Synthesis and structural studies of [(H2NPPh2)2N]+[N{P(S)Ph2}2]

Tuan Q Ly; Alexandra Martha Zoya Slawin; John Derek Woollins

Synthesis and structural studies of [(H₂NPPh₂)₂N]+[N{P(S)Ph₂}₂]

Tuan Q Ly, Alexandra Martha Zoya Slawin, John Derek Woollins

Research output: Other contribution

Abstract

K[N{P(S)Ph-2}(2)], K[N{P(O)Ph-2}(2)], K[PhC(O)NP(S)Ph-2] and K[(C5H4N)C(S)NP(S)Ph-2] were reacted with [(H2NPPh2)(2)N]Cl-+(-) to give [(H2NPPh2)(2)N](+) [N{P(S)Ph-2}2](-), [(H2NPPh2)(2)N](+) [N{P(O)Ph-2}(2)](-) [(H2NPPh2)(2)N](+) [PhC(O)NP(S)Ph-2](-) and [(H2NPPh2)(2)N](+) [C5H4NC(S)-NP(S)Ph-2](-) respectively. Single crystal X-ray studies of [(H2NPPh2)(2)N](+) [N(P(S)Ph-2}(2)](-) reveal multiple cross hydrogen bonding between the two ions.

Original language	English
Volume	3
Publication status	Published - 2000

Keywords

CRYSTAL-STRUCTURE
MOLECULAR-STRUCTURE
CATION
ARYL
ACID

Cite this

@misc{dd3375da1051479d86fbd303e795670e,

title = "Synthesis and structural studies of [(H2NPPh2)2N]+[N{P(S)Ph2}2]",

abstract = "K[N{P(S)Ph-2}(2)], K[N{P(O)Ph-2}(2)], K[PhC(O)NP(S)Ph-2] and K[(C5H4N)C(S)NP(S)Ph-2] were reacted with [(H2NPPh2)(2)N]Cl-+(-) to give [(H2NPPh2)(2)N](+) [N{P(S)Ph-2}2](-), [(H2NPPh2)(2)N](+) [N{P(O)Ph-2}(2)](-) [(H2NPPh2)(2)N](+) [PhC(O)NP(S)Ph-2](-) and [(H2NPPh2)(2)N](+) [C5H4NC(S)-NP(S)Ph-2](-) respectively. Single crystal X-ray studies of [(H2NPPh2)(2)N](+) [N(P(S)Ph-2}(2)](-) reveal multiple cross hydrogen bonding between the two ions.",

keywords = "CRYSTAL-STRUCTURE, MOLECULAR-STRUCTURE, CATION, ARYL, ACID",

author = "Ly, {Tuan Q} and Slawin, {Alexandra Martha Zoya} and Woollins, {John Derek}",

note = "Main Group Chemistry",

year = "2000",

language = "English",

volume = "3",

type = "Other",

}

TY - GEN

T1 - Synthesis and structural studies of [(H2NPPh2)2N]+[N{P(S)Ph2}2]

AU - Ly, Tuan Q

AU - Slawin, Alexandra Martha Zoya

AU - Woollins, John Derek

N1 - Main Group Chemistry

PY - 2000

Y1 - 2000

N2 - K[N{P(S)Ph-2}(2)], K[N{P(O)Ph-2}(2)], K[PhC(O)NP(S)Ph-2] and K[(C5H4N)C(S)NP(S)Ph-2] were reacted with [(H2NPPh2)(2)N]Cl-+(-) to give [(H2NPPh2)(2)N](+) [N{P(S)Ph-2}2](-), [(H2NPPh2)(2)N](+) [N{P(O)Ph-2}(2)](-) [(H2NPPh2)(2)N](+) [PhC(O)NP(S)Ph-2](-) and [(H2NPPh2)(2)N](+) [C5H4NC(S)-NP(S)Ph-2](-) respectively. Single crystal X-ray studies of [(H2NPPh2)(2)N](+) [N(P(S)Ph-2}(2)](-) reveal multiple cross hydrogen bonding between the two ions.

AB - K[N{P(S)Ph-2}(2)], K[N{P(O)Ph-2}(2)], K[PhC(O)NP(S)Ph-2] and K[(C5H4N)C(S)NP(S)Ph-2] were reacted with [(H2NPPh2)(2)N]Cl-+(-) to give [(H2NPPh2)(2)N](+) [N{P(S)Ph-2}2](-), [(H2NPPh2)(2)N](+) [N{P(O)Ph-2}(2)](-) [(H2NPPh2)(2)N](+) [PhC(O)NP(S)Ph-2](-) and [(H2NPPh2)(2)N](+) [C5H4NC(S)-NP(S)Ph-2](-) respectively. Single crystal X-ray studies of [(H2NPPh2)(2)N](+) [N(P(S)Ph-2}(2)](-) reveal multiple cross hydrogen bonding between the two ions.

KW - CRYSTAL-STRUCTURE

KW - MOLECULAR-STRUCTURE

KW - CATION

KW - ARYL

KW - ACID

M3 - Other contribution

VL - 3

ER -

Synthesis and structural studies of [(H2NPPh2)2N]+[N{P(S)Ph2}2]

Abstract

Keywords

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Synthesis and structural studies of [(H₂NPPh₂)₂N]+[N{P(S)Ph₂}₂]