Synthesis and structure of novel [Ph(RO)PSe2](-) complexes

I P  Gray; A M Z  Slawin; J D  Woollins

doi:10.1039/B503793J

Synthesis and structure of novel [Ph(RO)PSe2](-) complexes

I P Gray, A M Z Slawin, J D Woollins

Research output: Contribution to journal › Article › peer-review

48 Citations (Scopus)

Abstract

Reaction of (PhPSe2)(2) (Woollins reagent) with NaOR (R = Me, Et, Pr-i) gives the non-symmetric phosphonodiselenoato anions [Ph(RO) PSe2](-) which can be complexed to a range of metals. The nickel complex Ni[Ph(MeO) PSe2](2) adopts a square-planar ML2 structure while the cadmium complex Cd[Ph(MeO) PSe2](2) displays a dimeric M2L4 structure. Two different lead complexes are observed, one consisting of PbL2 units joined by Pb center dot center dot center dot Se interactions to form distinct dimeric pairs. The other displays a novel dimeric structure built around a central four-membered Pb2Se2 ring. All new compounds have been characterised spectroscopically (P-31, H-1, C-13 NMR, IR, mass spectroscopy), by elemental analysis and five demonstrative X-ray structures are reported.

Original language	English
Pages (from-to)	2188-2194
Number of pages	7
Journal	Dalton Transactions
Issue number	12
DOIs	https://doi.org/10.1039/B503793J
Publication status	Published - 2005

Keywords

RAY CRYSTAL-STRUCTURE
CU-8(I) CUBIC CLUSTERS
LAWESSONS REAGENT
DISELENOPHOSPHATE LIGANDS
COORDINATION CHEMISTRY
METAL-COMPLEXES
RARE EXAMPLE
PR-I
PHOSPHORUS
SELENIUM

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title = "Synthesis and structure of novel [Ph(RO)PSe2](-) complexes",

abstract = "Reaction of (PhPSe2)(2) (Woollins reagent) with NaOR (R = Me, Et, Pr-i) gives the non-symmetric phosphonodiselenoato anions [Ph(RO) PSe2](-) which can be complexed to a range of metals. The nickel complex Ni[Ph(MeO) PSe2](2) adopts a square-planar ML2 structure while the cadmium complex Cd[Ph(MeO) PSe2](2) displays a dimeric M2L4 structure. Two different lead complexes are observed, one consisting of PbL2 units joined by Pb center dot center dot center dot Se interactions to form distinct dimeric pairs. The other displays a novel dimeric structure built around a central four-membered Pb2Se2 ring. All new compounds have been characterised spectroscopically (P-31, H-1, C-13 NMR, IR, mass spectroscopy), by elemental analysis and five demonstrative X-ray structures are reported.",

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author = "Gray, {I P} and Slawin, {A M Z} and Woollins, {J D}",

year = "2005",

doi = "10.1039/B503793J",

language = "English",

pages = "2188--2194",

journal = "Dalton Transactions",

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T1 - Synthesis and structure of novel [Ph(RO)PSe2](-) complexes

AU - Gray, I P

AU - Slawin, A M Z

AU - Woollins, J D

PY - 2005

Y1 - 2005

N2 - Reaction of (PhPSe2)(2) (Woollins reagent) with NaOR (R = Me, Et, Pr-i) gives the non-symmetric phosphonodiselenoato anions [Ph(RO) PSe2](-) which can be complexed to a range of metals. The nickel complex Ni[Ph(MeO) PSe2](2) adopts a square-planar ML2 structure while the cadmium complex Cd[Ph(MeO) PSe2](2) displays a dimeric M2L4 structure. Two different lead complexes are observed, one consisting of PbL2 units joined by Pb center dot center dot center dot Se interactions to form distinct dimeric pairs. The other displays a novel dimeric structure built around a central four-membered Pb2Se2 ring. All new compounds have been characterised spectroscopically (P-31, H-1, C-13 NMR, IR, mass spectroscopy), by elemental analysis and five demonstrative X-ray structures are reported.

AB - Reaction of (PhPSe2)(2) (Woollins reagent) with NaOR (R = Me, Et, Pr-i) gives the non-symmetric phosphonodiselenoato anions [Ph(RO) PSe2](-) which can be complexed to a range of metals. The nickel complex Ni[Ph(MeO) PSe2](2) adopts a square-planar ML2 structure while the cadmium complex Cd[Ph(MeO) PSe2](2) displays a dimeric M2L4 structure. Two different lead complexes are observed, one consisting of PbL2 units joined by Pb center dot center dot center dot Se interactions to form distinct dimeric pairs. The other displays a novel dimeric structure built around a central four-membered Pb2Se2 ring. All new compounds have been characterised spectroscopically (P-31, H-1, C-13 NMR, IR, mass spectroscopy), by elemental analysis and five demonstrative X-ray structures are reported.

KW - RAY CRYSTAL-STRUCTURE

KW - CU-8(I) CUBIC CLUSTERS

KW - LAWESSONS REAGENT

KW - DISELENOPHOSPHATE LIGANDS

KW - COORDINATION CHEMISTRY

KW - METAL-COMPLEXES

KW - RARE EXAMPLE

KW - PR-I

KW - PHOSPHORUS

KW - SELENIUM

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DO - 10.1039/B503793J

M3 - Article

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SP - 2188

EP - 2194

JO - Dalton Transactions

JF - Dalton Transactions

IS - 12

ER -

Synthesis and structure of novel [Ph(RO)PSe2](-) complexes

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Keywords

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