Synthesis and structure of new phosphines containing PN bonds

Mireia i Zubiri; Heather Milton; Alexandra Martha Zoya Slawin; John Derek Woollins

doi:10.1016/j.ica.2003.10.028

Synthesis and structure of new phosphines containing PN bonds

Mireia i Zubiri, Heather Milton, Alexandra Martha Zoya Slawin, John Derek Woollins

Research output: Contribution to journal › Article › peer-review

14 Citations (Scopus)

Abstract

New phosphines containing the homopiperazine backbone have been prepared. The X-ray structure of the P(III) phosphine and its P(V) sulphide are compared. The P-N bond length is shortened on oxidation from P(III) to P(V). (C) 2003 Elsevier B.V. All rights reserved.

Original language	English
Pages (from-to)	1243-1246
Number of pages	4
Journal	Inorganica Chimica Acta
Volume	357
Issue number	4
DOIs	https://doi.org/10.1016/j.ica.2003.10.028
Publication status	Published - 10 Mar 2004

Keywords

RHODIUM-CATALYZED HYDROFORMYLATION
COORDINATION CHEMISTRY
LIGANDS
DERIVATIVES
COMPLEXES
MECHANISM
BULKY
CARBONYLATION
DIPHOSPHINES
SELECTIVITY

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10.1016/j.ica.2003.10.028

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title = "Synthesis and structure of new phosphines containing PN bonds",

abstract = "New phosphines containing the homopiperazine backbone have been prepared. The X-ray structure of the P(III) phosphine and its P(V) sulphide are compared. The P-N bond length is shortened on oxidation from P(III) to P(V). (C) 2003 Elsevier B.V. All rights reserved.",

keywords = "RHODIUM-CATALYZED HYDROFORMYLATION, COORDINATION CHEMISTRY, LIGANDS, DERIVATIVES, COMPLEXES, MECHANISM, BULKY, CARBONYLATION, DIPHOSPHINES, SELECTIVITY",

author = "{i Zubiri}, Mireia and Heather Milton and Slawin, {Alexandra Martha Zoya} and Woollins, {John Derek}",

year = "2004",

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doi = "10.1016/j.ica.2003.10.028",

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journal = "Inorganica Chimica Acta",

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T1 - Synthesis and structure of new phosphines containing PN bonds

AU - i Zubiri, Mireia

AU - Milton, Heather

AU - Slawin, Alexandra Martha Zoya

AU - Woollins, John Derek

PY - 2004/3/10

Y1 - 2004/3/10

N2 - New phosphines containing the homopiperazine backbone have been prepared. The X-ray structure of the P(III) phosphine and its P(V) sulphide are compared. The P-N bond length is shortened on oxidation from P(III) to P(V). (C) 2003 Elsevier B.V. All rights reserved.

AB - New phosphines containing the homopiperazine backbone have been prepared. The X-ray structure of the P(III) phosphine and its P(V) sulphide are compared. The P-N bond length is shortened on oxidation from P(III) to P(V). (C) 2003 Elsevier B.V. All rights reserved.

KW - RHODIUM-CATALYZED HYDROFORMYLATION

KW - COORDINATION CHEMISTRY

KW - LIGANDS

KW - DERIVATIVES

KW - COMPLEXES

KW - MECHANISM

KW - BULKY

KW - CARBONYLATION

KW - DIPHOSPHINES

KW - SELECTIVITY

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DO - 10.1016/j.ica.2003.10.028

M3 - Article

SN - 0020-1693

VL - 357

SP - 1243

EP - 1246

JO - Inorganica Chimica Acta

JF - Inorganica Chimica Acta

IS - 4

ER -

Synthesis and structure of new phosphines containing PN bonds

Abstract

Keywords

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