Synthesis, characterization, and structural properties of mercury(II), cadmium(II) and zinc(II) tripiperidinophosphine chalcogenide complexes

Fatimetou Ebnou; Mohamed M’Haiham; Khaled Ebeid; Cameron L. Carpenter-Warren; Alexandra M. Z. Slawin; J Derek Woollins; Med Taieb Ben Dhia; M. Abderrahmane Sanhoury

doi:10.1016/j.poly.2018.11.059

Synthesis, characterization, and structural properties of mercury(II), cadmium(II) and zinc(II) tripiperidinophosphine chalcogenide complexes

Fatimetou Ebnou, Mohamed M’Haiham, Khaled Ebeid, Cameron L. Carpenter-Warren, Alexandra M. Z. Slawin, J Derek Woollins, Med Taieb Ben Dhia, M. Abderrahmane Sanhoury

Research output: Contribution to journal › Article › peer-review

Abstract

Reaction of metal chlorides (MCl₂) with tripiperidinophosphine chalcogenides (Pip₃PE) produces new dimer species (1-6) of the formula [MCl₂(Pip₃PE)]₂ (Pip = piperidinyl; E = S or Se; M = Hg, Cd or Zn). These coordination complexes were characterized by elemental analysis, IR, multinuclear (³¹P, ¹¹³Cd and ¹⁹⁹Hg) NMR spectroscopy and single crystal X-ray analysis. Compounds 1-6 exist as centrosymmetric homobimetallic dimers, [M(µ-Cl)Cl(Pip₃PE)]₂. Each dimer incorporates two µ₂-chloro atoms and two terminal M–Cl bonds. The E atom of Pip₃PE forms terminal M–E bonds {S; 2.305(11); Se: 2.412(6)-2.589(15) Å} and thus the geometry about each metal centre is distorted tetrahedral and the range of tetrahedral bond angles is 102.83(3) to 113.32(3)^o. The P=Se bond lengths of 2.183(9)-2.205(2) Å in the selenide complexes are slightly elongated compared to those in the free ligands [2.1090(4) Å]. The results are discussed and compared with those obtained for related analogues.

Original language	English
Pages (from-to)	206-211
Journal	Polyhedron
Volume	159
Early online date	6 Dec 2018
DOIs	https://doi.org/10.1016/j.poly.2018.11.059
Publication status	Published - 1 Feb 2019

Keywords

Cadmium
Mercury
Zinc complex
Tripiperidinophosphine chalcogenide
31P
77Se
113Cd NMR

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10.1016/j.poly.2018.11.059

Woollins_2018_Poly_MCl2-Pip3PE_AAM
Copyright © 2018 Elsevier Ltd. All rights reserved. This work has been made available online in accordance with the publisher’s policies. This is the author created accepted version manuscript following peer review and as such may differ slightly from the final published version. The final published version of this work is available at https://doi.org/10.1016/j.poly.2018.11.059
Accepted author manuscript, 1.18 MBLicence: CC BY-NC-ND

Synthesis, characterization, and structural properties of mercury(II), cadmium(II) and zinc(II) tripiperidinophosphine chalcogenide complexes (dataset)
Ebnou, F. (Creator), M’Haiham, M. (Creator), Ebeid, K. (Creator), Carpenter-Warren, C. L. (Creator), Slawin, A. M. Z. (Creator), Woollins, J. D. (Creator), Ben Dhia, M. T. (Creator) & Sanhoury, M. A. (Creator), Cambridge Crystallographic Data Centre, 11 Dec 2018
https://dx.doi.org/10.5517/ccdc.csd.cc20krn0 and 3 more links, https://dx.doi.org/10.5517/ccdc.csd.cc20krp1, https://dx.doi.org/10.5517/ccdc.csd.cc20krq2, https://dx.doi.org/10.5517/ccdc.csd.cc20krr3 (show fewer)
Dataset

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@article{53fd524862aa4f0eb92e84cce6ac59d4,

title = "Synthesis, characterization, and structural properties of mercury(II), cadmium(II) and zinc(II) tripiperidinophosphine chalcogenide complexes",

abstract = "Reaction of metal chlorides (MCl2) with tripiperidinophosphine chalcogenides (Pip3PE) produces new dimer species (1-6) of the formula [MCl2(Pip3PE)]2 (Pip = piperidinyl; E = S or Se; M = Hg, Cd or Zn). These coordination complexes were characterized by elemental analysis, IR, multinuclear (31P, 113Cd and 199Hg) NMR spectroscopy and single crystal X-ray analysis. Compounds 1-6 exist as centrosymmetric homobimetallic dimers, [M(µ-Cl)Cl(Pip3PE)]2. Each dimer incorporates two µ2-chloro atoms and two terminal M–Cl bonds. The E atom of Pip3PE forms terminal M–E bonds {S; 2.305(11); Se: 2.412(6)-2.589(15) {\AA}} and thus the geometry about each metal centre is distorted tetrahedral and the range of tetrahedral bond angles is 102.83(3) to 113.32(3)o. The P=Se bond lengths of 2.183(9)-2.205(2) {\AA} in the selenide complexes are slightly elongated compared to those in the free ligands [2.1090(4) {\AA}]. The results are discussed and compared with those obtained for related analogues.",

keywords = "Cadmium, Mercury, Zinc complex, Tripiperidinophosphine chalcogenide, 31P, 77Se, 113Cd NMR",

author = "Fatimetou Ebnou and Mohamed M{\textquoteright}Haiham and Khaled Ebeid and Carpenter-Warren, {Cameron L.} and Slawin, {Alexandra M. Z.} and Woollins, {J Derek} and {Ben Dhia}, {Med Taieb} and Sanhoury, {M. Abderrahmane}",

note = "We are grateful to the Tunisian Ministry of High Education and Scientific Research for support [grant number LR99ES14] and to the French Service for Cooperation and Cultural Action in Nouakchott, Mauritania for a scholarship to FE.",

year = "2019",

month = feb,

day = "1",

doi = "10.1016/j.poly.2018.11.059",

language = "English",

volume = "159",

pages = "206--211",

journal = "Polyhedron",

issn = "0277-5387",

publisher = "Elsevier",

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TY - JOUR

T1 - Synthesis, characterization, and structural properties of mercury(II), cadmium(II) and zinc(II) tripiperidinophosphine chalcogenide complexes

AU - Ebnou, Fatimetou

AU - M’Haiham, Mohamed

AU - Ebeid, Khaled

AU - Carpenter-Warren, Cameron L.

AU - Slawin, Alexandra M. Z.

AU - Woollins, J Derek

AU - Ben Dhia, Med Taieb

AU - Sanhoury, M. Abderrahmane

N1 - We are grateful to the Tunisian Ministry of High Education and Scientific Research for support [grant number LR99ES14] and to the French Service for Cooperation and Cultural Action in Nouakchott, Mauritania for a scholarship to FE.

PY - 2019/2/1

Y1 - 2019/2/1

N2 - Reaction of metal chlorides (MCl2) with tripiperidinophosphine chalcogenides (Pip3PE) produces new dimer species (1-6) of the formula [MCl2(Pip3PE)]2 (Pip = piperidinyl; E = S or Se; M = Hg, Cd or Zn). These coordination complexes were characterized by elemental analysis, IR, multinuclear (31P, 113Cd and 199Hg) NMR spectroscopy and single crystal X-ray analysis. Compounds 1-6 exist as centrosymmetric homobimetallic dimers, [M(µ-Cl)Cl(Pip3PE)]2. Each dimer incorporates two µ2-chloro atoms and two terminal M–Cl bonds. The E atom of Pip3PE forms terminal M–E bonds {S; 2.305(11); Se: 2.412(6)-2.589(15) Å} and thus the geometry about each metal centre is distorted tetrahedral and the range of tetrahedral bond angles is 102.83(3) to 113.32(3)o. The P=Se bond lengths of 2.183(9)-2.205(2) Å in the selenide complexes are slightly elongated compared to those in the free ligands [2.1090(4) Å]. The results are discussed and compared with those obtained for related analogues.

AB - Reaction of metal chlorides (MCl2) with tripiperidinophosphine chalcogenides (Pip3PE) produces new dimer species (1-6) of the formula [MCl2(Pip3PE)]2 (Pip = piperidinyl; E = S or Se; M = Hg, Cd or Zn). These coordination complexes were characterized by elemental analysis, IR, multinuclear (31P, 113Cd and 199Hg) NMR spectroscopy and single crystal X-ray analysis. Compounds 1-6 exist as centrosymmetric homobimetallic dimers, [M(µ-Cl)Cl(Pip3PE)]2. Each dimer incorporates two µ2-chloro atoms and two terminal M–Cl bonds. The E atom of Pip3PE forms terminal M–E bonds {S; 2.305(11); Se: 2.412(6)-2.589(15) Å} and thus the geometry about each metal centre is distorted tetrahedral and the range of tetrahedral bond angles is 102.83(3) to 113.32(3)o. The P=Se bond lengths of 2.183(9)-2.205(2) Å in the selenide complexes are slightly elongated compared to those in the free ligands [2.1090(4) Å]. The results are discussed and compared with those obtained for related analogues.

KW - Cadmium

KW - Mercury

KW - Zinc complex

KW - Tripiperidinophosphine chalcogenide

KW - 31P

KW - 77Se

KW - 113Cd NMR

U2 - 10.1016/j.poly.2018.11.059

DO - 10.1016/j.poly.2018.11.059

M3 - Article

SN - 0277-5387

VL - 159

SP - 206

EP - 211

JO - Polyhedron

JF - Polyhedron

ER -

Synthesis, characterization, and structural properties of mercury(II), cadmium(II) and zinc(II) tripiperidinophosphine chalcogenide complexes

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Keywords

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Synthesis, characterization, and structural properties of mercury(II), cadmium(II) and zinc(II) tripiperidinophosphine chalcogenide complexes (dataset)

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