Synthesis and Coordination of 2-Diphenylphosphinothiophenocarboxamide and bis(2,5-diphenylphosphinepicolinamide)

HL Milton, MV Wheatley, Alexandra Martha Zoya Slawin, John Derek Woollins

Research output: Contribution to journalArticlepeer-review

17 Citations (Scopus)

Abstract

2-Diphenylphosphinothiophenocarboxamide (dpptc) and bis(2,5-diphenylphosphinepicolinamide) (bdpppa) have been prepared and complexed with a variety of metals. Bdpptc behaves as a monodentate P donor ligand and can become bidentate by making use of the C=O site. Bdpppa behaves as a P donor bridging ligand. In many cases, the X-ray structures reveal that the ligand backbone geometry is strongly influenced by intramolecular H-bonding. (C) 2004 Elsevier Ltd. All rights reserved.

Original languageEnglish
Pages (from-to)2575-2585
Number of pages11
JournalPolyhedron
Volume23
DOIs
Publication statusPublished - 20 Oct 2004

Keywords

  • phosphine
  • synthesis
  • coordination
  • X-ray structure
  • COMPLEXES
  • CATALYSIS

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