Synthesis and X-ray crystal structures of [pyH][Fe(pic)2Cl2] and [Fe22-OMe)2(pic)4] (Hpic=2-picolinic acid)

Sneh L Jain, Pravat Bhattacharyya, Heather L Milton, Alexandra Martha Zoya Slawin, John Derek Woollins

Research output: Contribution to journalArticlepeer-review

17 Citations (Scopus)

Abstract

The passage of dichlorine gas through a dichloromethane solution of [Fe(pic)(2)(py)(2)] gives [pyH][Fe(pic)(2)Cl-2] (1) whilst the methoxy bridged diiron(III) complex 2 was prepared and crystallised directly from the reaction of [Fe(pic)(2)(py)(2)] with methanol in air. The X-ray structures of 1 and 2 are reported. (C) 2004 Elsevier B.V. All rights reserved.

Original languageEnglish
Pages (from-to)423-425
Number of pages3
JournalInorganic Chemistry Communications
Volume7
Issue number3
DOIs
Publication statusPublished - Mar 2004

Keywords

  • coordination chemistry
  • iron
  • Gif catalysts
  • crystal structure
  • SYSTEMS
  • HYDROCARBONS

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