year = "2000",

language = "English",

volume = "10",

pages = "2375--2380",

journal = "Journal of Materials Chemistry",

issn = "0959-9428",

publisher = "Royal Society of Chemistry",

}

TY - JOUR

T1 - Synthesis of a family of aluminium benzylphosphonates

AU - Zakowsky, N

AU - Hix, GB

AU - Morris, Russell Edward

PY - 2000

Y1 - 2000

N2 - A family of four aluminium benzylphosphonate phases has been synthesised using hydrothermal methods. The effect of changing the synthetic conditions (starting pH, starting Al : P ratio, aluminium source etc.) has been studied and full structural characterisation of two of the phases by NMR, TGA and X-ray diffraction methods has been completed; Al(OH)(O3PCH2C6H5). H2O, monoclinic P2(1)/c, a = 14.985(9), b = 7.066(5), c = 9.613(9) Angstrom, beta = 113.9(3)degrees, and Al3H(PO3CH2C6H5)(5). H2O, monoclinic P2(1)/c, a = 17.2497(13), b = 25.7851(18), c = 9.4339(7) Angstrom, beta = 103.567(1)degrees.

AB - A family of four aluminium benzylphosphonate phases has been synthesised using hydrothermal methods. The effect of changing the synthetic conditions (starting pH, starting Al : P ratio, aluminium source etc.) has been studied and full structural characterisation of two of the phases by NMR, TGA and X-ray diffraction methods has been completed; Al(OH)(O3PCH2C6H5). H2O, monoclinic P2(1)/c, a = 14.985(9), b = 7.066(5), c = 9.613(9) Angstrom, beta = 113.9(3)degrees, and Al3H(PO3CH2C6H5)(5). H2O, monoclinic P2(1)/c, a = 17.2497(13), b = 25.7851(18), c = 9.4339(7) Angstrom, beta = 103.567(1)degrees.

KW - METAL PHOSPHONATES

KW - STRUCTURAL CHARACTERIZATION

KW - UNIDIMENSIONAL CHANNELS

KW - ZIRCONIUM-PHOSPHATE

KW - ALMEPO-ALPHA

KW - PHENYLPHOSPHONATES

KW - METHYLPHOSPHONATE

KW - ARRANGEMENT

KW - CALCIUM

KW - BETA

UR - http://www.scopus.com/inward/record.url?scp=0033775995&partnerID=8YFLogxK

M3 - Article

SN - 0959-9428

VL - 10

SP - 2375

EP - 2380

JO - Journal of Materials Chemistry

JF - Journal of Materials Chemistry

ER -

Synthesis of a family of aluminium benzylphosphonates

Abstract

Keywords

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