Synthesis of a D-3-symmetric "trefoil" knotted cyclophane

Karla I. Arias, Eli Zysman-Colman, Jon C. Loren, Anthony Linden, Jay S. Siegel*

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

32 Citations (Scopus)

Abstract

A D-3-symmetric knotted cyclophane, with a subgraph of trefoil topology, was synthesized by cyclization of a D-3-symmetric scaffold. Control of configuration at the three metal-based stereocenters arises from a bascule/pivot mechanism.

Original languageEnglish
Pages (from-to)9588-9590
Number of pages3
JournalChemical Communications
Volume47
Issue number34
DOIs
Publication statusPublished - 2011

Keywords

  • SINGLE-STRANDED-DNA
  • MOLECULAR KNOTS
  • ABSOLUTE-CONFIGURATION
  • PROTEIN
  • PALLADIUM
  • COPPER(I)
  • STEREOCHEMISTRY
  • RECOMBINATION
  • DERIVATIVES
  • PRECURSOR

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