SYNTHESIS AND X-RAY STRUCTURES OF BIS(3,5-DI-TERT-BUTYLCATECHOLATO)(PHENANTHROLINE)VANADIUM(IV) AND ITS VANADIUM(V) ANALOG [V(DTBC)2(PHEN)][SBF6]

T A KABANOS, A J P WHITE, D J WILLIAMS, J D WOOLLINS

Research output: Contribution to journalArticlepeer-review

35 Citations (Scopus)

Abstract

Bis(3,5-di-tert-butylcatecholato)(phenanthroline)vanadium(iv) 1 is prepared, and oxidised with silver hexafluoroantimonate to give its vanadium(v) analogue 2; both complexes are characterised by X-ray crystallography revealing significant differences in their coordination geometry.

Original languageEnglish
Pages (from-to)17-18
Number of pages2
JournalJournal of the Chemical Society, Chemical Communications
Issue number1
Publication statusPublished - 1 Jan 1992

Keywords

  • COMPLEXES

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