Synthesis, characterization, and structures of zinc(II) and cadmium(II) complexes with phosphoramides bearing cyclic amino groups

Mohamed M’haiham; Khaled Ebeid; Fatimetou Ebnou; Cameron L. Carpenter-Warren; Alexandra M. Z. Slawin; John Derek Woollins; Med Taieb Ben Dhia; Med Abderrahmane K. Sanhoury

doi:10.1080/00958972.2020.1731485

Synthesis, characterization, and structures of zinc(II) and cadmium(II) complexes with phosphoramides bearing cyclic amino groups

Mohamed M’haiham, Khaled Ebeid, Fatimetou Ebnou, Cameron L. Carpenter-Warren, Alexandra M. Z. Slawin, John Derek Woollins, Med Taieb Ben Dhia, Med Abderrahmane K. Sanhoury

Research output: Contribution to journal › Article › peer-review

4 Citations (Scopus)

Abstract

Twelve new zinc(II) and cadmium(II) complexes with symmetric ligands, [MCl₂((R₂N)₃PO)₂] (M = Zn, R₂N = pyrrolidinyl (1), piperidinyl (2); M = Cd, R₂N = pyrrolidinyl (3), piperidinyl (4)), and differently substituted ligands of the general formula [MCl₂(R₂N)PO(R’₂N)₂] (M = Zn or Cd; R₂N = Pyrr, Pip or Mor; R’₂N = Pyrr, Pip or Mor (5–12) have been synthesized from reaction of zinc(II) or cadmium(II) chlorides with the ligands, giving yields of 43–76%. The complexes were characterized with multinuclear (¹H, ¹³C and ³¹P) NMR, conductivity, IR spectroscopy, and X-ray analyses. Complexes 1, 3, 11, and 12 are comprised of two ligands coordinated to the metal center in a distorted monomeric tetrahedral arrangement. The P = O bond lengths of 1.490(3) (1), 1.497(4) (3), 1.480(4) (11), and 1.479(5) Å (12) are in the order observed for analogous phosphoramide complexes. The results are compared with those reported for related chalcogen counterparts.

Original language	English
Pages (from-to)	1-14
Number of pages	14
Journal	Journal of Coordination Chemistry
Early online date	28 Feb 2020
DOIs	https://doi.org/10.1080/00958972.2020.1731485
Publication status	E-pub ahead of print - 28 Feb 2020

Keywords

Phosphoramides
Zinc(II)
Cadmium(II)
Metal complex
NMR
X-ray analysis

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10.1080/00958972.2020.1731485

Synthesis, characterization, and structures of zinc(II) and cadmium(II) complexes (dataset)
Carpenter-Warren, C. L. (Creator), Slawin, A. M. Z. (Creator) & Woollins, J. D. (Creator), Cambridge Crystallographic Data Centre, 2020
https://dx.doi.org/10.5517/ccdc.csd.cc23hckk and 3 more links, https://dx.doi.org/10.5517/ccdc.csd.cc23hcll, https://dx.doi.org/10.5517/ccdc.csd.cc23hcmm, https://dx.doi.org/10.5517/ccdc.csd.cc23hcnn (show fewer)
Dataset

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M’haiham, M., Ebeid, K., Ebnou, F., Carpenter-Warren, C. L., Slawin, A. M. Z., Woollins, J. D., Ben Dhia, M. T., & Sanhoury, M. A. K. (2020). Synthesis, characterization, and structures of zinc(II) and cadmium(II) complexes with phosphoramides bearing cyclic amino groups. Journal of Coordination Chemistry, 1-14. Advance online publication. https://doi.org/10.1080/00958972.2020.1731485

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title = "Synthesis, characterization, and structures of zinc(II) and cadmium(II) complexes with phosphoramides bearing cyclic amino groups",

abstract = "Twelve new zinc(II) and cadmium(II) complexes with symmetric ligands, [MCl2((R2N)3PO)2] (M = Zn, R2N = pyrrolidinyl (1), piperidinyl (2); M = Cd, R2N = pyrrolidinyl (3), piperidinyl (4)), and differently substituted ligands of the general formula [MCl2(R2N)PO(R{\textquoteright}2N)2] (M = Zn or Cd; R2N = Pyrr, Pip or Mor; R{\textquoteright}2N = Pyrr, Pip or Mor (5–12) have been synthesized from reaction of zinc(II) or cadmium(II) chlorides with the ligands, giving yields of 43–76%. The complexes were characterized with multinuclear (1H, 13C and 31P) NMR, conductivity, IR spectroscopy, and X-ray analyses. Complexes 1, 3, 11, and 12 are comprised of two ligands coordinated to the metal center in a distorted monomeric tetrahedral arrangement. The P = O bond lengths of 1.490(3) (1), 1.497(4) (3), 1.480(4) (11), and 1.479(5) {\AA} (12) are in the order observed for analogous phosphoramide complexes. The results are compared with those reported for related chalcogen counterparts.",

keywords = "Phosphoramides, Zinc(II), Cadmium(II), Metal complex, NMR, X-ray analysis",

author = "Mohamed M{\textquoteright}haiham and Khaled Ebeid and Fatimetou Ebnou and Carpenter-Warren, {Cameron L.} and Slawin, {Alexandra M. Z.} and Woollins, {John Derek} and {Ben Dhia}, {Med Taieb} and Sanhoury, {Med Abderrahmane K.}",

note = "We are grateful to the Tunisian Ministry of High Education and Scientific Research for financial support (LR99ES14), to the French Service for Cooperation and Cultural Action and AgenceUniversitaire de la Francophonie (AUF) in Nouakchott, Mauritania for a scholarship to MM.",

year = "2020",

month = feb,

day = "28",

doi = "10.1080/00958972.2020.1731485",

language = "English",

pages = "1--14",

journal = "Journal of Coordination Chemistry",

issn = "0095-8972",

publisher = "Taylor & Francis",

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TY - JOUR

T1 - Synthesis, characterization, and structures of zinc(II) and cadmium(II) complexes with phosphoramides bearing cyclic amino groups

AU - M’haiham, Mohamed

AU - Ebeid, Khaled

AU - Ebnou, Fatimetou

AU - Carpenter-Warren, Cameron L.

AU - Slawin, Alexandra M. Z.

AU - Woollins, John Derek

AU - Ben Dhia, Med Taieb

AU - Sanhoury, Med Abderrahmane K.

N1 - We are grateful to the Tunisian Ministry of High Education and Scientific Research for financial support (LR99ES14), to the French Service for Cooperation and Cultural Action and AgenceUniversitaire de la Francophonie (AUF) in Nouakchott, Mauritania for a scholarship to MM.

PY - 2020/2/28

Y1 - 2020/2/28

N2 - Twelve new zinc(II) and cadmium(II) complexes with symmetric ligands, [MCl2((R2N)3PO)2] (M = Zn, R2N = pyrrolidinyl (1), piperidinyl (2); M = Cd, R2N = pyrrolidinyl (3), piperidinyl (4)), and differently substituted ligands of the general formula [MCl2(R2N)PO(R’2N)2] (M = Zn or Cd; R2N = Pyrr, Pip or Mor; R’2N = Pyrr, Pip or Mor (5–12) have been synthesized from reaction of zinc(II) or cadmium(II) chlorides with the ligands, giving yields of 43–76%. The complexes were characterized with multinuclear (1H, 13C and 31P) NMR, conductivity, IR spectroscopy, and X-ray analyses. Complexes 1, 3, 11, and 12 are comprised of two ligands coordinated to the metal center in a distorted monomeric tetrahedral arrangement. The P = O bond lengths of 1.490(3) (1), 1.497(4) (3), 1.480(4) (11), and 1.479(5) Å (12) are in the order observed for analogous phosphoramide complexes. The results are compared with those reported for related chalcogen counterparts.

AB - Twelve new zinc(II) and cadmium(II) complexes with symmetric ligands, [MCl2((R2N)3PO)2] (M = Zn, R2N = pyrrolidinyl (1), piperidinyl (2); M = Cd, R2N = pyrrolidinyl (3), piperidinyl (4)), and differently substituted ligands of the general formula [MCl2(R2N)PO(R’2N)2] (M = Zn or Cd; R2N = Pyrr, Pip or Mor; R’2N = Pyrr, Pip or Mor (5–12) have been synthesized from reaction of zinc(II) or cadmium(II) chlorides with the ligands, giving yields of 43–76%. The complexes were characterized with multinuclear (1H, 13C and 31P) NMR, conductivity, IR spectroscopy, and X-ray analyses. Complexes 1, 3, 11, and 12 are comprised of two ligands coordinated to the metal center in a distorted monomeric tetrahedral arrangement. The P = O bond lengths of 1.490(3) (1), 1.497(4) (3), 1.480(4) (11), and 1.479(5) Å (12) are in the order observed for analogous phosphoramide complexes. The results are compared with those reported for related chalcogen counterparts.

KW - Phosphoramides

KW - Zinc(II)

KW - Cadmium(II)

KW - Metal complex

KW - NMR

KW - X-ray analysis

U2 - 10.1080/00958972.2020.1731485

DO - 10.1080/00958972.2020.1731485

M3 - Article

SN - 0095-8972

SP - 1

EP - 14

JO - Journal of Coordination Chemistry

JF - Journal of Coordination Chemistry

ER -

Synthesis, characterization, and structures of zinc(II) and cadmium(II) complexes with phosphoramides bearing cyclic amino groups

Abstract

Keywords

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Datasets

Synthesis, characterization, and structures of zinc(II) and cadmium(II) complexes (dataset)

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