Synthesis and structures of ring and cage compounds containing Si-O-As bonds

G Ferguson, B J O'Leary, T R Spalding

Research output: Contribution to journalArticlepeer-review

2 Citations (Scopus)

Abstract

The cyclic arsenosilicate compounds (PhAsO)(2)((Bu2SiO)-Si-t)(2), 7, {PhAs(O)O}(2)((Bu2SiO)-Si-t)(2), 8, [OCMe2CH2C(H) MeO] AsOSiPh3, 9, and cage- structured (BuSi)-Si-t{OAs(Ph)O}(3)SiBut, 10 and As((OSiBu2O)-O-t) 3As, 11, have been synthesised, their spectroscopic (IR and NMR) and mass spectrometric properties recorded and the solid state structures of 7, 9 and 10 established with single crystal X-ray techniques.

Original languageEnglish
Pages (from-to)255-267
Number of pages13
JournalARKIVOC
Publication statusPublished - 2003

Keywords

  • arsenosilicate
  • synthesis
  • structures
  • X-ray
  • spectroscopy
  • CRYSTAL-STRUCTURES

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