Synthesis and structural characterisation of the copper MOF: STAM-NMe2

Lauren N. McHugh; Leonardo Olivera Perez; Paul S. Wheatley; David B. Cordes; Alexandra M. Z. Slawin; Russell E. Morris

doi:10.1039/C9CE01035A

Synthesis and structural characterisation of the copper MOF: STAM-NMe2

Lauren N. McHugh, Leonardo Olivera Perez, Paul S. Wheatley, David B. Cordes, Alexandra M. Z. Slawin, Russell E. Morris

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Abstract

Here we demonstrate the synthesis and structural characterisation of a novel copper MOF: STAM-NMe₂, developed using the linker 5-dimethylamino isophthalic acid. The material is a member of the STAM series of MOFs, with a Kagome lattice structure and contains two types of pore system. The structure was investigated using single crystal X-ray diffraction, variable temperature powder X-ray diffraction was used to determine the thermal stability of the MOF, and nitrogen BET adsorption was employed to determine the porosity of the material.

Original language	English
Pages (from-to)	5387-5391
Journal	CrystEngComm
Volume	21
Issue number	36
Early online date	23 Aug 2019
DOIs	https://doi.org/10.1039/C9CE01035A
Publication status	Published - 28 Sept 2019

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10.1039/C9CE01035A

CrystEngComm_template_L.N.McHugh_revised
Copyright © 2019 The Author(s). This work has been made available online in accordance with publisher policies or with permission. Permission for further reuse of this content should be sought from the publisher or the rights holder. This is the author created accepted manuscript following peer review and may differ slightly from the final published version. The final published version of this work is available at https://doi.org/10.1039/C9CE01035A
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Synthesis and structural characterisation of the copper MOF: STAM-NMe2 (dataset 2)
McHugh, L. N. (Creator), Perez, L. O. (Creator), Wheatley, P. S. (Creator), Cordes, D. B. (Creator), Slawin, A. M. Z. (Creator) & Morris, R. E. (Creator), University of St Andrews, 2019
DOI: 10.17630/e2eed9cf-617b-4e7b-bb0b-578b95879833
Dataset

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Synthesis and structural characterisation of the copper MOF: STAM-NMe2 (dataset)
McHugh, L. N. (Creator), Perez, L. O. (Creator), Wheatley, P. S. (Creator), Cordes, D. B. (Creator), Slawin, A. M. Z. (Creator) & Morris, R. E. (Creator), Cambridge Crystallographic Data Centre, 2019
https://dx.doi.org/10.5517/ccdc.csd.cc231q1y
Dataset

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title = "Synthesis and structural characterisation of the copper MOF: STAM-NMe2",

abstract = "Here we demonstrate the synthesis and structural characterisation of a novel copper MOF: STAM-NMe2, developed using the linker 5-dimethylamino isophthalic acid. The material is a member of the STAM series of MOFs, with a Kagome lattice structure and contains two types of pore system. The structure was investigated using single crystal X-ray diffraction, variable temperature powder X-ray diffraction was used to determine the thermal stability of the MOF, and nitrogen BET adsorption was employed to determine the porosity of the material. ",

author = "McHugh, {Lauren N.} and {Olivera Perez}, Leonardo and Wheatley, {Paul S.} and Cordes, {David B.} and Slawin, {Alexandra M. Z.} and Morris, {Russell E.}",

note = "The authors would like to acknowledge the financial support from the EPSRC industrial CASE award (grant EP/N50936X/1).",

year = "2019",

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doi = "10.1039/C9CE01035A",

language = "English",

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T1 - Synthesis and structural characterisation of the copper MOF

T2 - STAM-NMe2

AU - McHugh, Lauren N.

AU - Olivera Perez, Leonardo

AU - Wheatley, Paul S.

AU - Cordes, David B.

AU - Slawin, Alexandra M. Z.

AU - Morris, Russell E.

N1 - The authors would like to acknowledge the financial support from the EPSRC industrial CASE award (grant EP/N50936X/1).

PY - 2019/9/28

Y1 - 2019/9/28

N2 - Here we demonstrate the synthesis and structural characterisation of a novel copper MOF: STAM-NMe2, developed using the linker 5-dimethylamino isophthalic acid. The material is a member of the STAM series of MOFs, with a Kagome lattice structure and contains two types of pore system. The structure was investigated using single crystal X-ray diffraction, variable temperature powder X-ray diffraction was used to determine the thermal stability of the MOF, and nitrogen BET adsorption was employed to determine the porosity of the material.

AB - Here we demonstrate the synthesis and structural characterisation of a novel copper MOF: STAM-NMe2, developed using the linker 5-dimethylamino isophthalic acid. The material is a member of the STAM series of MOFs, with a Kagome lattice structure and contains two types of pore system. The structure was investigated using single crystal X-ray diffraction, variable temperature powder X-ray diffraction was used to determine the thermal stability of the MOF, and nitrogen BET adsorption was employed to determine the porosity of the material.

U2 - 10.1039/C9CE01035A

DO - 10.1039/C9CE01035A

M3 - Article

SN - 1466-8033

VL - 21

SP - 5387

EP - 5391

JO - CrystEngComm

JF - CrystEngComm

IS - 36

ER -

Synthesis and structural characterisation of the copper MOF: STAM-NMe2

Abstract

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Datasets

Synthesis and structural characterisation of the copper MOF: STAM-NMe2 (dataset 2)

Synthesis and structural characterisation of the copper MOF: STAM-NMe2 (dataset)

Cite this