Abstract
A series of seven O-ethyl-N-butylphenylphosphonamidates with benzyl ether substituents at the para or meta position have been prepared and fully characterised. Upon treatment with n-butyllithium in THF at RT, these undergo Wittig rearrangement in six cases to give the novel phosphonamidate-substituted diarylmethanols in moderate to good yield.
Original language | English |
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Pages (from-to) | 59-69 |
Number of pages | 11 |
Journal | Organics |
Volume | 4 |
Issue number | 1 |
DOIs | |
Publication status | Published - 3 Feb 2023 |
Keywords
- Wittig rearrangement
- Phosphonamidate
- Diarylmethanol
- Aryl benzyl ether
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Dive into the research topics of 'Synthesis and Wittig rearrangement of 3- and 4-benzyloxyphenylphosphonamidates'. Together they form a unique fingerprint.Datasets
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Synthesis and Wittig Rearrangement of 3- and 4-Benzyloxyphenylphosphonamidates (dataset)
Aitken, R. A. (Creator) & Inwood, R. (Creator), University of St Andrews, 3 Feb 2023
DOI: 10.17630/bd44d649-c8e8-436c-bd62-3cfdb1f77bd5
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