Synthesis and X-ray crystal structures of [pyH][Fe(pic)2Cl2] and [Fe2(μ2-OMe)2(pic)4] (Hpic=2-picolinic acid)

Sneh L Jain; Pravat Bhattacharyya; Heather L Milton; Alexandra Martha Zoya Slawin; John Derek Woollins

doi:10.1016/j.inoche.2003.12.034

Synthesis and X-ray crystal structures of [pyH][Fe(pic)₂Cl₂] and [Fe₂(μ₂-OMe)₂(pic)₄] (Hpic=2-picolinic acid)

Sneh L Jain, Pravat Bhattacharyya, Heather L Milton, Alexandra Martha Zoya Slawin, John Derek Woollins

Research output: Contribution to journal › Article › peer-review

Abstract

The passage of dichlorine gas through a dichloromethane solution of [Fe(pic)(2)(py)(2)] gives [pyH][Fe(pic)(2)Cl-2] (1) whilst the methoxy bridged diiron(III) complex 2 was prepared and crystallised directly from the reaction of [Fe(pic)(2)(py)(2)] with methanol in air. The X-ray structures of 1 and 2 are reported. (C) 2004 Elsevier B.V. All rights reserved.

Original language	English
Pages (from-to)	423-425
Number of pages	3
Journal	Inorganic Chemistry Communications
Volume	7
Issue number	3
DOIs	https://doi.org/10.1016/j.inoche.2003.12.034
Publication status	Published - Mar 2004

Keywords

coordination chemistry
iron
Gif catalysts
crystal structure
SYSTEMS
HYDROCARBONS

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title = "Synthesis and X-ray crystal structures of [pyH][Fe(pic)2Cl2] and [Fe2(μ2-OMe)2(pic)4] (Hpic=2-picolinic acid)",

abstract = "The passage of dichlorine gas through a dichloromethane solution of [Fe(pic)(2)(py)(2)] gives [pyH][Fe(pic)(2)Cl-2] (1) whilst the methoxy bridged diiron(III) complex 2 was prepared and crystallised directly from the reaction of [Fe(pic)(2)(py)(2)] with methanol in air. The X-ray structures of 1 and 2 are reported. (C) 2004 Elsevier B.V. All rights reserved.",

keywords = "coordination chemistry, iron, Gif catalysts, crystal structure, SYSTEMS, HYDROCARBONS",

author = "Jain, \{Sneh L\} and Pravat Bhattacharyya and Milton, \{Heather L\} and Slawin, \{Alexandra Martha Zoya\} and Woollins, \{John Derek\}",

year = "2004",

month = mar,

doi = "10.1016/j.inoche.2003.12.034",

language = "English",

volume = "7",

pages = "423--425",

journal = "Inorganic Chemistry Communications",

issn = "1387-7003",

publisher = "Elsevier",

number = "3",

}

TY - JOUR

T1 - Synthesis and X-ray crystal structures of [pyH][Fe(pic)2Cl2] and [Fe2(μ2-OMe)2(pic)4] (Hpic=2-picolinic acid)

AU - Jain, Sneh L

AU - Bhattacharyya, Pravat

AU - Milton, Heather L

AU - Slawin, Alexandra Martha Zoya

AU - Woollins, John Derek

PY - 2004/3

Y1 - 2004/3

N2 - The passage of dichlorine gas through a dichloromethane solution of [Fe(pic)(2)(py)(2)] gives [pyH][Fe(pic)(2)Cl-2] (1) whilst the methoxy bridged diiron(III) complex 2 was prepared and crystallised directly from the reaction of [Fe(pic)(2)(py)(2)] with methanol in air. The X-ray structures of 1 and 2 are reported. (C) 2004 Elsevier B.V. All rights reserved.

AB - The passage of dichlorine gas through a dichloromethane solution of [Fe(pic)(2)(py)(2)] gives [pyH][Fe(pic)(2)Cl-2] (1) whilst the methoxy bridged diiron(III) complex 2 was prepared and crystallised directly from the reaction of [Fe(pic)(2)(py)(2)] with methanol in air. The X-ray structures of 1 and 2 are reported. (C) 2004 Elsevier B.V. All rights reserved.

KW - coordination chemistry

KW - iron

KW - Gif catalysts

KW - crystal structure

KW - SYSTEMS

KW - HYDROCARBONS

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DO - 10.1016/j.inoche.2003.12.034

M3 - Article

SN - 1387-7003

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SP - 423

EP - 425

JO - Inorganic Chemistry Communications

JF - Inorganic Chemistry Communications

IS - 3

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