Synthesis and structures of ring and cage compounds containing Si-O-As bonds

G  Ferguson; B J  O'Leary; T R  Spalding

Synthesis and structures of ring and cage compounds containing Si-O-As bonds

G Ferguson, B J O'Leary, T R Spalding

School of Chemistry

Research output: Contribution to journal › Article › peer-review

4 Citations (Scopus)

Abstract

The cyclic arsenosilicate compounds (PhAsO)(2)((Bu2SiO)-Si-t)(2), 7, {PhAs(O)O}(2)((Bu2SiO)-Si-t)(2), 8, [OCMe2CH2C(H) MeO] AsOSiPh3, 9, and cage- structured (BuSi)-Si-t{OAs(Ph)O}(3)SiBut, 10 and As((OSiBu2O)-O-t) 3As, 11, have been synthesised, their spectroscopic (IR and NMR) and mass spectrometric properties recorded and the solid state structures of 7, 9 and 10 established with single crystal X-ray techniques.

Original language	English
Pages (from-to)	255-267
Number of pages	13
Journal	ARKIVOC
Publication status	Published - 2003

Keywords

arsenosilicate
synthesis
structures
X-ray
spectroscopy
CRYSTAL-STRUCTURES

Cite this

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title = "Synthesis and structures of ring and cage compounds containing Si-O-As bonds",

abstract = "The cyclic arsenosilicate compounds (PhAsO)(2)((Bu2SiO)-Si-t)(2), 7, {PhAs(O)O}(2)((Bu2SiO)-Si-t)(2), 8, [OCMe2CH2C(H) MeO] AsOSiPh3, 9, and cage- structured (BuSi)-Si-t{OAs(Ph)O}(3)SiBut, 10 and As((OSiBu2O)-O-t) 3As, 11, have been synthesised, their spectroscopic (IR and NMR) and mass spectrometric properties recorded and the solid state structures of 7, 9 and 10 established with single crystal X-ray techniques.",

keywords = "arsenosilicate, synthesis, structures, X-ray, spectroscopy, CRYSTAL-STRUCTURES",

author = "G Ferguson and O'Leary, {B J} and Spalding, {T R}",

year = "2003",

language = "English",

pages = "255--267",

journal = "ARKIVOC",

issn = "1551-7004",

publisher = "Arkat USA",

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TY - JOUR

T1 - Synthesis and structures of ring and cage compounds containing Si-O-As bonds

AU - Ferguson, G

AU - O'Leary, B J

AU - Spalding, T R

PY - 2003

Y1 - 2003

N2 - The cyclic arsenosilicate compounds (PhAsO)(2)((Bu2SiO)-Si-t)(2), 7, {PhAs(O)O}(2)((Bu2SiO)-Si-t)(2), 8, [OCMe2CH2C(H) MeO] AsOSiPh3, 9, and cage- structured (BuSi)-Si-t{OAs(Ph)O}(3)SiBut, 10 and As((OSiBu2O)-O-t) 3As, 11, have been synthesised, their spectroscopic (IR and NMR) and mass spectrometric properties recorded and the solid state structures of 7, 9 and 10 established with single crystal X-ray techniques.

AB - The cyclic arsenosilicate compounds (PhAsO)(2)((Bu2SiO)-Si-t)(2), 7, {PhAs(O)O}(2)((Bu2SiO)-Si-t)(2), 8, [OCMe2CH2C(H) MeO] AsOSiPh3, 9, and cage- structured (BuSi)-Si-t{OAs(Ph)O}(3)SiBut, 10 and As((OSiBu2O)-O-t) 3As, 11, have been synthesised, their spectroscopic (IR and NMR) and mass spectrometric properties recorded and the solid state structures of 7, 9 and 10 established with single crystal X-ray techniques.

KW - arsenosilicate

KW - synthesis

KW - structures

KW - X-ray

KW - spectroscopy

KW - CRYSTAL-STRUCTURES

M3 - Article

SN - 1551-7004

SP - 255

EP - 267

JO - ARKIVOC

JF - ARKIVOC

ER -

Synthesis and structures of ring and cage compounds containing Si-O-As bonds

Abstract

Keywords

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