Synthesis and structure of a novel large-pore microporous magnesium-containing aluminophosphate (DAF-1)

Paul A. Wright; Richard H. Jones; Srinivasan Natarajan; Robert G. Bell; Jiesheng Chen; Michael B. Hursthouse; John Meurig Thomas

doi:10.1039/C39930000633

Synthesis and structure of a novel large-pore microporous magnesium-containing aluminophosphate (DAF-1)

Paul A. Wright^*
, Richard H. Jones
, Srinivasan Natarajan
, Robert G. Bell
, Jiesheng Chen
, Michael B. Hursthouse
, John Meurig Thomas

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

Abstract

Mg _o.22Al _o.78P0₄·0.12(C ₁₆H₃₈N₂)-xH₂0 crystallizes during hydrothermal synthesis into a unique extended three-dimensional (3-D) tetrahedrally-coordinated framework structure possessing two parallel channel systems with approximately circular aperture openings of ca. 6.1 and 7.5 Å reapectively, the latter of which contains supercages 16.3 Å in diameter; these large pores are linked perpendicularly by two types of interconnecting apertures, the minimum diameter of one of which is ca. 3.9 and that of the other 5.4 Å.

Original language	English
Pages (from-to)	633-635
Number of pages	3
Journal	Journal of the Chemical Society, Chemical Communications
Issue number	7
DOIs	https://doi.org/10.1039/C39930000633
Publication status	Published - 1 Dec 1993

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@article{409046b9cdb7467a829aec96b500af83,

title = "Synthesis and structure of a novel large-pore microporous magnesium-containing aluminophosphate (DAF-1)",

abstract = "Mg o.22Al o.78P04·0.12(C 16H38N2)-xH20 crystallizes during hydrothermal synthesis into a unique extended three-dimensional (3-D) tetrahedrally-coordinated framework structure possessing two parallel channel systems with approximately circular aperture openings of ca. 6.1 and 7.5 {\AA} reapectively, the latter of which contains supercages 16.3 {\AA} in diameter; these large pores are linked perpendicularly by two types of interconnecting apertures, the minimum diameter of one of which is ca. 3.9 and that of the other 5.4 {\AA}.",

author = "Wright, \{Paul A.\} and Jones, \{Richard H.\} and Srinivasan Natarajan and Bell, \{Robert G.\} and Jiesheng Chen and Hursthouse, \{Michael B.\} and Thomas, \{John Meurig\}",

year = "1993",

month = dec,

day = "1",

doi = "10.1039/C39930000633",

language = "English",

pages = "633--635",

journal = "Journal of the Chemical Society, Chemical Communications",

issn = "0022-4936",

publisher = "Chemical Society",

number = "7",

}

TY - JOUR

T1 - Synthesis and structure of a novel large-pore microporous magnesium-containing aluminophosphate (DAF-1)

AU - Wright, Paul A.

AU - Jones, Richard H.

AU - Natarajan, Srinivasan

AU - Bell, Robert G.

AU - Chen, Jiesheng

AU - Hursthouse, Michael B.

AU - Thomas, John Meurig

PY - 1993/12/1

Y1 - 1993/12/1

N2 - Mg o.22Al o.78P04·0.12(C 16H38N2)-xH20 crystallizes during hydrothermal synthesis into a unique extended three-dimensional (3-D) tetrahedrally-coordinated framework structure possessing two parallel channel systems with approximately circular aperture openings of ca. 6.1 and 7.5 Å reapectively, the latter of which contains supercages 16.3 Å in diameter; these large pores are linked perpendicularly by two types of interconnecting apertures, the minimum diameter of one of which is ca. 3.9 and that of the other 5.4 Å.

AB - Mg o.22Al o.78P04·0.12(C 16H38N2)-xH20 crystallizes during hydrothermal synthesis into a unique extended three-dimensional (3-D) tetrahedrally-coordinated framework structure possessing two parallel channel systems with approximately circular aperture openings of ca. 6.1 and 7.5 Å reapectively, the latter of which contains supercages 16.3 Å in diameter; these large pores are linked perpendicularly by two types of interconnecting apertures, the minimum diameter of one of which is ca. 3.9 and that of the other 5.4 Å.

UR - https://www.scopus.com/pages/publications/37049075177

U2 - 10.1039/C39930000633

DO - 10.1039/C39930000633

M3 - Article

AN - SCOPUS:37049075177

SN - 0022-4936

SP - 633

EP - 635

JO - Journal of the Chemical Society, Chemical Communications

JF - Journal of the Chemical Society, Chemical Communications

IS - 7

ER -

Synthesis and structure of a novel large-pore microporous magnesium-containing aluminophosphate (DAF-1)

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