Abstract
The synthesis and solid state conformations of a number of N,N'-linked carbazoles and indoles has been investigated. Using xylyl-based linkers, the o, m and p-linked carbazoles and indoles 4-6, 8-10 and 12, 13 were prepared, Likewise, unsymmetrical derivatives were also prepared. Investigation using X-ray crystallography showed that the heterocycles adopted either stretched or folded conformations in the solid state. (C) 2002 Elsevier Science Ltd. All rights reserved.
| Original language | English |
|---|---|
| Pages (from-to) | 3709-3720 |
| Number of pages | 12 |
| Journal | Tetrahedron |
| Volume | 58 |
| Issue number | 19 |
| Publication status | Published - 6 May 2002 |
Keywords
- polycyclic heterocyclic compounds
- indoles
- conformation
- X-ray crystallography
- INTRAMOLECULAR EXCIMER FORMATION
- RIGID MOLECULAR TWEEZERS
- PHOTOPHYSICAL PROPERTIES
- CONFORMATION
- COMPLEXATION
- HOSTS
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