SYNTHESIS AND X-RAY STUDIES OF THE 7-COORDINATE TI(IV)(THPED) DIMER

D F  EVANS; J  PARR; S  RAHMAN; A M Z  SLAWIN; D J  WILLIAMS; C Y  WONG; J D  WOOLLINS

doi:10.1016/S0277-5387(00)81732-5

SYNTHESIS AND X-RAY STUDIES OF THE 7-COORDINATE TI(IV)(THPED) DIMER

D F EVANS, J PARR, S RAHMAN, A M Z SLAWIN, D J WILLIAMS, C Y WONG, J D WOOLLINS

Research output: Contribution to journal › Comment/debate › peer-review

Abstract

The synthesis and X-ray structure of the seven-coordinate Ti(IV)(THPED) dimer, where H4THPED = N,N,N',N'-tetrakis-(2-hydroxypropyl)ethylenediamine, is described. The structure is dimeric with each titanium atom chelating to an N2O5 donor set. One oxygen atom in each ligand is binucleating, thus forming a central Ti2O2 ring.

Original language	English
Pages (from-to)	337-341
Number of pages	5
Journal	Polyhedron
Volume	12
Issue number	3
DOIs	https://doi.org/10.1016/S0277-5387(00)81732-5
Publication status	Published - Feb 1993

Keywords

COMPLEX

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title = "SYNTHESIS AND X-RAY STUDIES OF THE 7-COORDINATE TI(IV)(THPED) DIMER",

abstract = "The synthesis and X-ray structure of the seven-coordinate Ti(IV)(THPED) dimer, where H4THPED = N,N,N',N'-tetrakis-(2-hydroxypropyl)ethylenediamine, is described. The structure is dimeric with each titanium atom chelating to an N2O5 donor set. One oxygen atom in each ligand is binucleating, thus forming a central Ti2O2 ring.",

keywords = "COMPLEX",

author = "EVANS, {D F} and J PARR and S RAHMAN and SLAWIN, {A M Z} and WILLIAMS, {D J} and WONG, {C Y} and WOOLLINS, {J D}",

year = "1993",

month = feb,

doi = "10.1016/S0277-5387(00)81732-5",

language = "English",

volume = "12",

pages = "337--341",

journal = "Polyhedron",

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TY - JOUR

T1 - SYNTHESIS AND X-RAY STUDIES OF THE 7-COORDINATE TI(IV)(THPED) DIMER

AU - EVANS, D F

AU - PARR, J

AU - RAHMAN, S

AU - SLAWIN, A M Z

AU - WILLIAMS, D J

AU - WONG, C Y

AU - WOOLLINS, J D

PY - 1993/2

Y1 - 1993/2

N2 - The synthesis and X-ray structure of the seven-coordinate Ti(IV)(THPED) dimer, where H4THPED = N,N,N',N'-tetrakis-(2-hydroxypropyl)ethylenediamine, is described. The structure is dimeric with each titanium atom chelating to an N2O5 donor set. One oxygen atom in each ligand is binucleating, thus forming a central Ti2O2 ring.

AB - The synthesis and X-ray structure of the seven-coordinate Ti(IV)(THPED) dimer, where H4THPED = N,N,N',N'-tetrakis-(2-hydroxypropyl)ethylenediamine, is described. The structure is dimeric with each titanium atom chelating to an N2O5 donor set. One oxygen atom in each ligand is binucleating, thus forming a central Ti2O2 ring.

KW - COMPLEX

U2 - 10.1016/S0277-5387(00)81732-5

DO - 10.1016/S0277-5387(00)81732-5

M3 - Comment/debate

SN - 0277-5387

VL - 12

SP - 337

EP - 341

JO - Polyhedron

JF - Polyhedron

IS - 3

ER -

SYNTHESIS AND X-RAY STUDIES OF THE 7-COORDINATE TI(IV)(THPED) DIMER

Abstract

Keywords

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