Synthesis and coordination chemistry of new tetradentate N2S2 donor Schiff-base ligand ca(2)-dapte: Mononuclear and dinuclear copper(I) complexes [Cu(ca(2)dapte)]ClO4 and [{Cu(PPh3)(X)}(2)(ca(2)dapte)] (X = I and Br)

Mahbod Morshedi; Mehdi Amirnasr; Alexandra M. Z. Slawin; J. Derek Woollins; Aliakbar Dehno Khalaji

doi:10.1016/j.poly.2008.10.018

Synthesis and coordination chemistry of new tetradentate N2S2 donor Schiff-base ligand ca(2)-dapte: Mononuclear and dinuclear copper(I) complexes [Cu(ca(2)dapte)]ClO4 and [{Cu(PPh3)(X)}(2)(ca(2)dapte)] (X = I and Br)

Mahbod Morshedi, Mehdi Amirnasr, Alexandra M. Z. Slawin, J. Derek Woollins, Aliakbar Dehno Khalaji

Research output: Contribution to journal › Article › peer-review

Abstract

A mononuclear copper(I) complex, [Cu(ca(2)dapte)]ClO4 (1), and two dinuclear copper(I) complexes, [{Cu(PPh3)(X)}(2)(ca(2)dapte)] (X = 1 (2) and Br (3)), of a new tetradentate N2S2 donor Schiff-base ligand ca2dapte have been prepared (ca(2)dapte = N,N'-bis(trans-cinnamaidehyde)-1,2-di(o-iminophenylthio)ethane). These compounds have been characterized by elemental analyses (CHN), FT-IR, UV-Vis and H-1 NMR spectroscopy. The crystal structures of these copper(l) complexes have been determined by single-crystal X-ray diffraction. The coordination geometry around Cu(I) centers in these complexes is a distorted tetrahedron. The Ca(2)dapte is coordinated to Cu(I) as a tetradentate ligand in 1, while it acts as a bis-bidentate bridging ligand in 2 and 3. (C) 2008 Elsevier Ltd. All rights reserved.

Original language	English
Pages (from-to)	167-171
Number of pages	5
Journal	Polyhedron
Volume	28
Issue number	1
DOIs	https://doi.org/10.1016/j.poly.2008.10.018
Publication status	Published - 14 Jan 2009

Keywords

N/S donor
Copper(I) complexes
Mononuclear
Dinuclear
Single-crystal X-ray diffraction
CRYSTAL-STRUCTURES
STRUCTURAL-CHARACTERIZATION
CU(I)
EMISSION
LUMINESCENCE
REACTIVITY
SYSTEMS

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Morshedi, M., Amirnasr, M., Slawin, A. M. Z., Woollins, J. D., & Khalaji, A. D. (2009). Synthesis and coordination chemistry of new tetradentate N2S2 donor Schiff-base ligand ca(2)-dapte: Mononuclear and dinuclear copper(I) complexes [Cu(ca(2)dapte)]ClO4 and [{Cu(PPh3)(X)}(2)(ca(2)dapte)] (X = I and Br). Polyhedron, 28(1), 167-171. https://doi.org/10.1016/j.poly.2008.10.018

@article{174fac908d914a4fba7f4bebd62d98f0,

title = "Synthesis and coordination chemistry of new tetradentate N2S2 donor Schiff-base ligand ca(2)-dapte: Mononuclear and dinuclear copper(I) complexes [Cu(ca(2)dapte)]ClO4 and [{Cu(PPh3)(X)}(2)(ca(2)dapte)] (X = I and Br)",

abstract = "A mononuclear copper(I) complex, [Cu(ca(2)dapte)]ClO4 (1), and two dinuclear copper(I) complexes, [{Cu(PPh3)(X)}(2)(ca(2)dapte)] (X = 1 (2) and Br (3)), of a new tetradentate N2S2 donor Schiff-base ligand ca2dapte have been prepared (ca(2)dapte = N,N'-bis(trans-cinnamaidehyde)-1,2-di(o-iminophenylthio)ethane). These compounds have been characterized by elemental analyses (CHN), FT-IR, UV-Vis and H-1 NMR spectroscopy. The crystal structures of these copper(l) complexes have been determined by single-crystal X-ray diffraction. The coordination geometry around Cu(I) centers in these complexes is a distorted tetrahedron. The Ca(2)dapte is coordinated to Cu(I) as a tetradentate ligand in 1, while it acts as a bis-bidentate bridging ligand in 2 and 3. (C) 2008 Elsevier Ltd. All rights reserved.",

keywords = "N/S donor, Copper(I) complexes, Mononuclear, Dinuclear, Single-crystal X-ray diffraction, CRYSTAL-STRUCTURES, STRUCTURAL-CHARACTERIZATION, CU(I), EMISSION, LUMINESCENCE, REACTIVITY, SYSTEMS",

author = "Mahbod Morshedi and Mehdi Amirnasr and Slawin, {Alexandra M. Z.} and Woollins, {J. Derek} and Khalaji, {Aliakbar Dehno}",

year = "2009",

month = jan,

day = "14",

doi = "10.1016/j.poly.2008.10.018",

language = "English",

volume = "28",

pages = "167--171",

journal = "Polyhedron",

issn = "0277-5387",

publisher = "Elsevier",

number = "1",

}

Morshedi, M, Amirnasr, M, Slawin, AMZ, Woollins, JD & Khalaji, AD 2009, 'Synthesis and coordination chemistry of new tetradentate N2S2 donor Schiff-base ligand ca(2)-dapte: Mononuclear and dinuclear copper(I) complexes [Cu(ca(2)dapte)]ClO4 and [{Cu(PPh3)(X)}(2)(ca(2)dapte)] (X = I and Br)', Polyhedron, vol. 28, no. 1, pp. 167-171. https://doi.org/10.1016/j.poly.2008.10.018

Synthesis and coordination chemistry of new tetradentate N2S2 donor Schiff-base ligand ca(2)-dapte: Mononuclear and dinuclear copper(I) complexes [Cu(ca(2)dapte)]ClO4 and [{Cu(PPh3)(X)}(2)(ca(2)dapte)] (X = I and Br). / Morshedi, Mahbod; Amirnasr, Mehdi; Slawin, Alexandra M. Z. et al.
In: Polyhedron, Vol. 28, No. 1, 14.01.2009, p. 167-171.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - Synthesis and coordination chemistry of new tetradentate N2S2 donor Schiff-base ligand ca(2)-dapte: Mononuclear and dinuclear copper(I) complexes [Cu(ca(2)dapte)]ClO4 and [{Cu(PPh3)(X)}(2)(ca(2)dapte)] (X = I and Br)

AU - Morshedi, Mahbod

AU - Amirnasr, Mehdi

AU - Slawin, Alexandra M. Z.

AU - Woollins, J. Derek

AU - Khalaji, Aliakbar Dehno

PY - 2009/1/14

Y1 - 2009/1/14

N2 - A mononuclear copper(I) complex, [Cu(ca(2)dapte)]ClO4 (1), and two dinuclear copper(I) complexes, [{Cu(PPh3)(X)}(2)(ca(2)dapte)] (X = 1 (2) and Br (3)), of a new tetradentate N2S2 donor Schiff-base ligand ca2dapte have been prepared (ca(2)dapte = N,N'-bis(trans-cinnamaidehyde)-1,2-di(o-iminophenylthio)ethane). These compounds have been characterized by elemental analyses (CHN), FT-IR, UV-Vis and H-1 NMR spectroscopy. The crystal structures of these copper(l) complexes have been determined by single-crystal X-ray diffraction. The coordination geometry around Cu(I) centers in these complexes is a distorted tetrahedron. The Ca(2)dapte is coordinated to Cu(I) as a tetradentate ligand in 1, while it acts as a bis-bidentate bridging ligand in 2 and 3. (C) 2008 Elsevier Ltd. All rights reserved.

AB - A mononuclear copper(I) complex, [Cu(ca(2)dapte)]ClO4 (1), and two dinuclear copper(I) complexes, [{Cu(PPh3)(X)}(2)(ca(2)dapte)] (X = 1 (2) and Br (3)), of a new tetradentate N2S2 donor Schiff-base ligand ca2dapte have been prepared (ca(2)dapte = N,N'-bis(trans-cinnamaidehyde)-1,2-di(o-iminophenylthio)ethane). These compounds have been characterized by elemental analyses (CHN), FT-IR, UV-Vis and H-1 NMR spectroscopy. The crystal structures of these copper(l) complexes have been determined by single-crystal X-ray diffraction. The coordination geometry around Cu(I) centers in these complexes is a distorted tetrahedron. The Ca(2)dapte is coordinated to Cu(I) as a tetradentate ligand in 1, while it acts as a bis-bidentate bridging ligand in 2 and 3. (C) 2008 Elsevier Ltd. All rights reserved.

KW - N/S donor

KW - Copper(I) complexes

KW - Mononuclear

KW - Dinuclear

KW - Single-crystal X-ray diffraction

KW - CRYSTAL-STRUCTURES

KW - STRUCTURAL-CHARACTERIZATION

KW - CU(I)

KW - EMISSION

KW - LUMINESCENCE

KW - REACTIVITY

KW - SYSTEMS

U2 - 10.1016/j.poly.2008.10.018

DO - 10.1016/j.poly.2008.10.018

M3 - Article

SN - 0277-5387

VL - 28

SP - 167

EP - 171

JO - Polyhedron

JF - Polyhedron

IS - 1

ER -