Synthesis of a D-3-symmetric "trefoil" knotted cyclophane

Karla I. Arias; Eli Zysman-Colman; Jon C. Loren; Anthony Linden; Jay S. Siegel

doi:10.1039/c1cc11209k

Synthesis of a D-3-symmetric "trefoil" knotted cyclophane

Karla I. Arias
, Eli Zysman-Colman
, Jon C. Loren
, Anthony Linden
, Jay S. Siegel^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

Abstract

A D-3-symmetric knotted cyclophane, with a subgraph of trefoil topology, was synthesized by cyclization of a D-3-symmetric scaffold. Control of configuration at the three metal-based stereocenters arises from a bascule/pivot mechanism.

Original language	English
Pages (from-to)	9588-9590
Number of pages	3
Journal	Chemical Communications
Volume	47
Issue number	34
DOIs	https://doi.org/10.1039/c1cc11209k
Publication status	Published - 2011

Keywords

SINGLE-STRANDED-DNA
MOLECULAR KNOTS
ABSOLUTE-CONFIGURATION
PROTEIN
PALLADIUM
COPPER(I)
STEREOCHEMISTRY
RECOMBINATION
DERIVATIVES
PRECURSOR

Access to Document

10.1039/c1cc11209k

Handle.net

Persistent link to portal record

Cite this

@article{837fb0d24332481a80943c67b0f5dfe8,

title = "Synthesis of a D-3-symmetric {"}trefoil{"} knotted cyclophane",

abstract = "A D-3-symmetric knotted cyclophane, with a subgraph of trefoil topology, was synthesized by cyclization of a D-3-symmetric scaffold. Control of configuration at the three metal-based stereocenters arises from a bascule/pivot mechanism.",

keywords = "SINGLE-STRANDED-DNA, MOLECULAR KNOTS, ABSOLUTE-CONFIGURATION, PROTEIN, PALLADIUM, COPPER(I), STEREOCHEMISTRY, RECOMBINATION, DERIVATIVES, PRECURSOR",

author = "Arias, \{Karla I.\} and Eli Zysman-Colman and Loren, \{Jon C.\} and Anthony Linden and Siegel, \{Jay S.\}",

year = "2011",

doi = "10.1039/c1cc11209k",

language = "English",

volume = "47",

pages = "9588--9590",

journal = "Chemical Communications",

issn = "1359-7345",

publisher = "Royal Society of Chemistry",

number = "34",

}

TY - JOUR

T1 - Synthesis of a D-3-symmetric "trefoil" knotted cyclophane

AU - Arias, Karla I.

AU - Zysman-Colman, Eli

AU - Loren, Jon C.

AU - Linden, Anthony

AU - Siegel, Jay S.

PY - 2011

Y1 - 2011

N2 - A D-3-symmetric knotted cyclophane, with a subgraph of trefoil topology, was synthesized by cyclization of a D-3-symmetric scaffold. Control of configuration at the three metal-based stereocenters arises from a bascule/pivot mechanism.

AB - A D-3-symmetric knotted cyclophane, with a subgraph of trefoil topology, was synthesized by cyclization of a D-3-symmetric scaffold. Control of configuration at the three metal-based stereocenters arises from a bascule/pivot mechanism.

KW - SINGLE-STRANDED-DNA

KW - MOLECULAR KNOTS

KW - ABSOLUTE-CONFIGURATION

KW - PROTEIN

KW - PALLADIUM

KW - COPPER(I)

KW - STEREOCHEMISTRY

KW - RECOMBINATION

KW - DERIVATIVES

KW - PRECURSOR

U2 - 10.1039/c1cc11209k

DO - 10.1039/c1cc11209k

M3 - Article

SN - 1359-7345

VL - 47

SP - 9588

EP - 9590

JO - Chemical Communications

JF - Chemical Communications

IS - 34

ER -

Synthesis of a D-3-symmetric "trefoil" knotted cyclophane

Abstract

Keywords

Access to Document

Handle.net

Fingerprint

Cite this