Abstract
The reactions of aminobis(phosphines), Ph2PN(R)PPh2 (R = H, Me, Et, '' Pr, '' Bu, Ph), with Me2Pt(COD) led to the formation of four-membered metallacycles in good yield. The enthalpies of the ligand substitution reactions are measured by the anaerobic solution calorimetry in THF at 30 degrees C. (c) 2005 Elsevier B.V. All rights reserved.
Original language | English |
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Pages (from-to) | 2817-2820 |
Number of pages | 4 |
Journal | Inorganica Chimica Acta |
Volume | 358 |
Issue number | 9 |
DOIs | |
Publication status | Published - 1 Jun 2005 |
Keywords
- aminobis(phosphines)
- thermochemistry
- enthalpy
- platinum complexes
- QUANTITATIVE-ANALYSIS
- MOLECULAR-STRUCTURES
- BOND STRENGTHS
- EFFECTS QALE
- X-RAY
- COMPLEXES
- CHEMISTRY
- CRYSTAL
- CL
- PLATINUM(II)