SYNTHESIS AND STRUCTURAL CHARACTERIZATION OF THE TRINUCLEAR BARIUM DISILOXANES [BA3(OSIPH2OSIPH2O)3(TETRAGLYME)2] AND [BA3(OSIPH2OSIPH2O)3(HMPA)5(H2O)], CONTAINING AN UNUSUAL BA3O7 CORE [TETRAGLYME = ME(OCH2CH2)4OME, HMPA = (ME2N)3P=O]

J A  DARR; S R  DRAKE; D J  WILLIAMS; A M Z  SLAWIN

SYNTHESIS AND STRUCTURAL CHARACTERIZATION OF THE TRINUCLEAR BARIUM DISILOXANES [BA3(OSIPH2OSIPH2O)3(TETRAGLYME)2] AND [BA3(OSIPH2OSIPH2O)3(HMPA)5(H2O)], CONTAINING AN UNUSUAL BA3O7 CORE [TETRAGLYME = ME(OCH2CH2)4OME, HMPA = (ME2N)3P=O]

J A DARR, S R DRAKE, D J WILLIAMS, A M Z SLAWIN

Research output: Contribution to journal › Article › peer-review

Abstract

Barium granules react with diphenylsilanediol in a mixed ammonia-toluene solution at -40-degrees-C to yield [Ba(OSiPh2OSiPh2O)(H2O)(NH3)0.33] 1, addition of either tetraglyme or hexamethylphosphoramide (hmpa) produces [Ba3(OSiPh2OSiPh2O)3(tetraglyme)2] 2 and [Ba3(OSiPh2OSiPh2O)3(hmpa)5(H2O)] 3, respectively; complexes 2 and 3 are the first X-ray structurally characterised barium disiloxanes and contain an unusual trinuclear array of Ba cations incorporating an identical Ba3O7 core.

Original language	English
Pages (from-to)	866-868
Number of pages	3
Journal	Journal of the Chemical Society, Chemical Communications
Issue number	10
Publication status	Published - 21 May 1993

Keywords

CRYSTAL

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DARR, J. A., DRAKE, S. R., WILLIAMS, D. J., & SLAWIN, A. M. Z. (1993). SYNTHESIS AND STRUCTURAL CHARACTERIZATION OF THE TRINUCLEAR BARIUM DISILOXANES [BA3(OSIPH2OSIPH2O)3(TETRAGLYME)2] AND [BA3(OSIPH2OSIPH2O)3(HMPA)5(H2O)], CONTAINING AN UNUSUAL BA3O7 CORE [TETRAGLYME = ME(OCH2CH2)4OME, HMPA = (ME2N)3P=O]. Journal of the Chemical Society, Chemical Communications, (10), 866-868.

DARR, J A ; DRAKE, S R ; WILLIAMS, D J et al. / SYNTHESIS AND STRUCTURAL CHARACTERIZATION OF THE TRINUCLEAR BARIUM DISILOXANES [BA3(OSIPH2OSIPH2O)3(TETRAGLYME)2] AND [BA3(OSIPH2OSIPH2O)3(HMPA)5(H2O)], CONTAINING AN UNUSUAL BA3O7 CORE [TETRAGLYME = ME(OCH2CH2)4OME, HMPA = (ME2N)3P=O]. In: Journal of the Chemical Society, Chemical Communications. 1993 ; No. 10. pp. 866-868.

@article{72557be1807b44d983487f83de1bf686,

title = "SYNTHESIS AND STRUCTURAL CHARACTERIZATION OF THE TRINUCLEAR BARIUM DISILOXANES [BA3(OSIPH2OSIPH2O)3(TETRAGLYME)2] AND [BA3(OSIPH2OSIPH2O)3(HMPA)5(H2O)], CONTAINING AN UNUSUAL BA3O7 CORE [TETRAGLYME = ME(OCH2CH2)4OME, HMPA = (ME2N)3P=O]",

abstract = "Barium granules react with diphenylsilanediol in a mixed ammonia-toluene solution at -40-degrees-C to yield [Ba(OSiPh2OSiPh2O)(H2O)(NH3)0.33] 1, addition of either tetraglyme or hexamethylphosphoramide (hmpa) produces [Ba3(OSiPh2OSiPh2O)3(tetraglyme)2] 2 and [Ba3(OSiPh2OSiPh2O)3(hmpa)5(H2O)] 3, respectively; complexes 2 and 3 are the first X-ray structurally characterised barium disiloxanes and contain an unusual trinuclear array of Ba cations incorporating an identical Ba3O7 core.",

keywords = "CRYSTAL",

author = "DARR, {J A} and DRAKE, {S R} and WILLIAMS, {D J} and SLAWIN, {A M Z}",

year = "1993",

month = may,

day = "21",

language = "English",

pages = "866--868",

journal = "Journal of the Chemical Society, Chemical Communications",

issn = "0022-4936",

publisher = "Chemical Society",

number = "10",

}

DARR, JA, DRAKE, SR, WILLIAMS, DJ & SLAWIN, AMZ 1993, 'SYNTHESIS AND STRUCTURAL CHARACTERIZATION OF THE TRINUCLEAR BARIUM DISILOXANES [BA3(OSIPH2OSIPH2O)3(TETRAGLYME)2] AND [BA3(OSIPH2OSIPH2O)3(HMPA)5(H2O)], CONTAINING AN UNUSUAL BA3O7 CORE [TETRAGLYME = ME(OCH2CH2)4OME, HMPA = (ME2N)3P=O]', Journal of the Chemical Society, Chemical Communications, no. 10, pp. 866-868.

SYNTHESIS AND STRUCTURAL CHARACTERIZATION OF THE TRINUCLEAR BARIUM DISILOXANES [BA3(OSIPH2OSIPH2O)3(TETRAGLYME)2] AND [BA3(OSIPH2OSIPH2O)3(HMPA)5(H2O)], CONTAINING AN UNUSUAL BA3O7 CORE [TETRAGLYME = ME(OCH2CH2)4OME, HMPA = (ME2N)3P=O]. / DARR, J A ; DRAKE, S R ; WILLIAMS, D J et al.
In: Journal of the Chemical Society, Chemical Communications, No. 10, 21.05.1993, p. 866-868.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - SYNTHESIS AND STRUCTURAL CHARACTERIZATION OF THE TRINUCLEAR BARIUM DISILOXANES [BA3(OSIPH2OSIPH2O)3(TETRAGLYME)2] AND [BA3(OSIPH2OSIPH2O)3(HMPA)5(H2O)], CONTAINING AN UNUSUAL BA3O7 CORE [TETRAGLYME = ME(OCH2CH2)4OME, HMPA = (ME2N)3P=O]

AU - DARR, J A

AU - DRAKE, S R

AU - WILLIAMS, D J

AU - SLAWIN, A M Z

PY - 1993/5/21

Y1 - 1993/5/21

N2 - Barium granules react with diphenylsilanediol in a mixed ammonia-toluene solution at -40-degrees-C to yield [Ba(OSiPh2OSiPh2O)(H2O)(NH3)0.33] 1, addition of either tetraglyme or hexamethylphosphoramide (hmpa) produces [Ba3(OSiPh2OSiPh2O)3(tetraglyme)2] 2 and [Ba3(OSiPh2OSiPh2O)3(hmpa)5(H2O)] 3, respectively; complexes 2 and 3 are the first X-ray structurally characterised barium disiloxanes and contain an unusual trinuclear array of Ba cations incorporating an identical Ba3O7 core.

AB - Barium granules react with diphenylsilanediol in a mixed ammonia-toluene solution at -40-degrees-C to yield [Ba(OSiPh2OSiPh2O)(H2O)(NH3)0.33] 1, addition of either tetraglyme or hexamethylphosphoramide (hmpa) produces [Ba3(OSiPh2OSiPh2O)3(tetraglyme)2] 2 and [Ba3(OSiPh2OSiPh2O)3(hmpa)5(H2O)] 3, respectively; complexes 2 and 3 are the first X-ray structurally characterised barium disiloxanes and contain an unusual trinuclear array of Ba cations incorporating an identical Ba3O7 core.

KW - CRYSTAL

M3 - Article

SN - 0022-4936

SP - 866

EP - 868

JO - Journal of the Chemical Society, Chemical Communications

JF - Journal of the Chemical Society, Chemical Communications

IS - 10

ER -