Synthesis and Structure of [Fc(EtO)PS2]- Complexes

IP Gray; Alexandra Martha Zoya Slawin; John Derek Woollins

doi:10.1002/zaac.200400161

Synthesis and Structure of [Fc(EtO)PS₂]- Complexes

IP Gray, Alexandra Martha Zoya Slawin, John Derek Woollins

Research output: Contribution to journal › Article › peer-review

Abstract

Reaction of Fc(S)PS2P(S)Fc with NaOEt gives the non symmetric phosphonodithioato anion [Fc(EtO)PS2](-) which can be complexed to a range of metal ions. The group 10 metals (Ni, Pd and Pt) adopt [ML2] complexes with square planar coordination. The first known mercury phosphonodithioate complex is shown to adopt a unique dimeric [M2L4] structure. A new structural motif for lead phosphonodithioate complexes is reported consisting of [PbL2] units joined by (PhS)-S-... interactions to form distinct dimeric pairs. All new compounds have been characterized spectroscopically and four demonstrative X-ray structures are reported.

Original language	English
Pages (from-to)	1851-1857
Number of pages	7
Journal	Zeitschrift für Anorganische und Allgemeine Chemie
Volume	630
Issue number	12
DOIs	https://doi.org/10.1002/zaac.200400161
Publication status	Published - 2004

Keywords

ferrocenylphosphonodithioata metal compounds
X-RAY CRYSTAL
PHOSPHOR-1,1-DITHIOLATO METAL-COMPLEXES
PHOSPHORUS-ACID-DERIVATIVES
SINGLE-SOURCE PRECURSORS
BICYCLIC DIMER HELD
MOLECULAR-STRUCTURE
SUPRAMOLECULAR ASSOCIATIONS
STEREOCHEMICAL ASPECTS
COORDINATION PATTERNS
LAWESSONS REAGENT

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10.1002/zaac.200400161

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title = "Synthesis and Structure of [Fc(EtO)PS2]- Complexes",

abstract = "Reaction of Fc(S)PS2P(S)Fc with NaOEt gives the non symmetric phosphonodithioato anion [Fc(EtO)PS2](-) which can be complexed to a range of metal ions. The group 10 metals (Ni, Pd and Pt) adopt [ML2] complexes with square planar coordination. The first known mercury phosphonodithioate complex is shown to adopt a unique dimeric [M2L4] structure. A new structural motif for lead phosphonodithioate complexes is reported consisting of [PbL2] units joined by (PhS)-S-... interactions to form distinct dimeric pairs. All new compounds have been characterized spectroscopically and four demonstrative X-ray structures are reported.",

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author = "IP Gray and Slawin, {Alexandra Martha Zoya} and Woollins, {John Derek}",

year = "2004",

doi = "10.1002/zaac.200400161",

language = "English",

volume = "630",

pages = "1851--1857",

journal = "Zeitschrift f{\"u}r Anorganische und Allgemeine Chemie",

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number = "12",

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TY - JOUR

T1 - Synthesis and Structure of [Fc(EtO)PS2]- Complexes

AU - Gray, IP

AU - Slawin, Alexandra Martha Zoya

AU - Woollins, John Derek

PY - 2004

Y1 - 2004

N2 - Reaction of Fc(S)PS2P(S)Fc with NaOEt gives the non symmetric phosphonodithioato anion [Fc(EtO)PS2](-) which can be complexed to a range of metal ions. The group 10 metals (Ni, Pd and Pt) adopt [ML2] complexes with square planar coordination. The first known mercury phosphonodithioate complex is shown to adopt a unique dimeric [M2L4] structure. A new structural motif for lead phosphonodithioate complexes is reported consisting of [PbL2] units joined by (PhS)-S-... interactions to form distinct dimeric pairs. All new compounds have been characterized spectroscopically and four demonstrative X-ray structures are reported.

AB - Reaction of Fc(S)PS2P(S)Fc with NaOEt gives the non symmetric phosphonodithioato anion [Fc(EtO)PS2](-) which can be complexed to a range of metal ions. The group 10 metals (Ni, Pd and Pt) adopt [ML2] complexes with square planar coordination. The first known mercury phosphonodithioate complex is shown to adopt a unique dimeric [M2L4] structure. A new structural motif for lead phosphonodithioate complexes is reported consisting of [PbL2] units joined by (PhS)-S-... interactions to form distinct dimeric pairs. All new compounds have been characterized spectroscopically and four demonstrative X-ray structures are reported.

KW - ferrocenylphosphonodithioata metal compounds

KW - X-RAY CRYSTAL

KW - PHOSPHOR-1,1-DITHIOLATO METAL-COMPLEXES

KW - PHOSPHORUS-ACID-DERIVATIVES

KW - SINGLE-SOURCE PRECURSORS

KW - BICYCLIC DIMER HELD

KW - MOLECULAR-STRUCTURE

KW - SUPRAMOLECULAR ASSOCIATIONS

KW - STEREOCHEMICAL ASPECTS

KW - COORDINATION PATTERNS

KW - LAWESSONS REAGENT

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U2 - 10.1002/zaac.200400161

DO - 10.1002/zaac.200400161

M3 - Article

SN - 0044-2313

VL - 630

SP - 1851

EP - 1857

JO - Zeitschrift für Anorganische und Allgemeine Chemie

JF - Zeitschrift für Anorganische und Allgemeine Chemie

IS - 12

ER -

Synthesis and Structure of [Fc(EtO)PS₂]- Complexes

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