Synthesis, characterization, and computational analysis of the dialanate dianion, [H3Al-AlH3]2−: a valence isoelectronic analogue of ethane

Simon J. Bonyhady, Nicole Holzmann, Gernot Frenking, Andreas Stasch, Cameron Jones

Research output: Contribution to journalArticlepeer-review

24 Citations (Scopus)
6 Downloads (Pure)

Abstract

The first example of a well-defined binary, low-oxidation-state aluminum hydride species that is stable at ambient temperature, namely the dianion in [{(DepNacnac)Mg}2(μ-H)]2[H3Al-AlH3] (DepNacnac=[(DepNCMe)2CH], Dep=2,6-diethylphenyl), has been prepared via a magnesium(I) reduction of the alanate complex, (DepNacnac)Mg(μ-H)3AlH(NEt3). An X-ray crystallographic analysis has shown the compound to be a contact ion complex, which computational studies have revealed to be the source of the stability of the aluminum(II) dianion.
Original languageEnglish
Pages (from-to)8527-8531
Number of pages5
JournalAngewandte Chemie International Edition
Volume56
Issue number29
Early online date9 Dec 2016
DOIs
Publication statusPublished - 10 Jul 2017

Keywords

  • DFT calculations
  • Dialanate
  • Hydride
  • Magnesium(I)
  • Metal–metal bonding

Fingerprint

Dive into the research topics of 'Synthesis, characterization, and computational analysis of the dialanate dianion, [H3Al-AlH3]2−: a valence isoelectronic analogue of ethane'. Together they form a unique fingerprint.

Cite this