Synthesis and structure of platinum(II) complexes with mixed Ph2PNHP(O)Ph2/[Ph2PNP(O)Ph2]- or Ph2PC6H4NH2/[Ph2PC6H4NH]- hybrid ligands: new M-P-N-H...N-P metallacycles

MB Smith; Alexandra Martha Zoya Slawin

doi:10.1039/a908282d

Synthesis and structure of platinum(II) complexes with mixed Ph₂PNHP(O)Ph₂/[Ph₂PNP(O)Ph₂]- or Ph₂PC₆H₄NH₂/[Ph₂PC₆H₄NH]- hybrid ligands: new M-P-N-H...N-P metallacycles

Research output: Contribution to journal › Article › peer-review

Abstract

Transmetallation of K[Ph2P(E)NP(E)Ph-2] (E = S or Se) with cis-[PtCl2(HL)(2)] [HL = Ph2PNHP(O)Ph-2-P] gave the mixed platinum(II) compounds [Pt{Ph2P(E)NP(E)Ph-2-E,E'}L(HL)] containing one deprotonated [Ph2PNP(O)Ph-2](-) ligand; X-ray crystallography reveals an unusual pseudo six-membered Pt-P-N-H ... N-P metalloring structure.

Original language	English
Pages (from-to)	65-67
Number of pages	3
Journal	New Journal of Chemistry
Volume	24
Issue number	2
DOIs	https://doi.org/10.1039/a908282d
Publication status	Published - Feb 2000

Keywords

COORDINATION CHEMISTRY
PH(2)PNHP(O)PH(2)
PHOSPHINE
CRYSTAL

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10.1039/a908282d

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title = "Synthesis and structure of platinum(II) complexes with mixed Ph2PNHP(O)Ph2/[Ph2PNP(O)Ph2]- or Ph2PC6H4NH2/[Ph2PC6H4NH]- hybrid ligands: new M-P-N-H...N-P metallacycles",

abstract = "Transmetallation of K[Ph2P(E)NP(E)Ph-2] (E = S or Se) with cis-[PtCl2(HL)(2)] [HL = Ph2PNHP(O)Ph-2-P] gave the mixed platinum(II) compounds [Pt{Ph2P(E)NP(E)Ph-2-E,E'}L(HL)] containing one deprotonated [Ph2PNP(O)Ph-2](-) ligand; X-ray crystallography reveals an unusual pseudo six-membered Pt-P-N-H ... N-P metalloring structure.",

keywords = "COORDINATION CHEMISTRY, PH(2)PNHP(O)PH(2), PHOSPHINE, CRYSTAL",

author = "MB Smith and Slawin, {Alexandra Martha Zoya}",

year = "2000",

month = feb,

doi = "10.1039/a908282d",

language = "English",

volume = "24",

pages = "65--67",

journal = "New Journal of Chemistry",

issn = "1144-0546",

publisher = "ROYAL SOC CHEMISTRY",

number = "2",

}

TY - JOUR

T1 - Synthesis and structure of platinum(II) complexes with mixed Ph2PNHP(O)Ph2/[Ph2PNP(O)Ph2]- or Ph2PC6H4NH2/[Ph2PC6H4NH]- hybrid ligands

T2 - new M-P-N-H...N-P metallacycles

AU - Smith, MB

AU - Slawin, Alexandra Martha Zoya

PY - 2000/2

Y1 - 2000/2

N2 - Transmetallation of K[Ph2P(E)NP(E)Ph-2] (E = S or Se) with cis-[PtCl2(HL)(2)] [HL = Ph2PNHP(O)Ph-2-P] gave the mixed platinum(II) compounds [Pt{Ph2P(E)NP(E)Ph-2-E,E'}L(HL)] containing one deprotonated [Ph2PNP(O)Ph-2](-) ligand; X-ray crystallography reveals an unusual pseudo six-membered Pt-P-N-H ... N-P metalloring structure.

AB - Transmetallation of K[Ph2P(E)NP(E)Ph-2] (E = S or Se) with cis-[PtCl2(HL)(2)] [HL = Ph2PNHP(O)Ph-2-P] gave the mixed platinum(II) compounds [Pt{Ph2P(E)NP(E)Ph-2-E,E'}L(HL)] containing one deprotonated [Ph2PNP(O)Ph-2](-) ligand; X-ray crystallography reveals an unusual pseudo six-membered Pt-P-N-H ... N-P metalloring structure.

KW - COORDINATION CHEMISTRY

KW - PH(2)PNHP(O)PH(2)

KW - PHOSPHINE

KW - CRYSTAL

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U2 - 10.1039/a908282d

DO - 10.1039/a908282d

M3 - Article

SN - 1144-0546

VL - 24

SP - 65

EP - 67

JO - New Journal of Chemistry

JF - New Journal of Chemistry

IS - 2

ER -

Synthesis and structure of platinum(II) complexes with mixed Ph₂PNHP(O)Ph₂/[Ph₂PNP(O)Ph₂]- or Ph₂PC₆H₄NH₂/[Ph₂PC₆H₄NH]- hybrid ligands: new M-P-N-H...N-P metallacycles

Abstract

Keywords

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