Synthesis and structure of an aluminium 3-aminopropylphosphonate sulfate hydrate

N Zakowsky; PS Wheatley; I Bull; MP Attfield; Russell Edward Morris

doi:10.1039/b103911n

Synthesis and structure of an aluminium 3-aminopropylphosphonate sulfate hydrate

N Zakowsky, PS Wheatley, I Bull, MP Attfield, Russell Edward Morris

Research output: Contribution to journal › Article › peer-review

Abstract

A new aluminium 3-aminopropylphosphonate sulfate hydrate has been prepared using hydrothermal methods, and its structure solved using microcrystal X-ray diffraction at a synchrotron source. The structure consists of one-dimensional chains of aluminium 3-aminopropylphosphonate with sulfate anions occluded between the chains. It is unusual in compounds of this type to have anionic groups between positively charged aluminium phosphonate units. Further characterisation of the compound has been carried out using magic angle spinning NMR.

Original language	English
Pages (from-to)	2899-2902
Number of pages	4
Journal	Journal of the Chemical Society, Dalton Transactions
DOIs	https://doi.org/10.1039/b103911n
Publication status	Published - 7 Oct 2001

Keywords

LAYERED ZIRCONIUM PHOSPHONATES
UNIDIMENSIONAL CHANNELS
PROTONIC CONDUCTIVITY
ALMEPO-ALPHA
METHYLPHOSPHONATE
PHENYLPHOSPHONATES
FAMILY
BETA

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title = "Synthesis and structure of an aluminium 3-aminopropylphosphonate sulfate hydrate",

abstract = "A new aluminium 3-aminopropylphosphonate sulfate hydrate has been prepared using hydrothermal methods, and its structure solved using microcrystal X-ray diffraction at a synchrotron source. The structure consists of one-dimensional chains of aluminium 3-aminopropylphosphonate with sulfate anions occluded between the chains. It is unusual in compounds of this type to have anionic groups between positively charged aluminium phosphonate units. Further characterisation of the compound has been carried out using magic angle spinning NMR.",

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author = "N Zakowsky and PS Wheatley and I Bull and MP Attfield and Morris, {Russell Edward}",

year = "2001",

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doi = "10.1039/b103911n",

language = "English",

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T1 - Synthesis and structure of an aluminium 3-aminopropylphosphonate sulfate hydrate

AU - Zakowsky, N

AU - Wheatley, PS

AU - Bull, I

AU - Attfield, MP

AU - Morris, Russell Edward

PY - 2001/10/7

Y1 - 2001/10/7

N2 - A new aluminium 3-aminopropylphosphonate sulfate hydrate has been prepared using hydrothermal methods, and its structure solved using microcrystal X-ray diffraction at a synchrotron source. The structure consists of one-dimensional chains of aluminium 3-aminopropylphosphonate with sulfate anions occluded between the chains. It is unusual in compounds of this type to have anionic groups between positively charged aluminium phosphonate units. Further characterisation of the compound has been carried out using magic angle spinning NMR.

AB - A new aluminium 3-aminopropylphosphonate sulfate hydrate has been prepared using hydrothermal methods, and its structure solved using microcrystal X-ray diffraction at a synchrotron source. The structure consists of one-dimensional chains of aluminium 3-aminopropylphosphonate with sulfate anions occluded between the chains. It is unusual in compounds of this type to have anionic groups between positively charged aluminium phosphonate units. Further characterisation of the compound has been carried out using magic angle spinning NMR.

KW - LAYERED ZIRCONIUM PHOSPHONATES

KW - UNIDIMENSIONAL CHANNELS

KW - PROTONIC CONDUCTIVITY

KW - ALMEPO-ALPHA

KW - METHYLPHOSPHONATE

KW - PHENYLPHOSPHONATES

KW - FAMILY

KW - BETA

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DO - 10.1039/b103911n

M3 - Article

SN - 1472-7773

SP - 2899

EP - 2902

JO - Journal of the Chemical Society, Dalton Transactions

JF - Journal of the Chemical Society, Dalton Transactions

ER -

Synthesis and structure of an aluminium 3-aminopropylphosphonate sulfate hydrate

Abstract

Keywords

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