Synthesis and characterization of photoluminescent vinylbiphenyl decorated polyhedral oligomeric silsesquioxanes

Nicolas R. Vautravers; Pascal Andre; A. M. Z. Slawin; David J. Cole-Hamilton

doi:10.1039/b814496f

Synthesis and characterization of photoluminescent vinylbiphenyl decorated polyhedral oligomeric silsesquioxanes

Nicolas R. Vautravers, Pascal Andre, A. M. Z. Slawin, David J. Cole-Hamilton

Research output: Contribution to journal › Article › peer-review

Abstract

Grubbs cross-metathesis has been used to functionalize octavinylsilsesquioxane with fluorescent vinylbiphenyl-modified chromophores to design new hybrid organic-inorganic nanomaterials. Those macromolecules have been characterized by NMR, microanalyses, MALDI-TOF mass spectrometry and photoluminescence. This last method was shown to be an interesting tool in the analysis of the purity of the cube derivatives.

Original language	English
Pages (from-to)	717-724
Number of pages	8
Journal	Organic & Biomolecular Chemistry
Volume	7
Issue number	4
DOIs	https://doi.org/10.1039/b814496f
Publication status	Published - 2009

Keywords

MOLECULAR RECOGNITION
CROSS-METATHESIS
DENDRIMERS
CATALYSIS
OCTAVINYLSILSESQUIOXANE
OLIGOSILSESQUIOXANES
FRAMEWORKS
CHEMISTRY
CLEAVAGE
SENSORS

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10.1039/b814496f

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@article{5432bf3647774faea606ae59edbc1ab8,

title = "Synthesis and characterization of photoluminescent vinylbiphenyl decorated polyhedral oligomeric silsesquioxanes",

abstract = "Grubbs cross-metathesis has been used to functionalize octavinylsilsesquioxane with fluorescent vinylbiphenyl-modified chromophores to design new hybrid organic-inorganic nanomaterials. Those macromolecules have been characterized by NMR, microanalyses, MALDI-TOF mass spectrometry and photoluminescence. This last method was shown to be an interesting tool in the analysis of the purity of the cube derivatives.",

keywords = "MOLECULAR RECOGNITION, CROSS-METATHESIS, DENDRIMERS, CATALYSIS, OCTAVINYLSILSESQUIOXANE, OLIGOSILSESQUIOXANES, FRAMEWORKS, CHEMISTRY, CLEAVAGE, SENSORS",

author = "Vautravers, {Nicolas R.} and Pascal Andre and Slawin, {A. M. Z.} and Cole-Hamilton, {David J.}",

year = "2009",

doi = "10.1039/b814496f",

language = "English",

volume = "7",

pages = "717--724",

journal = "Organic & Biomolecular Chemistry",

issn = "1477-0520",

publisher = "Royal Society of Chemistry",

number = "4",

}

TY - JOUR

T1 - Synthesis and characterization of photoluminescent vinylbiphenyl decorated polyhedral oligomeric silsesquioxanes

AU - Vautravers, Nicolas R.

AU - Andre, Pascal

AU - Slawin, A. M. Z.

AU - Cole-Hamilton, David J.

PY - 2009

Y1 - 2009

N2 - Grubbs cross-metathesis has been used to functionalize octavinylsilsesquioxane with fluorescent vinylbiphenyl-modified chromophores to design new hybrid organic-inorganic nanomaterials. Those macromolecules have been characterized by NMR, microanalyses, MALDI-TOF mass spectrometry and photoluminescence. This last method was shown to be an interesting tool in the analysis of the purity of the cube derivatives.

AB - Grubbs cross-metathesis has been used to functionalize octavinylsilsesquioxane with fluorescent vinylbiphenyl-modified chromophores to design new hybrid organic-inorganic nanomaterials. Those macromolecules have been characterized by NMR, microanalyses, MALDI-TOF mass spectrometry and photoluminescence. This last method was shown to be an interesting tool in the analysis of the purity of the cube derivatives.

KW - MOLECULAR RECOGNITION

KW - CROSS-METATHESIS

KW - DENDRIMERS

KW - CATALYSIS

KW - OCTAVINYLSILSESQUIOXANE

KW - OLIGOSILSESQUIOXANES

KW - FRAMEWORKS

KW - CHEMISTRY

KW - CLEAVAGE

KW - SENSORS

U2 - 10.1039/b814496f

DO - 10.1039/b814496f

M3 - Article

SN - 1477-0520

VL - 7

SP - 717

EP - 724

JO - Organic & Biomolecular Chemistry

JF - Organic & Biomolecular Chemistry

IS - 4

ER -

Synthesis and characterization of photoluminescent vinylbiphenyl decorated polyhedral oligomeric silsesquioxanes

Abstract

Keywords

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