Synthesis and structure of an unusual new layered aluminophosphate containing oxalate groups, [NH3CH2CH2NH3]2.5[Al4H(HPO4)4(H2PO4)2(C2O4)4]

Philip Lightfoot; ZAD Lethbridge; Russell Edward Morris; DS Wragg; Paul Anthony Wright; A Kvick; G Vaughan

Synthesis and structure of an unusual new layered aluminophosphate containing oxalate groups, [NH₃CH₂CH₂NH₃]_2.5[Al₄H(HPO₄)₄(H₂PO₄)₂(C₂O₄)₄]

Philip Lightfoot, ZAD Lethbridge, Russell Edward Morris, DS Wragg, Paul Anthony Wright, A Kvick, G Vaughan

Research output: Contribution to journal › Article › peer-review

Abstract

The first example of an aluminophosphate containing organic anions covalently bonded to the framework of the structure is reported; [NH3CH2CH2NH3](2.5)[Al4H(HPO4)(4)(H2PO4)(2)(C2O4)(4)] was prepared hydrothermally and adopts a layered structure. The oxalate groups act as bidentate ligands to Al3+ and hold the structure together by strong interlayer P-O-H-oxalate hydrogen bonds. The structure was solved from synchrotron X-ray diffraction data collected on a very small single crystal, space group C2/m, a = 19.683(4) Angstrom, b = 12.360(3) Angstrom, c = 16.734(3) Angstrom, beta = 110.51(3)degrees. (C) 1999 Academic Press.

Original language	English
Pages (from-to)	74
Number of pages	74
Journal	Journal of Solid State Chemistry
Volume	143
Publication status	Published - 15 Feb 1999

Keywords

MOLECULAR-SIEVES
OPEN-FRAMEWORK

Cite this

@article{1f754334cccd4e35939ae5b1084952db,

title = "Synthesis and structure of an unusual new layered aluminophosphate containing oxalate groups, [NH3CH2CH2NH3]2.5[Al4H(HPO4)4(H2PO4)2(C2O4)4]",

abstract = "The first example of an aluminophosphate containing organic anions covalently bonded to the framework of the structure is reported; [NH3CH2CH2NH3](2.5)[Al4H(HPO4)(4)(H2PO4)(2)(C2O4)(4)] was prepared hydrothermally and adopts a layered structure. The oxalate groups act as bidentate ligands to Al3+ and hold the structure together by strong interlayer P-O-H-oxalate hydrogen bonds. The structure was solved from synchrotron X-ray diffraction data collected on a very small single crystal, space group C2/m, a = 19.683(4) Angstrom, b = 12.360(3) Angstrom, c = 16.734(3) Angstrom, beta = 110.51(3)degrees. (C) 1999 Academic Press.",

keywords = "MOLECULAR-SIEVES, OPEN-FRAMEWORK",

author = "Philip Lightfoot and ZAD Lethbridge and Morris, \{Russell Edward\} and DS Wragg and Wright, \{Paul Anthony\} and A Kvick and G Vaughan",

year = "1999",

month = feb,

day = "15",

language = "English",

volume = "143",

pages = "74",

journal = "Journal of Solid State Chemistry",

issn = "0022-4596",

publisher = "Academic Press/Elsevier ",

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TY - JOUR

T1 - Synthesis and structure of an unusual new layered aluminophosphate containing oxalate groups, [NH3CH2CH2NH3]2.5[Al4H(HPO4)4(H2PO4)2(C2O4)4]

AU - Lightfoot, Philip

AU - Lethbridge, ZAD

AU - Morris, Russell Edward

AU - Wragg, DS

AU - Wright, Paul Anthony

AU - Kvick, A

AU - Vaughan, G

PY - 1999/2/15

Y1 - 1999/2/15

N2 - The first example of an aluminophosphate containing organic anions covalently bonded to the framework of the structure is reported; [NH3CH2CH2NH3](2.5)[Al4H(HPO4)(4)(H2PO4)(2)(C2O4)(4)] was prepared hydrothermally and adopts a layered structure. The oxalate groups act as bidentate ligands to Al3+ and hold the structure together by strong interlayer P-O-H-oxalate hydrogen bonds. The structure was solved from synchrotron X-ray diffraction data collected on a very small single crystal, space group C2/m, a = 19.683(4) Angstrom, b = 12.360(3) Angstrom, c = 16.734(3) Angstrom, beta = 110.51(3)degrees. (C) 1999 Academic Press.

AB - The first example of an aluminophosphate containing organic anions covalently bonded to the framework of the structure is reported; [NH3CH2CH2NH3](2.5)[Al4H(HPO4)(4)(H2PO4)(2)(C2O4)(4)] was prepared hydrothermally and adopts a layered structure. The oxalate groups act as bidentate ligands to Al3+ and hold the structure together by strong interlayer P-O-H-oxalate hydrogen bonds. The structure was solved from synchrotron X-ray diffraction data collected on a very small single crystal, space group C2/m, a = 19.683(4) Angstrom, b = 12.360(3) Angstrom, c = 16.734(3) Angstrom, beta = 110.51(3)degrees. (C) 1999 Academic Press.

KW - MOLECULAR-SIEVES

KW - OPEN-FRAMEWORK

UR - https://www.scopus.com/pages/publications/0002366275

M3 - Article

SN - 0022-4596

VL - 143

SP - 74

JO - Journal of Solid State Chemistry

JF - Journal of Solid State Chemistry

ER -

Synthesis and structure of an unusual new layered aluminophosphate containing oxalate groups, [NH₃CH₂CH₂NH₃]_2.5[Al₄H(HPO₄)₄(H₂PO₄)₂(C₂O₄)₄]

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Keywords

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