Synthesis and structural characterization of a single-crystal to single-crystal transformable coordination polymer

Yuyang Tian; Phoebe K. Allan; Catherine L. Renouf; Xiang He; Laura J. McCormick; Russell E. Morris

doi:10.1039/c3dt52579a

Synthesis and structural characterization of a single-crystal to single-crystal transformable coordination polymer

Yuyang Tian, Phoebe K. Allan, Catherine L. Renouf, Xiang He, Laura J. McCormick, Russell E. Morris^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

Abstract

A single-crystal to single-crystal transformable coordination polymer compound was hydrothermally synthesized. The structural rearrangement is induced by selecting a ligand that contains both strong and weaker coordinating groups. Both hydrated and dehydrated structures were determined by single crystal X-ray analysis.

Original language	English
Pages (from-to)	1519-1523
Number of pages	5
Journal	Dalton Transactions
Volume	43
Issue number	4
Early online date	13 Nov 2013
DOIs	https://doi.org/10.1039/c3dt52579a
Publication status	Published - 2014

Keywords

Metal organic framework
Adsorption
Hydrogen
Dehydration
Selectivity
Mechanism
Storage

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10.1039/c3dt52579a

Yuyang_dalton_revised
© 2014, The Royal Society of Chemistry.
Accepted author manuscript, 1.98 MB

Assembly Disassembly Reassembly: Assembly disassembly reassembly - New routes to extended structures and their impact
Morris, R. E. (PI)
EPSRC
1/08/13 → 31/07/18
Project: Fellowship
Hemilabile switchable metal-organic: Hemilabile and switchable metal-organic frameworks
Morris, R. E. (PI)
EPSRC
1/03/13 → 28/02/16
Project: Standard

Cite this

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title = "Synthesis and structural characterization of a single-crystal to single-crystal transformable coordination polymer",

abstract = "A single-crystal to single-crystal transformable coordination polymer compound was hydrothermally synthesized. The structural rearrangement is induced by selecting a ligand that contains both strong and weaker coordinating groups. Both hydrated and dehydrated structures were determined by single crystal X-ray analysis.",

keywords = "Metal organic framework, Adsorption, Hydrogen, Dehydration , Selectivity, Mechanism, Storage",

author = "Yuyang Tian and Allan, {Phoebe K.} and Renouf, {Catherine L.} and Xiang He and McCormick, {Laura J.} and Morris, {Russell E.}",

year = "2014",

doi = "10.1039/c3dt52579a",

language = "English",

volume = "43",

pages = "1519--1523",

journal = "Dalton Transactions",

issn = "1477-9226",

publisher = "ROYAL SOC CHEMISTRY",

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T1 - Synthesis and structural characterization of a single-crystal to single-crystal transformable coordination polymer

AU - Tian, Yuyang

AU - Allan, Phoebe K.

AU - Renouf, Catherine L.

AU - He, Xiang

AU - McCormick, Laura J.

AU - Morris, Russell E.

PY - 2014

Y1 - 2014

N2 - A single-crystal to single-crystal transformable coordination polymer compound was hydrothermally synthesized. The structural rearrangement is induced by selecting a ligand that contains both strong and weaker coordinating groups. Both hydrated and dehydrated structures were determined by single crystal X-ray analysis.

AB - A single-crystal to single-crystal transformable coordination polymer compound was hydrothermally synthesized. The structural rearrangement is induced by selecting a ligand that contains both strong and weaker coordinating groups. Both hydrated and dehydrated structures were determined by single crystal X-ray analysis.

KW - Metal organic framework

KW - Adsorption

KW - Hydrogen

KW - Dehydration

KW - Selectivity

KW - Mechanism

KW - Storage

U2 - 10.1039/c3dt52579a

DO - 10.1039/c3dt52579a

M3 - Article

SN - 1477-9226

VL - 43

SP - 1519

EP - 1523

JO - Dalton Transactions

JF - Dalton Transactions

IS - 4

ER -

Synthesis and structural characterization of a single-crystal to single-crystal transformable coordination polymer

Abstract

Keywords

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Projects

Assembly Disassembly Reassembly: Assembly disassembly reassembly - New routes to extended structures and their impact

Hemilabile switchable metal-organic: Hemilabile and switchable metal-organic frameworks

Cite this