Synthesis and reactivity of [Au(NHC)(Bpin)] complexes

Caroline M. Zinser; Fady Nahra; Laura Falivene; Marcel Brill; David B. Cordes; Alexandra M. Z. Slawin; Luigi Cavallo; Catherine Cazin; Steven Nolan

doi:10.1039/C9CC03171E

Synthesis and reactivity of [Au(NHC)(Bpin)] complexes

Caroline M. Zinser, Fady Nahra, Laura Falivene, Marcel Brill, David B. Cordes, Alexandra M. Z. Slawin, Luigi Cavallo, Catherine Cazin, Steven Nolan

Research output: Contribution to journal › Article › peer-review

Abstract

A new class of [Au(NHC)(Bpin)] complexes has been synthesized and their unusual reactivity was investigated using computational and experimental methods. The gold-boryl complexes exhibit unexpected high stability and reactivity.

Original language	English
Journal	Chemical Communications
Volume	55
Issue number	47
Early online date	15 May 2019
DOIs	https://doi.org/10.1039/C9CC03171E
Publication status	Published - 14 Jun 2019

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10.1039/C9CC03171E

Zinser_2019_CC_Synthesis_AAM
Copyright © 2019 The Author(s). This work has been made available online in accordance with the publisher’s policies. This is the author created, accepted version manuscript following peer review and may differ slightly from the final published version. The final published version of this work is available at https://doi.org/10.1039/C9CC03171E
Accepted author manuscript, 402 KB

Catalytic C-H bond functionalisation: Catalytic C-H bond functionalisation
Cazin, C. S. J. (PI)
The Royal Society
1/10/11 → 6/05/17
Project: Fellowship

Alexandra Martha Zoya Slawin
- amzsst-andrews.acuk
- School of Chemistry - Emeritus Professor
- EaSTCHEM
Person: Emeritus Professor

Synthesis and reactivity of [Au(NHC)(Bpin)] complexes (dataset)
Zinser, C. M. (Creator), Nahra, F. (Creator), Falivene, L. (Creator), Brill, M. (Creator), Cordes, D. B. (Creator), Slawin, A. M. Z. (Creator), Cavallo, L. (Creator), Cazin, C. (Creator) & Nolan, S. (Creator), Cambridge Crystallographic Data Centre, 2019
https://dx.doi.org/10.5517/ccdc.csd.cc1zq6lh and 3 more links, https://dx.doi.org/10.5517/ccdc.csd.cc1zq6mj, https://dx.doi.org/10.5517/ccdc.csd.cc1zq6pl, https://dx.doi.org/10.5517/ccdc.csd.cc1zq6nk (show fewer)
Dataset

Cite this

@article{bf87352de9524fd5960c59e2180fefb6,

title = "Synthesis and reactivity of [Au(NHC)(Bpin)] complexes",

abstract = "A new class of [Au(NHC)(Bpin)] complexes has been synthesized and their unusual reactivity was investigated using computational and experimental methods. The gold-boryl complexes exhibit unexpected high stability and reactivity.",

author = "Zinser, {Caroline M.} and Fady Nahra and Laura Falivene and Marcel Brill and Cordes, {David B.} and Slawin, {Alexandra M. Z.} and Luigi Cavallo and Catherine Cazin and Steven Nolan",

note = "The authors gratefully acknowledge the Royal Society (University Research Fellowship to C.S.J.C.), AstraZeneca (Studenship to C.M.Z) and VLAIO (CO2PERATE) for support of this work. We thank King Saud University (DSF Program) and KAUST (Award No.OSR-2015-CCF-1974-03) for support.",

year = "2019",

month = jun,

day = "14",

doi = "10.1039/C9CC03171E",

language = "English",

volume = "55",

journal = "Chemical Communications",

issn = "1359-7345",

publisher = "Royal Society of Chemistry",

number = "47",

}

TY - JOUR

T1 - Synthesis and reactivity of [Au(NHC)(Bpin)] complexes

AU - Zinser, Caroline M.

AU - Nahra, Fady

AU - Falivene, Laura

AU - Brill, Marcel

AU - Cordes, David B.

AU - Slawin, Alexandra M. Z.

AU - Cavallo, Luigi

AU - Cazin, Catherine

AU - Nolan, Steven

N1 - The authors gratefully acknowledge the Royal Society (University Research Fellowship to C.S.J.C.), AstraZeneca (Studenship to C.M.Z) and VLAIO (CO2PERATE) for support of this work. We thank King Saud University (DSF Program) and KAUST (Award No.OSR-2015-CCF-1974-03) for support.

PY - 2019/6/14

Y1 - 2019/6/14

N2 - A new class of [Au(NHC)(Bpin)] complexes has been synthesized and their unusual reactivity was investigated using computational and experimental methods. The gold-boryl complexes exhibit unexpected high stability and reactivity.

AB - A new class of [Au(NHC)(Bpin)] complexes has been synthesized and their unusual reactivity was investigated using computational and experimental methods. The gold-boryl complexes exhibit unexpected high stability and reactivity.

U2 - 10.1039/C9CC03171E

DO - 10.1039/C9CC03171E

M3 - Article

SN - 1359-7345

VL - 55

JO - Chemical Communications

JF - Chemical Communications

IS - 47

ER -

Synthesis and reactivity of [Au(NHC)(Bpin)] complexes

Abstract

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Projects

Catalytic C-H bond functionalisation: Catalytic C-H bond functionalisation

Profiles

Alexandra Martha Zoya Slawin

Datasets

Synthesis and reactivity of [Au(NHC)(Bpin)] complexes (dataset)

Cite this