Synthesis and Coordination of 2-Diphenylphosphinothiophenocarboxamide and bis(2,5-diphenylphosphinepicolinamide)

HL Milton; MV Wheatley; Alexandra Martha Zoya Slawin; John Derek Woollins

doi:10.1016/j.poly.2004.09.014

Synthesis and Coordination of 2-Diphenylphosphinothiophenocarboxamide and bis(2,5-diphenylphosphinepicolinamide)

HL Milton, MV Wheatley, Alexandra Martha Zoya Slawin, John Derek Woollins

Research output: Contribution to journal › Article › peer-review

18 Citations (Scopus)

Abstract

2-Diphenylphosphinothiophenocarboxamide (dpptc) and bis(2,5-diphenylphosphinepicolinamide) (bdpppa) have been prepared and complexed with a variety of metals. Bdpptc behaves as a monodentate P donor ligand and can become bidentate by making use of the C=O site. Bdpppa behaves as a P donor bridging ligand. In many cases, the X-ray structures reveal that the ligand backbone geometry is strongly influenced by intramolecular H-bonding. (C) 2004 Elsevier Ltd. All rights reserved.

Original language	English
Pages (from-to)	2575-2585
Number of pages	11
Journal	Polyhedron
Volume	23
DOIs	https://doi.org/10.1016/j.poly.2004.09.014
Publication status	Published - 20 Oct 2004

Keywords

phosphine
synthesis
coordination
X-ray structure
COMPLEXES
CATALYSIS

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10.1016/j.poly.2004.09.014

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title = "Synthesis and Coordination of 2-Diphenylphosphinothiophenocarboxamide and bis(2,5-diphenylphosphinepicolinamide)",

abstract = "2-Diphenylphosphinothiophenocarboxamide (dpptc) and bis(2,5-diphenylphosphinepicolinamide) (bdpppa) have been prepared and complexed with a variety of metals. Bdpptc behaves as a monodentate P donor ligand and can become bidentate by making use of the C=O site. Bdpppa behaves as a P donor bridging ligand. In many cases, the X-ray structures reveal that the ligand backbone geometry is strongly influenced by intramolecular H-bonding. (C) 2004 Elsevier Ltd. All rights reserved.",

keywords = "phosphine, synthesis, coordination, X-ray structure, COMPLEXES, CATALYSIS",

author = "HL Milton and MV Wheatley and Slawin, {Alexandra Martha Zoya} and Woollins, {John Derek}",

year = "2004",

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T1 - Synthesis and Coordination of 2-Diphenylphosphinothiophenocarboxamide and bis(2,5-diphenylphosphinepicolinamide)

AU - Milton, HL

AU - Wheatley, MV

AU - Slawin, Alexandra Martha Zoya

AU - Woollins, John Derek

PY - 2004/10/20

Y1 - 2004/10/20

N2 - 2-Diphenylphosphinothiophenocarboxamide (dpptc) and bis(2,5-diphenylphosphinepicolinamide) (bdpppa) have been prepared and complexed with a variety of metals. Bdpptc behaves as a monodentate P donor ligand and can become bidentate by making use of the C=O site. Bdpppa behaves as a P donor bridging ligand. In many cases, the X-ray structures reveal that the ligand backbone geometry is strongly influenced by intramolecular H-bonding. (C) 2004 Elsevier Ltd. All rights reserved.

AB - 2-Diphenylphosphinothiophenocarboxamide (dpptc) and bis(2,5-diphenylphosphinepicolinamide) (bdpppa) have been prepared and complexed with a variety of metals. Bdpptc behaves as a monodentate P donor ligand and can become bidentate by making use of the C=O site. Bdpppa behaves as a P donor bridging ligand. In many cases, the X-ray structures reveal that the ligand backbone geometry is strongly influenced by intramolecular H-bonding. (C) 2004 Elsevier Ltd. All rights reserved.

KW - phosphine

KW - synthesis

KW - coordination

KW - X-ray structure

KW - COMPLEXES

KW - CATALYSIS

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U2 - 10.1016/j.poly.2004.09.014

DO - 10.1016/j.poly.2004.09.014

M3 - Article

SN - 0277-5387

VL - 23

SP - 2575

EP - 2585

JO - Polyhedron

JF - Polyhedron

ER -

Synthesis and Coordination of 2-Diphenylphosphinothiophenocarboxamide and bis(2,5-diphenylphosphinepicolinamide)

Abstract

Keywords

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