Synthesis, characterisation, and oxygen atom transfer reactions involving the first gold(I)-alkylperoxo complexes

Alba Collado-Martinez; Adrian Gomez Suarez; Yoshihiro Oonishi; Alexandra Martha Zoya Slawin; Steven Patrick Nolan

doi:10.1039/c3cc47030j

Synthesis, characterisation, and oxygen atom transfer reactions involving the first gold(I)-alkylperoxo complexes

Alba Collado-Martinez, Adrian Gomez Suarez, Yoshihiro Oonishi, Alexandra Martha Zoya Slawin, Steven Patrick Nolan

Research output: Contribution to journal › Article › peer-review

19 Citations (Scopus)

Abstract

The synthesis of a new class of organogold species containing a peroxo moiety is reported. Complexes [Au(IPr)(OOtBu)] and [Au(SIPr)(OOtBu)] have been synthesised via a straightforward methodology using the parent gold(I) hydroxide complexes as
synthons. These complexes have been successfully used in oxygentransfer reactions to triphenylphosphine.

Original language	English
Pages (from-to)	10745-10747
Number of pages	3
Journal	Chemical Communications
Volume	49
Early online date	30 Sept 2013
DOIs	https://doi.org/10.1039/c3cc47030j
Publication status	Published - 2013

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title = "Synthesis, characterisation, and oxygen atom transfer reactions involving the first gold(I)-alkylperoxo complexes",

abstract = "The synthesis of a new class of organogold species containing a peroxo moiety is reported. Complexes [Au(IPr)(OOtBu)] and [Au(SIPr)(OOtBu)] have been synthesised via a straightforward methodology using the parent gold(I) hydroxide complexes assynthons. These complexes have been successfully used in oxygentransfer reactions to triphenylphosphine. ",

author = "Alba Collado-Martinez and {Gomez Suarez}, Adrian and Yoshihiro Oonishi and Slawin, {Alexandra Martha Zoya} and Nolan, {Steven Patrick}",

year = "2013",

doi = "10.1039/c3cc47030j",

language = "English",

volume = "49",

pages = "10745--10747",

journal = "Chemical Communications",

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publisher = "Royal Society of Chemistry",

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T1 - Synthesis, characterisation, and oxygen atom transfer reactions involving the first gold(I)-alkylperoxo complexes

AU - Collado-Martinez, Alba

AU - Gomez Suarez, Adrian

AU - Oonishi, Yoshihiro

AU - Slawin, Alexandra Martha Zoya

AU - Nolan, Steven Patrick

PY - 2013

Y1 - 2013

N2 - The synthesis of a new class of organogold species containing a peroxo moiety is reported. Complexes [Au(IPr)(OOtBu)] and [Au(SIPr)(OOtBu)] have been synthesised via a straightforward methodology using the parent gold(I) hydroxide complexes assynthons. These complexes have been successfully used in oxygentransfer reactions to triphenylphosphine.

AB - The synthesis of a new class of organogold species containing a peroxo moiety is reported. Complexes [Au(IPr)(OOtBu)] and [Au(SIPr)(OOtBu)] have been synthesised via a straightforward methodology using the parent gold(I) hydroxide complexes assynthons. These complexes have been successfully used in oxygentransfer reactions to triphenylphosphine.

U2 - 10.1039/c3cc47030j

DO - 10.1039/c3cc47030j

M3 - Article

SN - 1359-7345

VL - 49

SP - 10745

EP - 10747

JO - Chemical Communications

JF - Chemical Communications

ER -

Synthesis, characterisation, and oxygen atom transfer reactions involving the first gold(I)-alkylperoxo complexes

Abstract

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