Synthesis and structure of an aluminium 3-aminopropylphosphonate sulfate hydrate

N Zakowsky, PS Wheatley, I Bull, MP Attfield, Russell Edward Morris

Research output: Contribution to journalArticlepeer-review

9 Citations (Scopus)

Abstract

A new aluminium 3-aminopropylphosphonate sulfate hydrate has been prepared using hydrothermal methods, and its structure solved using microcrystal X-ray diffraction at a synchrotron source. The structure consists of one-dimensional chains of aluminium 3-aminopropylphosphonate with sulfate anions occluded between the chains. It is unusual in compounds of this type to have anionic groups between positively charged aluminium phosphonate units. Further characterisation of the compound has been carried out using magic angle spinning NMR.

Original languageEnglish
Pages (from-to)2899-2902
Number of pages4
JournalJournal of the Chemical Society, Dalton Transactions
DOIs
Publication statusPublished - 7 Oct 2001

Keywords

  • LAYERED ZIRCONIUM PHOSPHONATES
  • UNIDIMENSIONAL CHANNELS
  • PROTONIC CONDUCTIVITY
  • ALMEPO-ALPHA
  • METHYLPHOSPHONATE
  • PHENYLPHOSPHONATES
  • FAMILY
  • BETA

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