Synthesis and structure of [An(RO)PS2](-) complexes

I P  Gray; A M Z  Slawin; J D  Woollins

doi:10.1039/B406411A

Synthesis and structure of [An(RO)PS2](-) complexes

I P Gray, A M Z Slawin, J D Woollins

Research output: Contribution to journal › Article › peer-review

Abstract

Reaction of An(S)PS2P(S)An with NaOR [R = Me, Et, Pr-i] gives the non-symmetric phosphonodithioato anions [An(RO)PS2](-) which can be complexed to a range of metals. The group 10 metals (Ni, Pd and Pt) adopt square planar ML2 complexes. The zinc and cadmium complexes adopt isostructural dimeric M2L4 structures whilst mercury complexes adopt a subtly different dimeric motif. Two distinctly different lead complexes are reported, one consisting of PbL2 units joined by Pb...S interactions to form distinct dimeric pairs, the other being a completely new structural motif for complexes of this type, PbL2 units held together by covalently bonded bridging ligands to form an infinite polymeric chain structure. All new compounds have been characterised spectroscopically and nine demonstrative X-ray structures are reported.

Original language	English
Pages (from-to)	2477-2486
Number of pages	10
Journal	Dalton Transactions
Issue number	16
DOIs	https://doi.org/10.1039/B406411A https://doi.org/10.1039/b406411a
Publication status	Published - 2004

Keywords

X-RAY CRYSTAL
PHOSPHOR-1,1-DITHIOLATO METAL-COMPLEXES
MOLECULAR-STRUCTURE
SUPRAMOLECULAR ASSOCIATIONS
SPECTROSCOPIC PROPERTIES
STEREOCHEMICAL ASPECTS
COORDINATION PATTERNS
LAWESSONS REAGENT
ZINC
O,O'-DIISOPROPYLPHOSPHORODITHIOATE

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title = "Synthesis and structure of [An(RO)PS2](-) complexes",

abstract = "Reaction of An(S)PS2P(S)An with NaOR [R = Me, Et, Pr-i] gives the non-symmetric phosphonodithioato anions [An(RO)PS2](-) which can be complexed to a range of metals. The group 10 metals (Ni, Pd and Pt) adopt square planar ML2 complexes. The zinc and cadmium complexes adopt isostructural dimeric M2L4 structures whilst mercury complexes adopt a subtly different dimeric motif. Two distinctly different lead complexes are reported, one consisting of PbL2 units joined by Pb...S interactions to form distinct dimeric pairs, the other being a completely new structural motif for complexes of this type, PbL2 units held together by covalently bonded bridging ligands to form an infinite polymeric chain structure. All new compounds have been characterised spectroscopically and nine demonstrative X-ray structures are reported.",

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author = "Gray, {I P} and Slawin, {A M Z} and Woollins, {J D}",

year = "2004",

doi = "10.1039/B406411A",

language = "English",

pages = "2477--2486",

journal = "Dalton Transactions",

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publisher = "ROYAL SOC CHEMISTRY",

number = "16",

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T1 - Synthesis and structure of [An(RO)PS2](-) complexes

AU - Gray, I P

AU - Slawin, A M Z

AU - Woollins, J D

PY - 2004

Y1 - 2004

N2 - Reaction of An(S)PS2P(S)An with NaOR [R = Me, Et, Pr-i] gives the non-symmetric phosphonodithioato anions [An(RO)PS2](-) which can be complexed to a range of metals. The group 10 metals (Ni, Pd and Pt) adopt square planar ML2 complexes. The zinc and cadmium complexes adopt isostructural dimeric M2L4 structures whilst mercury complexes adopt a subtly different dimeric motif. Two distinctly different lead complexes are reported, one consisting of PbL2 units joined by Pb...S interactions to form distinct dimeric pairs, the other being a completely new structural motif for complexes of this type, PbL2 units held together by covalently bonded bridging ligands to form an infinite polymeric chain structure. All new compounds have been characterised spectroscopically and nine demonstrative X-ray structures are reported.

AB - Reaction of An(S)PS2P(S)An with NaOR [R = Me, Et, Pr-i] gives the non-symmetric phosphonodithioato anions [An(RO)PS2](-) which can be complexed to a range of metals. The group 10 metals (Ni, Pd and Pt) adopt square planar ML2 complexes. The zinc and cadmium complexes adopt isostructural dimeric M2L4 structures whilst mercury complexes adopt a subtly different dimeric motif. Two distinctly different lead complexes are reported, one consisting of PbL2 units joined by Pb...S interactions to form distinct dimeric pairs, the other being a completely new structural motif for complexes of this type, PbL2 units held together by covalently bonded bridging ligands to form an infinite polymeric chain structure. All new compounds have been characterised spectroscopically and nine demonstrative X-ray structures are reported.

KW - X-RAY CRYSTAL

KW - PHOSPHOR-1,1-DITHIOLATO METAL-COMPLEXES

KW - MOLECULAR-STRUCTURE

KW - SUPRAMOLECULAR ASSOCIATIONS

KW - SPECTROSCOPIC PROPERTIES

KW - STEREOCHEMICAL ASPECTS

KW - COORDINATION PATTERNS

KW - LAWESSONS REAGENT

KW - ZINC

KW - O,O'-DIISOPROPYLPHOSPHORODITHIOATE

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U2 - 10.1039/B406411A

DO - 10.1039/B406411A

M3 - Article

SN - 1477-9226

SP - 2477

EP - 2486

JO - Dalton Transactions

JF - Dalton Transactions

IS - 16

ER -

Synthesis and structure of [An(RO)PS2](-) complexes

Abstract

Keywords

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