Synthesis and structure of all-syn-1,2,3,4-tetrafluorocyclohexane

Alastair J. Durie; Alexandra M. Z. Slawin; Tomas Lebl; Peer Kirschb; David O'Hagan

doi:10.1039/c1cc13016a

Synthesis and structure of all-syn-1,2,3,4-tetrafluorocyclohexane

Alastair J. Durie
, Alexandra M. Z. Slawin
, Tomas Lebl
, Peer Kirschb
, David O'Hagan

Research output: Contribution to journal › Article › peer-review

Abstract

Preparation of the all-syn isomer of 1,2,3,4-tetrafluorocyclohexane is reported; X-ray structural studies shows a conformation with two of the C-F bonds oriented 1,3-diaxial to each other and F-19-NMR reveals a through space diaxial (4)J(FF) coupling constant of 29 Hz.

Original language	English
Pages (from-to)	8265-8267
Number of pages	3
Journal	Chemical Communications
Volume	47
Issue number	29
Early online date	28 Jun 2011
DOIs	https://doi.org/10.1039/c1cc13016a
Publication status	Published - 7 Aug 2011

Keywords

FLUORINE
CHEMISTRY
COMPLEX
BOND

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Enzymatic fluorination in Streptomyces: Enzymatic Fluorination in Streptomyces cattleya. Setting a framework for biotechnological development
O'Hagan, D. (PI) & Naismith, J. (CoI)
Biotechnology and Biological Sciences Research Council
1/01/08 → 31/05/12
Project: Standard

Cite this

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title = "Synthesis and structure of all-syn-1,2,3,4-tetrafluorocyclohexane",

abstract = "Preparation of the all-syn isomer of 1,2,3,4-tetrafluorocyclohexane is reported; X-ray structural studies shows a conformation with two of the C-F bonds oriented 1,3-diaxial to each other and F-19-NMR reveals a through space diaxial (4)J(FF) coupling constant of 29 Hz.",

keywords = "FLUORINE, CHEMISTRY, COMPLEX, BOND",

author = "Durie, \{Alastair J.\} and Slawin, \{Alexandra M. Z.\} and Tomas Lebl and Peer Kirschb and David O'Hagan",

year = "2011",

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doi = "10.1039/c1cc13016a",

language = "English",

volume = "47",

pages = "8265--8267",

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publisher = "Royal Society of Chemistry",

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AU - Durie, Alastair J.

AU - Slawin, Alexandra M. Z.

AU - Lebl, Tomas

AU - Kirschb, Peer

AU - O'Hagan, David

PY - 2011/8/7

Y1 - 2011/8/7

N2 - Preparation of the all-syn isomer of 1,2,3,4-tetrafluorocyclohexane is reported; X-ray structural studies shows a conformation with two of the C-F bonds oriented 1,3-diaxial to each other and F-19-NMR reveals a through space diaxial (4)J(FF) coupling constant of 29 Hz.

AB - Preparation of the all-syn isomer of 1,2,3,4-tetrafluorocyclohexane is reported; X-ray structural studies shows a conformation with two of the C-F bonds oriented 1,3-diaxial to each other and F-19-NMR reveals a through space diaxial (4)J(FF) coupling constant of 29 Hz.

KW - FLUORINE

KW - CHEMISTRY

KW - COMPLEX

KW - BOND

U2 - 10.1039/c1cc13016a

DO - 10.1039/c1cc13016a

M3 - Article

SN - 1359-7345

VL - 47

SP - 8265

EP - 8267

JO - Chemical Communications

JF - Chemical Communications

IS - 29

ER -

Synthesis and structure of all-syn-1,2,3,4-tetrafluorocyclohexane

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Keywords

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Projects

Enzymatic fluorination in Streptomyces: Enzymatic Fluorination in Streptomyces cattleya. Setting a framework for biotechnological development

Cite this