SYNTHESIS AND X-RAY STUDIES OF THE 7-COORDINATE TI(IV)(THPED) DIMER

D F EVANS, J PARR, S RAHMAN, A M Z SLAWIN, D J WILLIAMS, C Y WONG, J D WOOLLINS

Research output: Contribution to journalComment/debatepeer-review

13 Citations (Scopus)

Abstract

The synthesis and X-ray structure of the seven-coordinate Ti(IV)(THPED) dimer, where H4THPED = N,N,N',N'-tetrakis-(2-hydroxypropyl)ethylenediamine, is described. The structure is dimeric with each titanium atom chelating to an N2O5 donor set. One oxygen atom in each ligand is binucleating, thus forming a central Ti2O2 ring.

Original languageEnglish
Pages (from-to)337-341
Number of pages5
JournalPolyhedron
Volume12
Issue number3
DOIs
Publication statusPublished - Feb 1993

Keywords

  • COMPLEX

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